1 6th WRBRF 2015 Berlin, March Review of changes voted to Section 38.3 of the UN Manual of Tests & Criteria (INF 11.) UNSCETDG Geneva, Dec. 1rst, 2014 Claude CHANSON PPT 5.

2 Content: 6 proposals of modification have been adopted Proposal 1. Add a § (f) to § Proposal 2. Modify § Proposal 3. Modify paragraph (g) Proposal 4. T4 shock test change. Option 1 Proposal 5. T5 Short Circuit Proposal 6. Change in SP First Informal WG, Brussels: Short circuit test request from DOT/PHMSA

1- Testing requirements of large format Lithium-batteries 3 PROPOSAL Note Add the following text “f) For batteries which are to be tested according to T.4 with a peak acceleration less than 150 gn, a change in the mass which could adversely impact the result of the T.4 test and lead to a failure. “ Justification will be presented with the discussion on T4, page 13.

2- Testing requirements of large format Lithium-batteries 4 PROPOSAL 2. Remove - a part of the sentence in § (f) and, - the last sentence of § (f). When testing a battery assembly […], with a nominal energy in Watt-hour of not more than Wh, that is assembled from batteries [or single cell batteries] that have passed all applicable tests, one assembled battery assembly in a fully charged state shall be tested under tests T.3, T.4 and T.5, and, in addition, test T.7 in the case of a rechargeable battery. A rechargeable battery shall have been cycled at least 25 cycles.”.

2- Testing requirements of large format Lithium-batteries 5 Cells tested + batteries tested Cells tested + batteries tested +assembled batteries tested Cells tested + batteries tested + ass. Batteries specified 12 kg limit 6200 Wh limit Justification for PROPOSAL The objective of the test of large batteries that are assembled from batteries is to check the quality of the mechanical assembly (tests T3 vibration, T4 shock) or electrical protections (test T5 short circuit and T7 overcharge when applicable). 2- These protections have already been tested for new cells and batteries (not yet assembled in the final battery) 3 –Batteries of the assembly have already been tested after 25 cycles. Consequently, the 25 cycles requirement are not necessary for the testing of the mechanical assembly. 4 - Realizing 25 cycles on a large battery requires specific equipment (charging and discharging systems adapted to the high capacity and/or high voltage of the battery) which may not be available in many tests facilities.

6 PROPOSAL 3.Modified wording of parag g. Justification: the text should describe the risks to prevent, rather than recommend means to prevent risks. 3- Testing requirements of large format Lithium-batteries When batteries or single cell batteries that have passed all applicable tests are electrically connected to form a battery in which the aggregate lithium content of all anodes, when fully charged, is more than 500 g, or in the case of a lithium ion battery, with a Watt-hour rating of more than Wh, the assembled battery does not need to be tested if the battery type has been verified as preventing: (i)It is designed with a battery management system that has been (ii)demonstrated to ensure that the battery will never be subject (iii)to overcharge; and (ii) The assembled battery is equipped with (iv)a system capable of preventing short circuits or over discharge (v)between the batteries.”. i.Overcharge; ii.Short circuits; and iii.Over discharge between the batteries.

3- Proposals for changes in T4 shock test. Test procedure of Test 4 : shock test 1. small batteries : peak acceleration of 150 gn pulse duration of 6 milliseconds. 2. large batteries (gross mass greater than 12 kg), peak acceleration of 50 gn pulse duration of 11 milliseconds. ISSUES: -1- The constant acceleration requirement 50 gn should not intend to impose excessively large forces to the large batteries (such as hybrid automotive type): currently there is for example for a 70 kg battery a N force required to achieve the 50gn acceleration. 7 PROPOSAL 4. OPTION 1.

8 2- A strong discontinuity is introduced in the test between a battery with a weight of kg at 17k N (150 gn) and a battery with a weight of kg battery at ~6k N. 3- Proposals for changes in T4 shock test.

Discussion/ Rationale: -Generic principle to avoid excessive increase of the force and discontinuity : test with a constant energy shock. -The consequence is a continuous change in the peak pulse acceleration and duration according the battery weight. -Other approach: replacement of the shock test by a drop test. -Finally not agreed, due to the potential difficulties for the control of the specification and of the realization of the test. (reproducibility potential issues) -But this test provides a peak acceleration change according weight considered as more representative: it has been agreed to take it in account. => A rationalized approach is proposed, adjusting acceleration based on constant energy and pulse duration for all battery weights. The pulse duration of 6 ms for small batteries and 11 ms for large batteries is maintained Proposals for changes in T4 shock test.

Proposal 4 (option 1) A formula allowing the calculation of the peak acceleration is provided And is applied for constant energy of 12kg, 50gn shoc Proposals for changes in T4 shock test.

Proposal 4 (option 1): Based on the new definition, the energy applied for the shock test is constant, and the forces are not increasing to excessively large values Proposals for changes in T4 shock test.

Proposal 4 (option 1): An illustration of the corresponding acceleration is shown below Proposals for changes in T4 shock test. Batteries ≤ 12.0 kgBatteries > 12.0 kg

adjusting acceleration based on constant energy and pulse duration for large batteries only. Justification: the scope of the working group is only large batteries. - the small batteries test is maintained at constant acceleration 150 gn. - The discontinuity between the small and large batteries is maintained. 13 PROPOSAL 4. OPTION Proposals for changes in T4 shock test.

