Download presentation
Presentation is loading. Please wait.
1
Chapter 2: Antacids
2
Antacids This chapter will introduce the chemistry needed to understand how antacids work Section 2.1: Types of Matter Section 2.2: Naming Chemicals Section 2.3: Writing Formulas Section 2.4: Acids & Bases Section 2.5: Chemical Reactions Section 2.6: Balancing Chemical Equations Section 2.7: Speeding up Chemical Reactions
3
Intro—Antacids
4
Why do we need antacids? Your body needs hydrochloric acid to digest food Too much causes heartburn, ulcers and can damage your esophagus
5
Antacids versus Acid Inhibitors
There are two types of medicines you can use Antacids Acid Inhibitors Neutralizes the acid currently in your system Controls the amount of acid your body produces Work quickly but your body will make more acid again Long-term solution, but needs to build up in your system to be most effective Alka-Seltzer ®, Rolaids ®, Tums ®, Malox ®, Mylanta ® Tagamat ®, Zantac ®, Pepcid AC ® Is it fair when a commercial compares the fast action of an antacid to an acid inhibitor that takes up to 7 days to build up?
6
Section 2.1—Types of Matter
8
Matter is…. Anything that has mass and takes up space (volume)
Anything made from atoms Examples: elements, molecules, cells, people, air, water, paper Non Examples: dreams, energy (light, heat), emotions
9
Pure Substances versus Mixtures
Matter is classified as either a pure substance or a mixture Pure Substances Mixtures Contain only 1 type of particle Elements or Compounds Contain 2 or more pure substances Homogeneous or Heterogeneous
10
Pure Substances Elements Compound
2 or more elements chemically bonded together to form molecules. Each is the same fixed ratio of elements. H2O, NaCl, CO2 Simplest kind of matter Made of only 1 kind of atom Cu, Ag, Fe, Br2
11
Elements can be found on the periodic table!
Single Atom Cannot be separated by chemical or physical processes Element Pure substance Every atom is the same Elements can be found on the periodic table!
12
Elements
13
Every molecule is the same
Compounds Single Molecule Made of more than one type of atom bonded together Compound Pure substance Every molecule is the same Can only be separated by chemical reactions
15
Physical combination of more than 1 type of pure substance
Mixtures More than 1 different type of matter Can be separated physically by Distillation Filtration Chromatography Mixture Not a pure substance Physical combination of more than 1 type of pure substance
16
Mixtures Homogeneous Heterogeneous (aka “solution”)
Mixtures can be classified as homogeneous or heterogeneous Homogeneous (aka “solution”) Heterogeneous It looks the same throughout; substances evenly dispersed Ex. salt water, alloys, clean air Different substances can be seen (chunks, bubbles, floaties, layers) Ex. salad dressing, fog, chocolate chip cookies, soil
17
Mixture possibilities
Mixtures can be any combination of solids, liquids and gases: Solid-solid: Medicine tablet Solid-gas: Pop Rocks candy Solid-liquid: Ice water Liquid-liquid: lemon water Gas-Liquid: Carbonated water Gas-Gas: Air
18
Homogeneous Mixtures Kool-Aid: sugar in water Brass: copper in zinc
Air: oxygen gas in nitrogen gas Milk: fat, proteins, sugar in water
19
Heterogeneous Mixtures
Oil in water Italian Salad Dressing Chicken Noodle Soup Fruit Salad
20
Classification of Matter
21
True Solutions, Colloids & Suspensions
Homogeneous Heterogeneous Heterogeneous True Solution Colloid Suspension SMALL particles don’t settle out and are too small to scatter light Ex: salt water, air, brass INTERMEDIATE particles don’t settle out but are large enough to scatter light: Ex: fog, foam, jello, paint LARGE particles that settle out over time Ex: oral medicines, italian dressing, paint Dissolved Particle Size Increases
22
True Solutions
23
vinegar and oil salad dressing
Suspensions vinegar and oil salad dressing
24
Particles Scattering Light
If the dissolved particles are large enough to scatter light, we say it exhibits the “Tyndall Effect” Solution Light passes through unchanged Colloids exhibit the Tyndall Effect Light is scattered by larger solute particles
25
Connect these concepts with Antacids
What type of matter do you think antacids are? Pure substance (Element or compound) Mixture (homogeneous or heterogeneous)
26
Connect these concepts with Antacids
Antacids are mixtures. They contain active & inactive ingredients What purposes could the inactive ingredients serve?
