Lauren, Allison and Caelin Amines and Amides Lauren, Allison and Caelin

Amines Most common organic bases Ammonia derivatives 1+ hydrogen atoms have been replaced by a carbon/substituent C dawg

There are primary, secondary and tertiary amines Structure There are primary, secondary and tertiary amines C talk l hold and look pretty

Properties Base because of pair of unshared electrons Substituent can be aromatic Polar High melting and boiling points Smaller-Ammonia smell Larger-Fishy or decaying smell

Naming Parent chain is longest carbon chain attached to the N Remove –e from corresponding alkane name and use the suffix amine Number the carbon in the parent chain to which the N is attached Other carbon chains on the nitrogen are substituents named with N- Sometimes it is necessary to name the amine group as a branch, use the prefix amino- in this case

methan-1-amine N-methylbutan-1-amine N-ethyl-N-propylbutan-1-amine

N,N-dimethylmethan-1-amine

How many ways can you name the most basic amine?

Methylamine Methanamine Aminomethane

Reactions involving amines Alkyl halide+Ammonia=1 Amine Alkyl halide+1 Amine=2 Amine Alkyl halide+2 Amine=3 Amine

Amides An amide is an organic compound that contains a carbonyl group bonded to a nitrogen atom Similar to esters but with a nitrgen bonded not an oxygen

Naming Parent chain is the one with C-O Use the suffix –amide -1st part comes from the amine -2nd part comes from the carboxylic acid *If other attachments then N- is used

ethanamide N-methylbutanamide

N,N-diethyl-2-ethylpentanamide

https://www.youtube.com/watch?v=bp7fb7Pn7xE

Properties Amides are weak bases Low molecular weight amides are soluble in water They have the ability to hydrogen bond High melting and boiling points Methanamide is liquid at room temperature, all others are solid

+ = Reactions of Amides N-methylbutylamide Preparing amides from amines and carboxylic acids + Condensation Reaction = N-methylbutylamide

Caffeine Serotonin Amide Amine Morphine Cadavorine Amine Amine

https://amazingamidesandamines.wikispaces.com/Videos

Resources Atkins, P; Jones, L (1989) Chemistry Molecules, Matter, and Change Third Edition. W.H. Freeman and Company: New York Dpcdsb.org editors Amines and Amides pdf. Retrieved September 22, 2016 from http://www.dpcdsb.org/NR/rdonlyres/9B6E4EF6-77F0-407F-A858-F0DF78B6896C/101830/17AminesandAmides.pdf Eastern Kentucky University Chapter 15 Amines and Amides. Retrieved September 23, 2016 from http://www.slideshare.net/kleppingerb/amines-and-amides Goldsmith, David J; Mandell, L; Menger, Fredric M (1972) Organic Chemistry A Concise Approach. W.A. Benjamin, Inc. Ktgss.edu.hk editors Academic Chemistry Amide. Retrieved September 30, 2016 from http://www.ktgss.edu.hk/academic/chemistry/2011-12/S5/5D/homologous/Amide.pdf Unknown Author(s) Amines and Amide. Retrieved September 24, 2016 from http://www.chem.latech.edu/~deddy/chem121/Amine.htm Unknown Author(s) Naming Amines and Amides Rules. Retrieved September 23, 2016 from http://www.laney.edu/wp/cheli-fossum/files/2012/01/Naming-Amines-and-Amides-rules.pdf

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