Chemical Hygiene Plan Training Program North Adams Public Schools Adapted from Oakland Community College Chemical Hygiene Training Powerpoint

Chemical Hygiene Plan Training Objectives Reduce number of lab accidents Achieve OSHA compliance

General Awareness Session Chemical Hygiene Plan Understanding MSDSs

Training Overview oPurpose and Policy and Responsibilities oHazardous Chemicals oLabeling, Storage, and Disposal oMaterial Safety Data Sheets (MSDSs) oEmergency Procedures and Control Measures oStandard Operating Procedures (SOPs) oExposure Monitoring and Medical Attention

For all staff in September 2013, and for new staff hired later during 1 st day manditory training Prior to new tasks involving hazardous chemicals Training shall occur:

This Chemical Hygiene Plan Training is not designed to: Satisfy all required elements of the Lab Standard Provide detailed safety training

By the end of this presentation, you will be able to Describe the purpose of a Chemical Hygiene Plan Identify locations where hazardous chemicals may be located in North Adams Public Schools buildings Identify North Adams Schools Chemical Hygiene Officer Know what to do in case of accidental contact with hazardous chemicals

NAPS Chemical Hygiene Plan

Purpose and Policy Purpose: Ensure that the hazards are evaluated Convey information to employees Policy: You are entitled to a safe and healthy place to work, and Have a right to know what you may be exposed to and how to protect yourself

Overview of Chemical Safety Plan The following slide review the 15 topics covered in the NAPS Chemical Safety Plan. The Plan will be available on the District Website by January, NAPS will also appoint a Chemical Safety Officer by January, 2014.

1. Employer Responsibilities Develop and implement a written Chemical Hygiene Plan (CHP) Inventory all hazardous materials and acquire all necessary Material Safety Data Sheets (MSDSs) Identify hazards by labeling chemicals using MSDSs Train employees on physical and health hazards and protective measures Provide medical monitoring for employees

2. Employee Responsibilities oFollow all procedures and policies relating to chemicals and follow appropriate laboratory procedures and rules as outlined in the Chemical Hygiene Plan oRefrain from operations without proper instruction and/or authorization oSeek out and request information oWear appropriate protective equipment oReport accidents and near-misses immediately, even minor injuries or exposures

3. Administrative Controls Assign a Chemical Hygiene Officer Ensure lab supervisors know their responsibilities under the Chemical Hygiene Plan

4. Operational Controls Generic Standard Operating Procedures Specific Standard Operating Procedures

Generic Standard Operating Procedures Described in the Chemical Hygiene Plan Include Chemical storage Using compressed gases Emergency response

Specific Standard Operating Procedures Science teachers write them Specific to each experimental procedure involving hazardous chemicals No required format Required content: Hazard controls Personal protective equipment Health & safety information Decontamination & waste disposal procedures

5. Engineering Controls in Drury Science Labs Fume Hoods Biosafety Cabinets Substitution

6. “ Other ” Control Measures Protective Equipment Respirators, goggles, gloves, lab coats Safety Equipment Safety showers, eyewashes, fire extinguishers, first aid kits, explosion- proof refrigerators Laboratory Maintenance and Inspection Safety inspections, fume hood condition, chemical storage, spill kits, etc.

7. Exposure Assessments Initial monitoring with: Signs or symptoms of overexposure You suspect exposure limits have been exceeded Periodic monitoring: Determined & carried out by Chemical Safety Officer

8. Medical Exams Offered as appropriate Required where mandated Hazard Assessment Carcinogens Acutely toxic chemicals Radioactive materials Biological hazards

9. Regulated Waste Management Wastes Considered Non-Hazardous Hazardous Liquid Industrial Universal

10.Hazardous Chemical Inventories An inventory of hazardous chemicals is required for each lab

11. Hazardous Chemicals Locations at NAPS May Include: Laboratory chemicals used or stored in science laboratories and preparation areas; Art supplies, including paints, stains, inks, glazes, and photo processing chemicals, used in (visual and performing) art and shop; Cleaning products utilized by custodial, cafeteria, and maintenance staff; Pesticides, fertilizers, and de-icers/salts/ sands used for grounds maintenance, as well as pesticides used for building maintenance; Paints, solvents, fuels, degreasers, and lubricants used in building operation and maintenance; Oils, fuels, paints, antifreeze, and other chemicals used to maintain and repair equipment for transportation, school maintenance, and shop classes; Inks, solvents, and adhesives used for printing in school offices; and