27
Connect these concepts with Antacids
Inactive ingredients might Add volume to make the pill able to be handled Add color and flavor Allow the tablet to be compressed and formed
28
Let’s Practice: Not in Notes
Example: Determine if each is element, compound, homogeneous or heterogeneous mixtures Tin can (Sn) Copper pipe (Cu) Concrete Carbon tetrachloride(CCl4) Sports drink
29
Let’s Practice Example:
Determine if each is element, compound, homogeneous or heterogeneous mixtures Tin Element Copper pipe Element Concrete Heterogeneous mix Carbon tetrachloride Compound Sports drink Homogenous mix
30
You Try! In Notes Example: Aluminum foil (Al)
Determine if each is element, compound, homogeneous or heterogeneous mixtures Aluminum foil (Al) Water (H2O) soda soil Carbon dioxide(CO2) Tap water
31
You Try! Example: Determine if each is element, compound, homogeneous or heterogeneous mixtures Aluminum foil (Al) Element Water (H2O) Compound Flat soda Homogeneous mix soil Heterogeneous mix Carbon dioxide(CO2) compound Tap water Homogeneous mix
32
The Science of Macaroni Salad
33
Section 2.2—Naming Chemicals
We need to be able to name the chemicals in the antacids!
34
The Language of Chemistry
Chemistry has a language all of its own Chemistry English Element Symbols Letters Chemical Formulas Words Chemical Equations Sentences Each element symbol starts with a capital letter
35
ELEMENTS: made of atoms
An atom consists of subatomic particles There are 3 subatomic particles: protons, electrons and neutrons Neutral atoms have the same number of protons and eletrons
36
IONS An atom or group of atoms with a charge.
The number of protons does not equal the number of electrons. WHY? Atoms can gain or lose electrons to acquire stability like a noble gas element.
37
The Periodic Table of Elements
Metals form cations NonMetals form anions H He Li Be B C N O F Ne Na Mg Al Si P S Cl Ar K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe Cs Ba Lu Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn Fr Ra Lr Rf Db Sg Bh Hs Mt Uun Uuu Uub Uut Metals Metalloids Non-metals
38
Monatomic Ions (formed from a single atom) Cations Positive charge
Cations Positive charge Metal atoms that lose electrons Group A (Representative metals/Type I ) The group # for metals in columns 1A, 2A, & 3A is equal to the charge of the cation Naming them: Take the element name and add the word ion
39
Monatomic Ions of Group A /Type I Metals
Group B
40
Group B (Transition/Type II Metals): have more than one charge
You should be familiar with the following transition metals with more than one charge. Fe+2 Fe+3 Sn+2 Sn+4 Pb+2 Pb+4 Co+2 Co+3 Cr Cr+3 Mn+2 Mn+3 Cu Cu+2 Naming them: Take the element name and place in parentheses the charge number as a roman numeral and add the word ion
41
Monatomic Ions of Transition/Type II Metals
+
42
Monatomic Ions (formed from a single atom) Cu+2, F-1
Anions Negative charge Nonmetals that gain electrons Group A (Representative nonmetals) Subtract the group # in columns 4A, 5A, 6A, and 7A from 8 to get the charge. Naming them: Drop the ending of the element and add –ide and then ion
43
You Try! Try These: Write the formula for each ion and name it.
Calcium Chromium Chlorine Sulfur
44
You Try! Try These: Write the formula for each ion and name it.
Calcium Ca+2 calcium ion Chromium Cr+2 chromium(II) ion Cr+3 chromium (III) ion Chlorine Cl-1 chloride ion Sulfur S-2 sulfide ion
45
Self Check Try These: Write the formula for each ion and name it.
