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Chapter 2: Antacids.

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1 Chapter 2: Antacids

2 Antacids This chapter will introduce the chemistry needed to understand how antacids work Section 2.1: Types of Matter Section 2.2: Naming Chemicals Section 2.3: Writing Formulas Section 2.4: Acids & Bases Section 2.5: Chemical Reactions Section 2.6: Balancing Chemical Equations Section 2.7: Speeding up Chemical Reactions

3 Intro—Antacids

4 Why do we need antacids? Your body needs hydrochloric acid to digest food Too much causes heartburn, ulcers and can damage your esophagus

5 Antacids versus Acid Inhibitors
There are two types of medicines you can use Antacids Acid Inhibitors Neutralizes the acid currently in your system Controls the amount of acid your body produces Work quickly but your body will make more acid again Long-term solution, but needs to build up in your system to be most effective Alka-Seltzer ®, Rolaids ®, Tums ®, Malox ®, Mylanta ® Tagamat ®, Zantac ®, Pepcid AC ® Is it fair when a commercial compares the fast action of an antacid to an acid inhibitor that takes up to 7 days to build up?

6 Section 2.1—Types of Matter

7

8 Matter is…. Anything that has mass and takes up space (volume)
Anything made from atoms Examples: elements, molecules, cells, people, air, water, paper Non Examples: dreams, energy (light, heat), emotions

9 Pure Substances versus Mixtures
Matter is classified as either a pure substance or a mixture Pure Substances Mixtures Contain only 1 type of particle Elements or Compounds Contain 2 or more pure substances Homogeneous or Heterogeneous

10 Pure Substances Elements Compound
2 or more elements chemically bonded together to form molecules. Each is the same fixed ratio of elements. H2O, NaCl, CO2 Simplest kind of matter Made of only 1 kind of atom Cu, Ag, Fe, Br2

11 Elements can be found on the periodic table!
Single Atom Cannot be separated by chemical or physical processes Element Pure substance Every atom is the same Elements can be found on the periodic table!

12 Elements

13 Every molecule is the same
Compounds Single Molecule Made of more than one type of atom bonded together Compound Pure substance Every molecule is the same Can only be separated by chemical reactions

14

15 Physical combination of more than 1 type of pure substance
Mixtures More than 1 different type of matter Can be separated physically by Distillation Filtration Chromatography Mixture Not a pure substance Physical combination of more than 1 type of pure substance

16 Mixtures Homogeneous Heterogeneous (aka “solution”)
Mixtures can be classified as homogeneous or heterogeneous Homogeneous (aka “solution”) Heterogeneous It looks the same throughout; substances evenly dispersed Ex. salt water, alloys, clean air Different substances can be seen (chunks, bubbles, floaties, layers) Ex. salad dressing, fog, chocolate chip cookies, soil

17 Mixture possibilities
Mixtures can be any combination of solids, liquids and gases: Solid-solid: Medicine tablet Solid-gas: Pop Rocks candy Solid-liquid: Ice water Liquid-liquid: lemon water Gas-Liquid: Carbonated water Gas-Gas: Air

18 Homogeneous Mixtures Kool-Aid: sugar in water Brass: copper in zinc
Air: oxygen gas in nitrogen gas Milk: fat, proteins, sugar in water

19 Heterogeneous Mixtures
Oil in water Italian Salad Dressing Chicken Noodle Soup Fruit Salad

20 Classification of Matter

21 True Solutions, Colloids & Suspensions
Homogeneous Heterogeneous Heterogeneous True Solution Colloid Suspension SMALL particles don’t settle out and are too small to scatter light Ex: salt water, air, brass INTERMEDIATE particles don’t settle out but are large enough to scatter light: Ex: fog, foam, jello, paint LARGE particles that settle out over time Ex: oral medicines, italian dressing, paint Dissolved Particle Size Increases

22 True Solutions

23 vinegar and oil salad dressing
Suspensions vinegar and oil salad dressing

24 Particles Scattering Light
If the dissolved particles are large enough to scatter light, we say it exhibits the “Tyndall Effect” Solution Light passes through unchanged Colloids exhibit the Tyndall Effect Light is scattered by larger solute particles

25 Connect these concepts with Antacids
What type of matter do you think antacids are? Pure substance (Element or compound) Mixture (homogeneous or heterogeneous)

26 Connect these concepts with Antacids
Antacids are mixtures. They contain active & inactive ingredients What purposes could the inactive ingredients serve?

