The heat of combustion – in other words, the amount of thermal energy released in the process of burning a mass unit of a given fuel – is a very Important.

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Presentation transcript:

The heat of combustion – in other words, the amount of thermal energy released in the process of burning a mass unit of a given fuel – is a very Important characteristic. In the table, there are the combustion heat data for major fuels we use today, and for hydrogen, which will hopefully be the main fuel in the. Missing are the data for ethyl alcohol and methyl alcohol (methanol). Their heat of combustion is about 70% of that for gasoline. A.k.a. natural gas – it is the “greenest” fuel of all fossil fuels.

Let’s talk about the pollutions resulting from fuel burning. One is the “waste heat” – about ¾ of all thermal energy released by burning all kinds of fuels is “dumped” to “heat sinks”. The remaining ¼ also ends up as heat. Is it a serious problem? Well, not yet: Total power received by Earth in the form of sunlight: This is the total power released to the en- vironment by us. Much? Not really…

Chemical pollutions: The cleanest of all fuels is hydrogen: -- just water vapor! Water vapor is a greenhouse gas, but it comes from oceans, lakes, rivers, from the soil and plants. Water vapor from fuel burning is not a significant figure in comparison to those natural sources. Unfortunately, hydrogen is not yet used at a major scale. Why? We will talk about that soon! Methane, or “natural gas”, is the second greenest of all fuels, and the greenest of all fossil fuels.

How much carbon dioxide is released when burning one kilogram of methane? Let’s calculate: The atomic weight of H is 1; The atomic weight of C is 12; The atomic weight of O is 16; Hence: The molecular weight of CH4 is 12+4 = 16; The molecular weight of H2O is 2+16 = 18; The molecular weight of CO2 is = 44;

Coal: with a sufficiently good approximation for our calculations, it is an almost pure carbon. Compare with natural gas: burning 1 kg of coal produces 3.67/2.75 times more carbon dioxide than burning 1 kg of methane – 33% more. Take combustion heat data: methane – 55.5 MJ/kg; coal – 27 MJ/kg So, obtaining the same amount of heat from coal as from methane releases (55.5/27)x1.33 = 2.7 times more carbon dioxide to the air!

Because of the relatively low carbon dioxide emission, natural gas is considered a “good guy” from the standpoint of energy alternatives. An efficient engine converting thermal energy from natural gas burning to mechanical power is the so-called “gas turbine”. A well-designed gas turbine can attain an efficiency as high as  = 37 %.

Gas turbines are quite compact machines, and certainly good-looking:

The exhaust gases from a gas turbine are still pretty hot. Hot enough for making steam that can be used for generating extra power in a steam turbine. Such a combined system can attain efficiency ε of nearly 50%, which is a record-high value for a thermal power plant.