Aluminum Zinc Iron Phosphorus Al+3 Aluminum Ion Zn+2 Zinc ion Fe+2 Iron (II) ion or Fe+3 Iron (III) ion P-3 Phosphide ion
46
Binary Ionic Compounds
Binary Ionic Compound- compound containing 2 elements—one metal and one non-metal The atoms are held together by Ionic Bonds- bond formed by attraction between + ions and – ions Metal Nonmetal + Cation - Anion Ionic Compound
47
Metals & Non-Metals Ionic Bonds are between metals & non-metals H He
Li Be B C N O F Ne Na Mg Al Si P S Cl Ar K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe Cs Ba Lu Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn Fr Ra Lr Rf Db Sg Bh Hs Mt Uun Uuu Uub Uut Metals Metalloids Non-metals
48
How to Identify & Name a Binary Ionic Compound
Look for: 2 elements (“binary”) A type I metal & a non-metal (“ionic”) To name these compounds: Write the name of the type 1 metal (the cation) Write the name of the non-metal (the anion) with the suffix “-ide” The subscripts in the formula do not matter when naming this type
49
Example #1 NaCl
50
NaCl Sodium Chloride Cation Anion “Sodium”
“Chlorine” becomes “Chloride” Sodium Chloride
51
Example #2 CaBr2
52
CaBr2 Calcium Bromide Cation Anion “Calcium”
“Bromine” becomes “Bromide” Calcium Bromide
53
Example #3 K2O
54
“Potassium” Cation K2O Anion “Oxygen” becomes “Oxide” Potassium Oxide
55
Write the name for the following compounds
Self Check Li2O Sr3P2 MgS BaI2 Example: Write the name for the following compounds
56
Write the name for the following compounds
Answers Li2O Sr3P2 MgS BaI2 Lithium oxide Strontium phosphide Magnesium sulfide Barium iodide Example: Write the name for the following compounds
57
Ternary Ionic Compounds
Ternary Ionic Compound- a compound containing at least one polyatomic ion Polyatomic Ion- an ion that has more than one atom that together have a single charge - Polyatomic Anion + Cation Ternary Ionic Compound + Polyatomic Cation - Anion
58
Common Polyatomic Ions
You don’t need to memorize them. Look at your reference sheet. COMMON POLYATOMIC IONS Acetate, CH3COO-1 or C2H3O2-1 Ammonium NH4+1 Bromate, BrO3-1 Bromite, BrO2-1 Carbonate, CO3-2 Carbonite, CO2-2 Chlorate, ClO3-1 Chlorite, ClO2-1 Chromate, CrO4-2 Cyanide, CN-1 Dichromate, Cr2O7-2 Dihydrogen phosphate, H2PO4-1 Hydrogen carbonate or bicarbonate, HCO3-1 Hydrogen phosphate or biphosphate, HPO4-2 Hydrogen sulfate or bisulfate, HSO4-1 Hydroxide, OH-1 Hypochlorite, ClO-1 Iodate, IO3-1 Iodite, IO2-1 Nitrate, NO3-1 Nitrite, NO2-1 Oxalate, C2O4-2 Perchlorate, ClO4-1 Permanganate, MnO4-1 Peroxide, O2-2 Phosphate, PO4-3 Phosphite, PO3-3 Silicate, SiO3-1 Sulfate, SO4-2 Sulfite, SO3-2
59
Identifying Polyatomic Ions: Hints
The only cation (front-half) polyatomic ion is “NH4+” All other polyatomic ions are anions (back-half) The subscripts within the polyatomic ion are important (it must match exactly with the one on your ion list) If there are parentheses, the polyatomic ion is inside (ignore the number outside)
60
Practice Identifying Polyatomic Ions
NaNO3 NH4Cl Ca(OH)2 (NH4)3PO4 K2CO3 Example: Underline& name the polyatomic ion in each compound
61
Practice Identifying Polyatomic Ions
NaNO3 NH4Cl Ca(OH)2 (NH4)3PO4 K2CO3 Nitrate Ammonium Hydroxide Ammonium & phosphate Carbonate Example: Identify and name the polyatomic ion in each compound
62
How to Identify & Name Ternary Ionic Compounds
Look for: More than 2 capital letters next to one another (not starting with H) Contain at least 1 metal & 1 non-metal To name these compounds: Write the name of the cation (either the metal element name or “Ammonium” for “NH4+”) If the anion is a polyatomic ion, write the given polyatomic ion’s name If the anion is a single non-metal element, write its name with the suffix “-ide”
63
Example # 4 Ca(NO3)2
64
“Calcium” Cation Ca(NO3)2 Polyatomic Anion “Nitrate” Calcium Nitrate
65
Example #5 Na3PO4
66
“Sodium” Cation Na3PO4 Polyatomic Anion “phosphate” Sodium phosphate
67
Example # 6 K2CO3
68
K2CO3 Potassium carbonate Cation Polyatomic Anion “potassium”
69
Write the name for the following compounds
Self Check Ca(C2H3O2)2 Li2SO3 Ba(OH)2 (NH4)2S Example: Write the name for the following compounds
70
Write the name for the following compounds