27 Connect these concepts with Antacids
Inactive ingredients might Add volume to make the pill able to be handled Add color and flavor Allow the tablet to be compressed and formed

28 Let’s Practice: Not in Notes
Example: Determine if each is element, compound, homogeneous or heterogeneous mixtures Tin can (Sn) Copper pipe (Cu) Concrete Carbon tetrachloride(CCl4) Sports drink

29 Let’s Practice Example:
Determine if each is element, compound, homogeneous or heterogeneous mixtures Tin Element Copper pipe Element Concrete Heterogeneous mix Carbon tetrachloride Compound Sports drink Homogenous mix

30 You Try! In Notes Example: Aluminum foil (Al)
Determine if each is element, compound, homogeneous or heterogeneous mixtures Aluminum foil (Al) Water (H2O) soda soil Carbon dioxide(CO2) Tap water

31 You Try! Example: Determine if each is element, compound, homogeneous or heterogeneous mixtures Aluminum foil (Al) Element Water (H2O) Compound Flat soda Homogeneous mix soil Heterogeneous mix Carbon dioxide(CO2) compound Tap water Homogeneous mix

32 The Science of Macaroni Salad

33 Section 2.2—Naming Chemicals
We need to be able to name the chemicals in the antacids!

34 The Language of Chemistry
Chemistry has a language all of its own Chemistry English Element Symbols Letters Chemical Formulas Words Chemical Equations Sentences Each element symbol starts with a capital letter

35 ELEMENTS: made of atoms
An atom consists of subatomic particles There are 3 subatomic particles: protons, electrons and neutrons Neutral atoms have the same number of protons and eletrons

36 IONS An atom or group of atoms with a charge.
The number of protons does not equal the number of electrons. WHY? Atoms can gain or lose electrons to acquire stability like a noble gas element.

37 The Periodic Table of Elements
Metals form cations NonMetals form anions H He Li Be B C N O F Ne Na Mg Al Si P S Cl Ar K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe Cs Ba Lu Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn Fr Ra Lr Rf Db Sg Bh Hs Mt Uun Uuu Uub Uut Metals Metalloids Non-metals

38 Monatomic Ions (formed from a single atom) Cations Positive charge
Cations Positive charge Metal atoms that lose electrons Group A (Representative metals/Type I ) The group # for metals in columns 1A, 2A, & 3A is equal to the charge of the cation Naming them: Take the element name and add the word ion

39 Monatomic Ions of Group A /Type I Metals
Group B

40 Group B (Transition/Type II Metals): have more than one charge
You should be familiar with the following transition metals with more than one charge. Fe+2 Fe+3 Sn+2 Sn+4 Pb+2 Pb+4 Co+2 Co+3 Cr Cr+3 Mn+2 Mn+3 Cu Cu+2 Naming them: Take the element name and place in parentheses the charge number as a roman numeral and add the word ion

41 Monatomic Ions of Transition/Type II Metals
+

42 Monatomic Ions (formed from a single atom) Cu+2, F-1
Anions Negative charge Nonmetals that gain electrons Group A (Representative nonmetals) Subtract the group # in columns 4A, 5A, 6A, and 7A from 8 to get the charge. Naming them: Drop the ending of the element and add –ide and then ion

43 You Try! Try These: Write the formula for each ion and name it.
 Calcium Chromium Chlorine Sulfur

44 You Try! Try These: Write the formula for each ion and name it.
 Calcium Ca+2 calcium ion Chromium Cr+2 chromium(II) ion Cr+3 chromium (III) ion Chlorine Cl-1 chloride ion Sulfur S-2 sulfide ion

45 Self Check Try These: Write the formula for each ion and name it.
 Aluminum Zinc Iron Phosphorus Al+3 Aluminum Ion Zn+2 Zinc ion Fe+2 Iron (II) ion or Fe+3 Iron (III) ion P-3 Phosphide ion

46 Binary Ionic Compounds
Binary Ionic Compound- compound containing 2 elements—one metal and one non-metal The atoms are held together by Ionic Bonds- bond formed by attraction between + ions and – ions Metal Nonmetal + Cation - Anion Ionic Compound

47 Metals & Non-Metals Ionic Bonds are between metals & non-metals H He
Li Be B C N O F Ne Na Mg Al Si P S Cl Ar K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe Cs Ba Lu Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn Fr Ra Lr Rf Db Sg Bh Hs Mt Uun Uuu Uub Uut Metals Metalloids Non-metals

48 How to Identify & Name a Binary Ionic Compound
Look for: 2 elements (“binary”) A type I metal & a non-metal (“ionic”) To name these compounds: Write the name of the type 1 metal (the cation) Write the name of the non-metal (the anion) with the suffix “-ide” The subscripts in the formula do not matter when naming this type

49 Example #1 NaCl

50 NaCl Sodium Chloride Cation Anion “Sodium”
“Chlorine” becomes “Chloride” Sodium Chloride

51 Example #2 CaBr2

52 CaBr2 Calcium Bromide Cation Anion “Calcium”
“Bromine” becomes “Bromide” Calcium Bromide

53 Example #3 K2O

54 “Potassium” Cation K2O Anion “Oxygen” becomes “Oxide” Potassium Oxide

55 Write the name for the following compounds
Self Check Li2O Sr3P2 MgS BaI2 Example: Write the name for the following compounds