Issues and proposal for change of (c): -If application of the proposed change => need to indicate changes in weight/mass triggering a new test. -No indication available in the present text, relative to the mass variation inside a design type. This point was not easy to define. By reference to the sub paragraph (c), “A change that would lead to failure of any of the tests, » the change of design type has been defined by reference to the test result: Proposal for (c) (Proposal 1) Add the sub paragraph: “f)For batteries which are to be tested according to T.4 with a peak acceleration less than 150 gn, a change in the mass which could adversely impact the result of the T.4 test and lead to a failure. “ Proposals for changes in T4 shock test.

5- Proposal for changes in T5 short circuit test 15 The cell or battery to be tested shall be temperature stabilized so that its external case temperature reaches 55 +/- 2 °C and then the cell or battery shall be subjected to a short circuit condition with a total external resistance of less than 0.1 ohm at 55 +- 2 °C. This short circuit condition is continued for at least one hour after the cell or battery external case temperature has returned to 55 +/- 2 °C. Requirement: Cells and batteries meet this requirement if their external temperature does not exceed 170 °C and there is no disassembly, no rupture and no fire during the test and within six hours after the test. PROPOSAL 5. Current text

16 Case 1: large battery test: fuse is opening 5- Proposal for changes in T5 short circuit test

17 Case 2: large battery test: fuse is not opening 5- Proposal for changes in T5 short circuit test

18 ISSUES Tolerance for the temperature +55°C (+/-2°C) too tight : Example: Thermal sensors at +/-2°C for temperature regulation, will generate larger tolerance on the battery. In several standards +/-4°C rather than +/-2°C +/-2°C is a constraint for the test equipment Time of observation after the maximum peak temperature. The cooling time for large batteries can be very long, depending on their thermal insulation. Once the surface temperature is decreasing, for a long time, observation time has no more technical utility. maintaining the battery inside the oven during the short circuit test makes the test unpractical: the temperature specification should describe the stabilized internal battery temperature only, before starting the test. The critical point to guarantee is the homogeneous temperature when the test is launched. Once the test is started, the possible temperature change induced by the short circuit is much faster than the effect of external cooling. 5- Proposal for changes in T5 short circuit test

19 Proposal of case A 5- Proposal for changes in T5 short circuit test

Comments from last SCTDG meeting Measuring on the external case cannot say if it is homogeneous: other place for measurement? Internal measurement would interfere with the design. It is not feasible. But homogeneity can be controlled through minimum time and/or surface temperature stabilization. Add ”for a minimum time” in the text. Is it a risk of fooling the test, as the ambient temperature is not mentioned when the short circuit test is started? Because the temperature is homogeneous when the battery is removed out of the thermal cabinet, then the surface temperature will be the first cooling place of the battery. Consequently, as the surface temperature is specified, there is no risk to fool the test. No text change needed. Propose for simplification to remove the part of the sentence about « temperature re-increase«. Agreed Proposal for changes in T5 short circuit test

The cell or battery to be tested shall be heated for a period of time necessary to reach an homogeneous stabilized temperature of stabilized so that its external case temperature reaches 57 o C ±4 o C, measured on the external case. This period of time depends on the size and design of the cell or battery. It The time required for achieving to acheive the stabilized temperature shall be assessed and documented. This period of time depends on the size and design of the cell or battery. If this assessment is not feasible, the exposure time shall be at least 6 hours for small cells and small batteries, and 12 hours for large cells and large batteries. Then the cell or battery at 57 o C ±4 o C shall be subjected to a one short circuit condition with a total external resistance of less than 0.1 ohm at 55 ±2 o C. This short circuit condition is continued for at least one hour after the cell or battery external case temperature has returned to 57 o C ±4 o C, or in the case of the large batteries, has decreased by half of the maximum temperature increas observed during the test and remains below that value., provided the temperature during the cooling phase has been steadily decreasing [not re-increased by more than 5 o C]. 21 Amendment Proposal: for § Test procedure. 5- Proposal for changes in T5 short circuit test

22 6- Proposal for changes in SP188 PROPOSAL 6. Justification: clarify in the UN Model Regulation that single cell batteries are cells for purposes of quantities permitted per package and for hazard communication. Add the following text to the end of SP188 “A single cell battery [as defined in the Manual of Tests and Criteria Part 3, Section 38.3] is considered a “cell” and shall be transported according to the requirements for “cells” for the purpose of this special provision.”

23 7- First Informal WG, Brussels: Short circuit test request from DOT/PHMSA DOT considere a new short circuit test is necessary “None of the ISC screening methods can address the basic concern on IS prevention. No recommendable test methods for preventing occurrence of ISC can be identified from literature search” DOT proposes an indentation test “It is important to test for the desired mechanical properties of the separator membranes to mitigate the occurrence of internal short-circuiting and thermal runaway”. The WG could not come to a consensus as to whether a new test method for the MT&C was necessary: UNSCTDG notification