Answers Ca(C2H3O2)2 Li2SO3 Ba(OH)2 (NH4)2S Calcium acetate Lithium sulfite Barium hydroxide Ammonium Sulfide Example: Write the name for the following compounds
71
Worksheet 1 (1-10 Answers) 1. Sodium sulfide 6. Silver chloride
2. Aluminum oxide 7. Boron nitride 8. Barium fluoride 3. Sodium chloride 4. Rubidium iodide 9. Strontium nitride 5. Zinc bromide 10. Magnesium chloride
72
Worksheet 2 (1-10 Answers) 1. copper(I) fluoride 6.chromium (VI) oxide
2. copper (II) fluoride 7. gold(I) bromide 8. nickel(II) oxide 3. chromium (III) oxide 9. vanadium(III) iodide 4. lead (II) iodide 10. tin(IV) oxide 5. lead (IV) chloride
73
Worksheet 3 (1-10 Answers) 1. vanadium(V) chlorate Gold(I) nitrate
7. iron(III) phosphite 2. rhenium(VI) sulfate 8. nickel(II) bromate 3. osmium(III) iodate 9. lead(IV) sulfide 10. Manganese (VII) dichromate 4. iridium(IV) phosphate 5. palladium(IV) sulfite
74
Worksheet 4 (1-10 Answers) 1. ammonium chloride 6. ammonium nitrate
2. hydrogen chlorite 7. strontium phosphate 8. zinc chlorate 3. calcium bromate 4. beryllium sulfate 9. silver iodate 5. ammonium nitride 10. potassium dichromate
75
Transition Metals Revisisted
Transition Metal- group “B” or Type II metal that has the possibility of having more than one cation charge; Common multivalent metals and their charges Cobalt Co Co+3 Copper Cu Cu+2 Iron Fe Fe+3 Manganese Mn+2 Mn+3 Mercury Hg2+2 Hg+2 IMPORTANT: Although group B metals, SILVER (+1), CADMIUM (+2), and ZINC (+2) only have 1 charge Although the elements of TIN and LEAD are group A elements, they do have more than one charge Sn(+2 and +4) and Pb(+2 and +4)
76
How to Identify & Name Ionic Compounds with Transition Metals
Look for: One of the transition metals, excluding Ag, Cd, and Zn To name these compounds: Write the name of the Type II metal element (cation) Write the name of the anion (element name with “-ide” or polyatomic ion name) Determine the charge of the transition metal 1. Total negative charge = total positive charge for all neutral compounds 2. Divide total positive charge by the number of metal atoms 3. Write the charge in roman numerals in parentheses after the Type II metal’s name
77
Example # 7 CuCl
78
CuCl Copper Chloride Cation Anion “Copper”
“Chlorine” becomes “Chloride”
79
CuCl (I) Copper Chloride Cation Anion “Copper”
Chloride has a –1 charge CuCl -1 charge * 1 ion = -1 A –1 charge needs a +1 charge Anion “Chlorine” becomes “Chloride” Therefore, copper must be +1, (I) Copper Chloride (I)
80
Example # 8 Fe2(CO3)3
81
“Iron” Cation Fe2(CO3)3 Iron carbonate Polyatomic Anion “Carbonate”
82
Fe2(CO3)3 Iron carbonate (III) Cation Polyatomic Anion “Iron”
Carbonate has a –2 charge Fe2(CO3)3 -2 charge * 3 ions = -6 A –6 charge needs a +6 charge and there are 2 iron ions Polyatomic Anion “Carbonate” Therefore, iron must be +3 (III) Iron carbonate (III)
83
Example # 9 ZnBr2
84
“Zinc” Cation ZnBr2 Zinc bromide monatomic Anion “bromide”
85
ZnBr2 Zinc bromide Cation Polyatomic Anion “Zinc”
bromide has a –1 charge ZnBr2 -1 charge * 2 ions = -2 A –2 charge needs a +2 charge and there is 1 zinc ion Polyatomic Anion “bromide” Therefore, zinc must be +2 (not needed) it only has one charge Zinc bromide
86
Write the name for the following compounds
Self Check PbCl2 PbCl4 MnO Mn2O3 Example: Write the name for the following compounds
87
Write the name for the following compounds
Answers PbCl2 PbCl4 MnO Mn2O3 Lead (II) chloride Lead (IV) chloride Manganese (II) oxide Manganese (III) oxide Example: Write the name for the following compounds
88
Binary Covalent (Molecular) Compounds
Binary Molecular Compounds are made from two non-metals that are covalently bonded Covalent bond a bond formed from atoms that share electrons Non metal Non metal Covalent compound
89
Identifying & Naming Binary Molecular
These compounds have: 2 elements (“binary”) Both non-metals (“covalent”) To name these compounds: Write the name of the first element with the prefix indicating the number of atoms (except don’t use “mono-” if only 1 atom) Write the name of the second element with the prefix indicating the number of atoms (including “mono-”) and the suffix “ide”
90
PREFIXES USED IN MOLECULAR COMPOUNDS