56 Write the name for the following compounds
Answers Li2O Sr3P2 MgS BaI2 Lithium oxide Strontium phosphide Magnesium sulfide Barium iodide Example: Write the name for the following compounds

57 Ternary Ionic Compounds
Ternary Ionic Compound- a compound containing at least one polyatomic ion Polyatomic Ion- an ion that has more than one atom that together have a single charge - Polyatomic Anion + Cation Ternary Ionic Compound + Polyatomic Cation - Anion

58 Common Polyatomic Ions
You don’t need to memorize them. Look at your reference sheet. COMMON POLYATOMIC IONS Acetate, CH3COO-1 or C2H3O2-1 Ammonium NH4+1 Bromate, BrO3-1 Bromite, BrO2-1 Carbonate, CO3-2 Carbonite, CO2-2 Chlorate, ClO3-1 Chlorite, ClO2-1 Chromate, CrO4-2 Cyanide, CN-1 Dichromate, Cr2O7-2 Dihydrogen phosphate, H2PO4-1 Hydrogen carbonate or bicarbonate, HCO3-1 Hydrogen phosphate or biphosphate, HPO4-2 Hydrogen sulfate or bisulfate, HSO4-1 Hydroxide, OH-1 Hypochlorite, ClO-1 Iodate, IO3-1 Iodite, IO2-1 Nitrate, NO3-1 Nitrite, NO2-1 Oxalate, C2O4-2 Perchlorate, ClO4-1 Permanganate, MnO4-1 Peroxide, O2-2 Phosphate, PO4-3 Phosphite, PO3-3 Silicate, SiO3-1 Sulfate, SO4-2 Sulfite, SO3-2

59 Identifying Polyatomic Ions: Hints
The only cation (front-half) polyatomic ion is “NH4+” All other polyatomic ions are anions (back-half) The subscripts within the polyatomic ion are important (it must match exactly with the one on your ion list) If there are parentheses, the polyatomic ion is inside (ignore the number outside)

60 Practice Identifying Polyatomic Ions
NaNO3 NH4Cl Ca(OH)2 (NH4)3PO4 K2CO3 Example: Underline& name the polyatomic ion in each compound

61 Practice Identifying Polyatomic Ions
NaNO3 NH4Cl Ca(OH)2 (NH4)3PO4 K2CO3 Nitrate Ammonium Hydroxide Ammonium & phosphate Carbonate Example: Identify and name the polyatomic ion in each compound

62 How to Identify & Name Ternary Ionic Compounds
Look for: More than 2 capital letters next to one another (not starting with H) Contain at least 1 metal & 1 non-metal To name these compounds: Write the name of the cation (either the metal element name or “Ammonium” for “NH4+”) If the anion is a polyatomic ion, write the given polyatomic ion’s name If the anion is a single non-metal element, write its name with the suffix “-ide”

63 Example # 4 Ca(NO3)2

64 “Calcium” Cation Ca(NO3)2 Polyatomic Anion “Nitrate” Calcium Nitrate

65 Example #5 Na3PO4

66 “Sodium” Cation Na3PO4 Polyatomic Anion “phosphate” Sodium phosphate

67 Example # 6 K2CO3

68 K2CO3 Potassium carbonate Cation Polyatomic Anion “potassium”

69 Write the name for the following compounds
Self Check Ca(C2H3O2)2 Li2SO3 Ba(OH)2 (NH4)2S Example: Write the name for the following compounds

70 Write the name for the following compounds
Answers Ca(C2H3O2)2 Li2SO3 Ba(OH)2 (NH4)2S Calcium acetate Lithium sulfite Barium hydroxide Ammonium Sulfide Example: Write the name for the following compounds

71 Worksheet 1 (1-10 Answers) 1. Sodium sulfide 6. Silver chloride
2. Aluminum oxide 7. Boron nitride 8. Barium fluoride 3. Sodium chloride 4. Rubidium iodide 9. Strontium nitride 5. Zinc bromide 10. Magnesium chloride

72 Worksheet 2 (1-10 Answers) 1. copper(I) fluoride 6.chromium (VI) oxide
2. copper (II) fluoride 7. gold(I) bromide 8. nickel(II) oxide 3. chromium (III) oxide 9. vanadium(III) iodide 4. lead (II) iodide 10. tin(IV) oxide 5. lead (IV) chloride

73 Worksheet 3 (1-10 Answers) 1. vanadium(V) chlorate Gold(I) nitrate
7. iron(III) phosphite 2. rhenium(VI) sulfate 8. nickel(II) bromate 3. osmium(III) iodate 9. lead(IV) sulfide 10. Manganese (VII) dichromate 4. iridium(IV) phosphate 5. palladium(IV) sulfite

