2. 1997 Lombardy inventory disaggregationG.Maffeis - TerrAria srl1 Spatial, temporal and chemical disaggregation of Lombardy 1997 gas inventory G.Maffeis, M.G. Longoni, E. Bossi g.maffeis@terraria.com Terraria srl. Milan - Italy Under contract with Institute for Environment and Sustainability JRC Ispra

3. 1997 Lombardy inventory disaggregationG.Maffeis - TerrAria srl2 Lombardy Emission Inventory INEMAR (INventario EMissioni ARia) project earthed by Regione Lombardia; Reference year: 1997; Last update: 2001; Time resolution: year; Spatial resolution: municipality; Pollutant: SO 2 NO X VOC CH 4 CO NH 3

4. 1997 Lombardy inventory disaggregationG.Maffeis - TerrAria srl3 Lombardy Emission Inventory macrosector % contribution

5. 1997 Lombardy inventory disaggregationG.Maffeis - TerrAria srl4 Lombardy Emission Inventory NO X (all macrosectors) ton/year

6. 1997 Lombardy inventory disaggregationG.Maffeis - TerrAria srl5 Spatial disaggregation of areal emission where: E Ci M : grid cell emission (macrosector M; cell Ci); S(u,M): landuse profile (use u; macrosector M); E c M : municipality emission (macrosector M; municipality c); A c Ci (u): landuse u surface, contained in cell Ci and belonging to municipality c.

7. 1997 Lombardy inventory disaggregationG.Maffeis - TerrAria srl6 Spatial disaggregation CORINE land cover

8. 1997 Lombardy inventory disaggregationG.Maffeis - TerrAria srl7 Spatial disaggregation (a) NOx macrosector 2 (ton/year) DOMAIN: (459; 4.945) UTM Km x and y step: 5000 m x cells: 47 y cells: 45

9. 1997 Lombardy inventory disaggregationG.Maffeis - TerrAria srl8 Spatial disaggregation (b) VOC macrosector 6 (ton/year) DOMAIN: (459; 4.945) UTM Km x and y step: 5000 m x cells: 47 y cells: 45

10. 1997 Lombardy inventory disaggregationG.Maffeis - TerrAria srl9 Spatial disaggregation (c) NOx macrosector 7 (ton/year) DOMAIN: (459; 4.945) UTM Km x and y step: 5000 m x cells: 47 y cells: 45

11. 1997 Lombardy inventory disaggregationG.Maffeis - TerrAria srl10 Spatial disaggregation (d) VOC macrosector 11 (ton/year) DOMAIN: (459; 4.945) UTM Km x and y step: 5000 m x cells: 47 y cells: 45

12. 1997 Lombardy inventory disaggregationG.Maffeis - TerrAria srl11 Temporal disaggregation of emission (a) E(t) = EF(t) * I(t) EF(t) = f 1 (h, d, m, p, a(t), M(t)) I(t) = f 2 (h, d, m, a(t)) E(t) = f 3 (h, d, m, p, a(t), M(t)) typical approximation: separation of functionality dependence f 3 (t) = f 31 (h) * f 32 (d) * f 33 (m) * f 34 (p) * f 35 (a) * f 36 (M) t: timeh: hour d: daym: month p: pollutant a(t): activity M(t): meteorology E(t): emission EF(t): emission factor I(t): indicator

13. 1997 Lombardy inventory disaggregationG.Maffeis - TerrAria srl12 Temporal disaggregation of emission (b) where: E{(h, gt, s), i, M, cc}: hourly emission (hour h, day gt, season s, pollutant i, macrosector M, climatic zone cc); P H {(h, gt, s), i, M, cc}: the 24 hours temporal profile (2376) for the day gt (3), the season s (4), the pollutant i (6), the macrosector M (11) the climatic zone s (3); E{(a, i, M, cc}: yearly emission (year a, pollutant i, macrosector M, climatic zone cc). General formulation (used in this work):

14. 1997 Lombardy inventory disaggregationG.Maffeis - TerrAria srl13 Temporal disaggregation Climatic zones 1 = green: plain; 2 = dark green: hill; 3 = brown: mountain.

15. 1997 Lombardy inventory disaggregationG.Maffeis - TerrAria srl14 Temporal disaggregation: NOx daily profile SNAP1

16. 1997 Lombardy inventory disaggregationG.Maffeis - TerrAria srl15 Temporal disaggregation: CO daily profile SNAP2

17. 1997 Lombardy inventory disaggregationG.Maffeis - TerrAria srl16 Temporal disaggregation: CO daily profile SNAP2

18. 1997 Lombardy inventory disaggregationG.Maffeis - TerrAria srl17 Temporal disaggregation: winter working profile SNAP7

19. 1997 Lombardy inventory disaggregationG.Maffeis - TerrAria srl18 Temporal disaggregation: CO winter daily profile SNAP7

20. 1997 Lombardy inventory disaggregationG.Maffeis - TerrAria srl19 VOC speciation (a) Reference: AEAT/ENV/R/0546 Issue 1 AEAT/ENV/R/0546 Issue 1 Speciation of UK emissions of non-methane organic compounds N.R. Passant - February 2002 Relative contribution of oxygenated hydrocarbons to the total biogenic VOC emissions of selected mid-European agricultural and natural plant species Relative contribution of oxygenated hydrocarbons to the total biogenic VOC emissions of selected mid-European agricultural and natural plant species G. Konig, M. Brunda, H. Puxbaum, C.N. Hewitt, S.C. Duckham and J. Rudolph Atmospheric Environment, 29, 861-874 - 1995

21. 1997 Lombardy inventory disaggregationG.Maffeis - TerrAria srl20 VOC speciation (b) where: PS(i, M): percentage speciation profile of species i, macrosector M; PS(i, M): percentage speciation profile of species i, activity a belonging to macrosector M PS(i, M): percentage speciation profile of species i, activity a belonging to macrosector M; E VOC (M): VOC yearly macrosector M emission; E VOC (a): VOC yearly activity a emission; A(M): number of activities a belonging to macrosector M.

22. 1997 Lombardy inventory disaggregationG.Maffeis - TerrAria srl21 VOC speciation SNAP4

23. 1997 Lombardy inventory disaggregationG.Maffeis - TerrAria srl22 VOC speciation SNAP6

24. 1997 Lombardy inventory disaggregationG.Maffeis - TerrAria srl23 VOC speciation SNAP7

25. 1997 Lombardy inventory disaggregationG.Maffeis - TerrAria srl24 VOC speciation SNAP11

26. 1997 Lombardy inventory disaggregationG.Maffeis - TerrAria srl25 VOC speciation UK vs LOMBARDY SNAP6