Covalent Prefixes PREFIXES USED IN MOLECULAR COMPOUNDS mono di- tri- tetra- penta- hexa- hepta- octa- nona- deca-
91
Example #10 P2O5
92
P2O5 Diphosphorus pentaoxide Phosphorus Oxygen 2 = “di-” 5 = “penta-”
93
Example #11 SiF4
94
SiF4 Silicon tetrafluoride Silicon Fluorine
Don’t use “mono-” on first element Silicon SiF4 Fluorine 4 = “tetra-” “fluoride” Silicon tetrafluoride
95
Write the name for the following compounds
Self Check SO2 N2Cl4 P4O10 CO Example: Write the name for the following compounds
96
Write the name for the following compounds
Answers SO2 N2Cl4 P4O10 CO sulfur dioxide Dinitrogen tetrachloride Tetraphosphorus decaoxide Carbon monoxide Example: Write the name for the following compounds
98
Write the name for the following compounds
Mixed Practice: Determine the type of compound, Ionic (m/nm) or Covalent (nm/nm) & then follow rules Na2O K3PO4 Cu(OH)2 N2S MgCl2 Example: Write the name for the following compounds
99
Write the name for the following compounds
Answers Na2O K3PO4 Cu(OH)2 N2S MgCl2 Sodium oxide Potassium phosphate Copper (II) hydroxide Dinitrogen monosulfide Magnesium chloride Example: Write the name for the following compounds
100
Section 2.3—Writing Chemical Formulas
We need to be able to read the formulas for chemicals in the antacids!
101
Reminders from Section 2.2
Your Reference sheet has a list of: Common polyatomic ions Use your periodic table is used to determine the charges of common elements when they form ions You must memorize the 10 prefixes for covalent compounds
102
Binary Ionic Compounds
containing two elements—one metal and one non-metal formed by attraction between + and - ions + Cation - Anion Ionic Compound
103
How to Write Formulas for Binary Ionic Compounds
These compounds: End in “-ide” (except “hydroxide and cyanide”) Do NOT contain covalent prefixes To write these formulas: Write the symbol & charge of the first element (the metal, cation) Write the symbol & charge of the second element (the non-metal, anion) Add more of the cations and/or anions to have a neutral compound Use subscripts to show how many of each type of ion is there.
104
Example #1 Sodium chloride
105
Na+1 Cation Sodium chloride Anion Cl-1 NaCl
106
NaCl Example #1 Sodium chloride +1 + -1 = 0 Na+1Cl-1 Cation Anion Na+1
The compound is neutral…no subscripts are needed. Cl-1 NaCl
107
Example #2 Calcium bromide
108
Example #2 Ca+2 Cation Calcium bromide Anion Br-1
109
CaBr2 Example #2 Calcium bromide +2 + -1 = +1 Ca+2 Br-1 Cation Anion
Ca+2 Br-1 Br-1 Br-1 = 0 CaBr2 The subscript “2” is used to show that 2 anions are needed.
110
A Simple Method to Writing Binary Ionic Formulas
The Criss - Cross Method: Write the symbol & charge of the first element (the metal, cation) Write the symbol & charge of the second element (the non-metal, anion) Cross ONLY the charge numbers down diagonally to make subscripts IF they are not equal to each other Simplify subscripts if you can Ca +2 Br-1 Ca1Br2 CaBr2
111
Write the following chemical formulas
Self Check Cesium chloride Potassium oxide Calcium sulfide Lithium nitride Example: Write the following chemical formulas
112
Write the following chemical formulas
Answers Cesium chloride Potassium oxide Calcium sulfide Lithium nitride CsCl K2O CaS Li3N Example: Write the following chemical formulas
113
Ternary Ionic Compounds
compound containing at least one polyatomic ion Either in the front, the back or in both places + Cation - Polyatomic Anion Polyatomic Ionic Compound
114
How to Identify & Name Ternary Ionic Compounds
These compounds: Do not end with “-ide” (except hydroxide & cyanide) Do not use covalent prefixes To write these formulas: Write the symbol & charge of the cation & anion Add additional cations or anions to have a neutral compound Use subscripts to show the number of ions When using subscripts with a polyatomic ion, you must put the polyatomic ion in a parenthesis with the subscript on the outside
115
Example #3 Sodium carbonate
116
Na+1 Cation Sodium carbonate Polyatomic Anion CO3-2
117
Na2CO3 Sodium carbonate +1 + -2 = -1 Na1+ CO32- Cation Polyatomic
Anion Na+ Na+ CO32- = 0 CO3-2 Na2CO3 The subscript “2” is used to show that 2 cations are needed.