Hazardous Chemicals In Laboratories May Consist Of: Corrosives - Nitric Acid Oxidizers - Silver Nitrate General Organic Compounds - Aniline Caustics - Calcium Oxide Reactive Metals - Sodium Explosive Anhydrides and Anhydrous Compounds - Sodium Peroxide Ketones - Acetone Poisons - Potassium Cyanide General Inorganic Compounds - Calcium Carbide Flammable Metals - Magnesium Flammables - Ethanol, Butanol, Ethyl Ether Carcinogens - Formaldehyde

12. Labels - Basics Identity of the hazardous chemical(s) Appropriate hazard warnings Name, address, and emergency telephone number of the chemical manufacturer or other responsible party

Labels - Other Information Appropriate protective equipment Carcinogenicity warning if applicable Signal word - Danger!, Warning!, or Caution! Statement of hazard Instructions in case of contact or exposure First-Aid or antidote Instructions in case of fire, spill, or leak Instructions for container handling and storage Never remove label, and if transferred to a secondary container, label it with appropriate information - chemical name, etc.

HMIS Label - Example Secondary Labeling System

CARCINOGEN

Labels- Symbols and Pictures

Labels - Example

13. Material Safety Data Sheets (MSDS ’ s) Chemical document put out by manufacturer detailing physical and health hazards One for every hazardous chemical on campus Master file located with Chemical Safety Officer Review before working with any chemical

Information on MSDSs Identity and date of preparation Manufacturer ’ s name, address, and telephone number Hazardous ingredients Physical and chemical properties - flash pt., appearance and odor, etc.

Information on MSDSs Control measures Physical hazards Routes of entry into body Acute and chronic health effects Carcinogenicity Handling and storage precautions

14. Chemical Sensitivities Many hazardous chemicals are used in the workplace Immune responses can vary among individuals Low-dose exposures over longer periods of time can alter function of immune system

Chemical Sensitivities Effects may develop slowly Symptoms may include Multiple Chemical Sensitivities, Contact Dermatitis Examples include – nickel compounds, amines, epoxides, some organic solvents

16. Protective Measures Routes of entry Inhalation Ingestion Skin or eye contact, and/or absorption Exposure = Dose x Duration

Protective Measures Avoid Inhalation Use proper ventilation (Fume Hood) Use respiratory protection (Respirator) Check MSDS for specific requirements

Protective Measures Prevent Ingestion NO eating, drinking, smoking, or applying cosmetics in labs Wash hands frequently Label everything Read labels and MSDSs

Protective Measures Prevent Skin or Eye Contact Wear protective equipment Minimize the area of exposed skin

Protective Measures - Review Avoid Inhalation Use proper ventilation Use respiratory protection when needed Prevent Ingestion No eating, drinking, smoking, or apply cosmetics in labs Wash hands frequently

Protective Measures - Review Prevent Skin or Eye Contact Wear protective equipment Minimize the area of exposed skin

Handle With Caution Use cautious approach Read labels, follow their directions Think about consequences Treat all substances as if they are hazardous Practice good chemical hygiene

15. Emergency Procedures for Chemical Spills Evacuate and call Public Safety at 911 for large spill (>5 gallons) situations Treat life threatening injuries immediately by calling 911 Contain the spill - read MSDS Wear protective equipment during clean-up Best response is preparation

Emergency Procedures Personal Contamination Flush contaminated area with water Remove contaminated clothing Rinse with water for 15 minutes Seek medical attention if irritation persists

Emergency Procedures Chemical in the Eye(s) Flush eyeballs and inner eyelids Forcibly hold eyes open Irrigate for at least 15 minutes Seek medical attention immediately

Summary You may be exposed to hazardous chemicals or chemicals products used in NAPS buildings Information is available on labels and MSDSs Program is in place in your work area to inform and train you

Follow the Link Below… …to certify that you have completed this training. (If the link above isn’t working, use the “Chem Safety Survey” link on the Professional Development page of the NAPS website)