118
Example #4 Magnesium nitrate
119
Mg+2 Cation Magnesium nitrate Polyatomic Anion NO3-1
120
Mg(NO3)2 Mg+2 Magnesium nitrate Mg+2NO31- +2 + -1 = 1 NO3-1 Cation
Polyatomic Anion = 0 NO3-1 The subscript “2” is used to show that 2 anions are needed. Mg(NO3)2 Use parenthesis when adding subscripts to polyatomic ions
121
Write the following chemical formulas
Self Check Sodium nitrate Calcium chlorate Potassium sulfite Calcium hydroxide Example: Write the following chemical formulas
122
Write the following chemical formulas
Answers Sodium nitrate Calcium chlorate Potassium sulfite Calcium hydroxide NaNO3 Ca(ClO3)2 K2SO3 Ca(OH)2 Example: Write the following chemical formulas
123
Transition Metals metal that has more than one possibility for cationic charge
124
How to Identify & Name Ionic Compounds with Transition Metals
These compounds: Will have roman numerals To write these formulas: Same as binary ionic or polyatomic ionic. The roman numerals tell the charge of the metal (cation)
125
Example #5 Iron (III) oxide
126
Fe+3 Cation Iron (III) oxide Anion O-2
127
Fe2O3 +3 + -2 = -1 Iron (III) oxide O-2 Fe+3 Fe+3 O2- Cation Anion
Fe+3 Fe+3 O2- O2- Anion = 0 O-2 The subscript “2” and “3” are used to show the numbers of atoms needed. Fe2O3
128
Example #6 Copper (II) nitrate
129
Cu+2 Cation Copper (II) nitrate Polyatomic Anion NO3-1
130
Cu(NO3)2 +2 + -1 = 1 Copper (II) nitrate Cu+2 Cu+2 NO31- NO3-1 Cation
Polyatomic Anion = 0 NO3-1 Use parenthesis when adding subscripts to a polyatomic ion Cu(NO3)2
131
Write the following chemical formulas
Self Check Iron (II) nitrate Copper (I) chloride Lead (IV) hydroxide Tin (II) oxide Example: Write the following chemical formulas
132
Write the following chemical formulas
Answers Iron (II) nitrate Copper (I) chloride Lead (IV) hydroxide Tin (II) oxide Fe(NO3)2 CuCl Pb(OH)4 SnO Example: Write the following chemical formulas
133
Binary Covalent Compounds
compound made from two non-metals between atoms that share electrons Non metal Non metal Covalent compound
134
How to Identify & Name Binary Covalent Compounds
These compounds: Use covalent prefixes To write these formulas: Write the symbols of the first and second element Use the covalent prefixes (assume the first element is “1” if there’s no prefix) as the subscripts to show number of atoms. Atoms do not form charges when bonding covalently…you DO NOT need to worry about charges with this type! NOR CRISS CROSS METHOD!
135
Dinitrogen Tetraoxide
Example #7 Dinitrogen Tetraoxide
136
Dinitrogen Tetraoxide
N2O4
137
Example #8 Silicon dioxide
138
Silicon dioxide SiO2 “Di-” = 2 Si O
“Mono-” is not written for the first element Si Silicon dioxide O “Di-” = 2 SiO2
139
CAUTION!!! “di” and “bi” do not mean the same thing! di- bi-
Stands for “2” in covalent compounds Means there’s a hydrogen in the polyatomic anion Carbon dioxide = CO2 Sodium biphosphate = Na2HPO4
140
Write the following chemical formulas
Self Check Carbon monoxide Sulfur tetraiodide Trichlorine pentasulfide Example: Write the following chemical formulas
141
Write the following chemical formulas
Answers Carbon monoxide Sulfur tetraiodide Trichlorine pentasulfide CO SI4 Cl3S5 Example: Write the following chemical formulas
143
Self Check: Mixed Practice
Magnesium hydroxide Copper (II) nitrate Iron (III) oxide Nitrogen dioxide Sodium bicarbonate Example: Write the following chemical formulas
144
Write the following chemical formulas
Answers Magnesium hydroxide Copper (II) nitrate Iron (III) oxide Nitrogen dioxide Sodium bicarbonate Mg(OH)2 Cu(NO3)2 Fe2O3 NO2 NaHCO3 Example: Write the following chemical formulas
145
Section 2.4 We need to know how acids behave when talking about ant-acids!
146
What is an Acid? – Arrhenius Definition
A substance that produces hydrogen ions (H+1) when dissolved in water. H+1 immediately reacts with water to make the hydronium ion, H3O+1 H O water H O +1 H +1
147
How do Acids produce Hydronium?
- water acid Hydrogen cation with some anion
148
How do Acids produce Hydronium?
- +1 H O
149
How do Acids produce Hydronium?
- +1 H O Hydronium ion Anion
150
How to Identify an Acid H2SO4 HCl H2CO3 HNO3 HC2H3O2
Look for a hydrogen ion, “H+” as the first element in an aqueous covalent compound. H2SO4 HCl H2CO3 HNO3 HC2H3O2
151
Naming Binary Acids: Non-Oxygen Acids
These compounds have to : Start with “H” (more than 1 “H” is OK, too). Do not contain oxygen To name these compounds: Use “hydro____ic acid” Fill in the blank with the root of the anion’s name
153
Example #1 HBr(aq)
154
HBr(aq) Hydrobromic acid No oxygen Use “hydro___ic” Hydrogen cation
It’s an acid Hydrogen cation HBr(aq) Hydrobromic acid Bromine No oxygen Use “hydro___ic”
155
Naming Oxyacids: contain oxygen
These compounds have: Start with “H” (more than 1 “H” is OK, too). Must contain oxygen To name these compounds: Use “___ic acids” for “-ate” anions Use “___ous acids” for “-ite” anions Do not use “hydro” with these…the word “acid” is how you know it begins with hydrogen, not “hydro-”
157
Example #2 HNO2(aq)
158
HNO2(aq) Nitrous acid Use “___ous” acid Hydrogen cation nitrite ion
It’s an acid Hydrogen cation HNO2(aq) nitrite ion “-ite” ion Use “___ous” acid Nitrous acid
159
Example #3 HC2H3O2(aq)
160
HC2H3O2(aq) acetic acid Use “___ic” Hydrogen cation acetate ion
It’s an acid Hydrogen cation HC2H3O2(aq) acetate ion “-ate” ion Use “___ic” acetic acid
161
Write the name for the following acids
Self Check HF H2S H3PO4 Example: Write the name for the following acids
162
Write the name for the following acids
Answers HF H2S H3PO4 Hydrofluoric acid Hydrosulfuric acid Phosphoric acid Example: Write the name for the following acids
163
Writing the chemical formula for “Hydro-” acids
To write these formulas: Write the cation, H+1 Write the anion symbol and charge Balance the charges by adding the appropriate subscript to the hydrogen cation OR Criss Cross Method
164
Example #4 Hydrobromic acid
165
Does not contain oxygen
H+1 Hydrogen cation Hydrobromic acid Does not contain oxygen Br-1
166
Does not contain oxygen
H+1 Hydrogen cation Hydrobromic acid Does not contain oxygen H+1Br-1 Br-1 = 0 HBr The compound is neutral. Subscripts are not needed
167
Writing chemical formulas for “Oxyacids”
To write these formulas: Write the cation H+1 If it is an “-ic” acid, determine the polyatomic ion ending in “-ate” If it is an “-ous” acid, determine the polyatomic ion ending in “-ite” Add subscript to the hydrogen cation to balance charges OR use Criss Cross Method
168
Example #5 Carbonic acid
169
From the “___ate” anion
Hydrogen cation Carbonic acid From the “___ate” anion CO3-2
170
From the “___ate” anion
Hydrogen cation H+ CO32- = -1 Carbonic acid H+ H+ CO32- = 0 From the “___ate” anion CO3-2 H2CO3
171
Example #6 Chlorous acid
172
From the “___ite” anion
Hydrogen cation chlorous acid From the “___ite” anion ClO2-1
173
From the “___ite” anion
Hydrogen cation Chlorous acid H+ClO2-1 From the “___ite” anion ClO2-1 = 0 HClO2
174
Write the formula for the following acids
Self Check Phosphorous acid Hydroiodic acid Example: Write the formula for the following acids
175
Write the formula for the following acids
Answers Phosphorous acid Hydroiodic acid H3PO3 HI Example: Write the formula for the following acids
176
You Really Only Need to Know These Acids! Memorize them!
Hydrochloric acid HCl Sulfuric acid H2SO4 Carbonic acid H2CO3 Nitric acid HNO3 Acetic acid HC2H3O2
177
What is a Base? – Arrhenius Definition
A substance that produces hydroxide ions, OH-1 in water H2O NaOH(s) Na+1(aq) + OH-1(aq) H O water H O -1 +1 H Na O Na Hydroxide Ion
178
How to Identify a Base NaOH Ca(OH)2 NH3
Look for an ionic compound that has a metal paired with the hydroxide ion, “OH-” OR Look for the ammonia molecule NaOH Ca(OH)2 NH3 **Do not assume all compounds ending in OH are bases: CH3OH is not a base but an alcohol
179
Naming & Writing Formulas for Metal Hydroxides
Follow the rules for ionic compounds. The most common exception to this is ammonia, NH3 NH3 (ammonia) is a base even though it doesn’t contain “-OH” as the anion
180
Example #7 NaOH
181
Sodium NaOH Sodium Hydroxide Hydroxide
182
Write the formula or name for each
Self Check Ca(OH)2 KOH Copper (II) hydroxide Lithium hydroxide Example: Write the formula or name for each
183
Write the formula or name for each
Answers Ca(OH)2 KOH Copper (II) hydroxide Lithium hydroxide Calcium hydroxide Potassium hydroxide Cu(OH)2 LiOH Example: Write the formula or name for each
184
What is an Acid according to Bronsted-Lowry?
Is a substance that is a proton or hydrogen donor Example: HCl + H2O H3O+1 + Cl-1 acid base
185
What is a base according to Bronsted-Lowry?
Is a substance that is a proton acceptor Example: NH3 + H2O OH- + NH4+ base acid conjugate conjugate base acid
186
Conjugate Acid-Base Pairs
Conjugate Acid- substance formed when a base gains a [H+] ion. Conjugate Base- substance formed when an acid loses a [H+] ion. Label the acid & base on the left side of the reaction & the conjugate acid & conjugate base on the right side. a) HNO H2O H3O NO3− ______ ______ ______ ______ b) NH H2O NH OH− _____ ______ ______ ______ acid base C.A. C.B. base acid C.A. C.B.
187
Characteristics of Acids & Bases
Produce H3O+1 (hydronium ion) in water Produce OH-1 (hydroxide ion) in water Tastes sour Tastes Bitter React with active metals to form hydrogen gas Feels slippery Neutralizes a base to form salt and water Neutralizes an acid to form salt and water Both forms ions when dissolved: conducts electricity: They are called ELECTROLYTES
189
Strength versus Concentration
190
strong acid – ALL acid molecules separate (dissociate) into [H+] ions in water; only ions present
Examples: HCl, HNO3, H2SO4 weak acid – Most acid molecules stay together, only a FEW separate into [H+] ions when in water; few ions present, mostly molecules Examples: HC2H3O2 (vinegar) , H2CO3
191
Strong Acid Weak Acid
192
Strong versus Weak Acids
How many hydronium ion – anion pairs can you find? - + - 3 + How many intact acid molecules can you find? + - 1 Strong acid Most of the acid molecules have donated the H+1 to water
193
Strong versus Weak Acids
+ How many hydronium ion – anion pairs can you find? 1 How many intact acid molecules can you find? - 3 Weak acid Only a few of the acid molecules have donated the H+1 to water
194
Strong Acids vs. Weak Acids
195
Concentrated versus Dilute
solvent solute DILUTE (low concentration) Very little solute (what’s being dissolved) particles in solution CONCENTRATED (higher concentration) Lots of solute (what’s being dissolved) particles in solution
196
Combinations of Concentration & Strength
Concentrated Dilute Strong A lot of acid/base added & all dissociates Not much acid/base added, but all of what’s there dissociates Weak A lot of acid/base added, but little dissociates Not much acid/base added and very little dissociates
198
Bases Strength & Concentration
Bases follow the same pattern as acids A common misconception is acids are dangerous but bases are not! Vinegar is an acid we eat…some of them are safe! Sodium hydroxide is a very caustic base…not all of them are less harmful than acids! The stronger and acid or base is & the more concentrated it is), the more dangerous it is for you!
199
The Power of the Hydrogen: pH
The pH scale to measure the acidity of a sample
200
Ways to measure pH Indicators change color based on pH
Liquid indicators – phenolphthalein or bromothymol blue Bromothymol Blue: Acid: turns Yellow Base: turns blue Phenolphthalein: Acid: stays clear Base: turns pink pH meters or pH probes Electronically determine pH and give a read-out Acid Base
201
Ways to measure pH Indicators change color based on pH
Paper with a liquid indicator on it (pH paper or Litmus paper) pH paper turns a color which matches to a pH number LITMUS PAPER (Mnemomic: See board!) Blue Litmus stays blue in a base but turns pink in an acid Red Litmus stays red in an acid but turns blue in a base
Similar presentations
© 2024 SlidePlayer.com Inc.
All rights reserved.