74 Worksheet 4 (1-10 Answers) 1. ammonium chloride 6. ammonium nitrate
2. hydrogen chlorite 7. strontium phosphate 8. zinc chlorate 3. calcium bromate 4. beryllium sulfate 9. silver iodate 5. ammonium nitride 10. potassium dichromate

75 Transition Metals Revisisted
Transition Metal- group “B” or Type II metal that has the possibility of having more than one cation charge; Common multivalent metals and their charges Cobalt Co Co+3 Copper Cu Cu+2 Iron Fe Fe+3 Manganese Mn+2 Mn+3 Mercury Hg2+2 Hg+2 IMPORTANT: Although group B metals, SILVER (+1), CADMIUM (+2), and ZINC (+2) only have 1 charge Although the elements of TIN and LEAD are group A elements, they do have more than one charge Sn(+2 and +4) and Pb(+2 and +4)

76 How to Identify & Name Ionic Compounds with Transition Metals
Look for: One of the transition metals, excluding Ag, Cd, and Zn To name these compounds: Write the name of the Type II metal element (cation) Write the name of the anion (element name with “-ide” or polyatomic ion name) Determine the charge of the transition metal 1. Total negative charge = total positive charge for all neutral compounds 2. Divide total positive charge by the number of metal atoms 3. Write the charge in roman numerals in parentheses after the Type II metal’s name

77 Example # 7 CuCl

78 CuCl Copper Chloride Cation Anion “Copper”
“Chlorine” becomes “Chloride”

79 CuCl (I) Copper Chloride Cation Anion “Copper”
Chloride has a –1 charge CuCl -1 charge * 1 ion = -1 A –1 charge needs a +1 charge Anion “Chlorine” becomes “Chloride” Therefore, copper must be +1, (I) Copper Chloride (I)

80 Example # 8 Fe2(CO3)3

81 “Iron” Cation Fe2(CO3)3 Iron carbonate Polyatomic Anion “Carbonate”

82 Fe2(CO3)3 Iron carbonate (III) Cation Polyatomic Anion “Iron”
Carbonate has a –2 charge Fe2(CO3)3 -2 charge * 3 ions = -6 A –6 charge needs a +6 charge and there are 2 iron ions Polyatomic Anion “Carbonate” Therefore, iron must be +3 (III) Iron carbonate (III)

83 Example # 9 ZnBr2

84 “Zinc” Cation ZnBr2 Zinc bromide monatomic Anion “bromide”

85 ZnBr2 Zinc bromide Cation Polyatomic Anion “Zinc”
bromide has a –1 charge ZnBr2 -1 charge * 2 ions = -2 A –2 charge needs a +2 charge and there is 1 zinc ion Polyatomic Anion “bromide” Therefore, zinc must be +2 (not needed) it only has one charge Zinc bromide

86 Write the name for the following compounds
Self Check PbCl2 PbCl4 MnO Mn2O3 Example: Write the name for the following compounds

87 Write the name for the following compounds
Answers PbCl2 PbCl4 MnO Mn2O3 Lead (II) chloride Lead (IV) chloride Manganese (II) oxide Manganese (III) oxide Example: Write the name for the following compounds

88 Binary Covalent (Molecular) Compounds
Binary Molecular Compounds are made from two non-metals that are covalently bonded Covalent bond a bond formed from atoms that share electrons Non metal Non metal Covalent compound

89 Identifying & Naming Binary Molecular
These compounds have: 2 elements (“binary”) Both non-metals (“covalent”) To name these compounds: Write the name of the first element with the prefix indicating the number of atoms (except don’t use “mono-” if only 1 atom) Write the name of the second element with the prefix indicating the number of atoms (including “mono-”) and the suffix “ide”

90 PREFIXES USED IN MOLECULAR COMPOUNDS
Covalent Prefixes PREFIXES USED IN MOLECULAR COMPOUNDS mono di- tri- tetra- penta- hexa- hepta- octa- nona- deca-

91 Example #10 P2O5

92 P2O5 Diphosphorus pentaoxide Phosphorus Oxygen 2 = “di-” 5 = “penta-”

93 Example #11 SiF4

94 SiF4 Silicon tetrafluoride Silicon Fluorine
Don’t use “mono-” on first element Silicon SiF4 Fluorine 4 = “tetra-” “fluoride” Silicon tetrafluoride

95 Write the name for the following compounds
Self Check SO2 N2Cl4 P4O10 CO Example: Write the name for the following compounds

96 Write the name for the following compounds
Answers SO2 N2Cl4 P4O10 CO sulfur dioxide Dinitrogen tetrachloride Tetraphosphorus decaoxide Carbon monoxide Example: Write the name for the following compounds

97

98 Write the name for the following compounds
Mixed Practice: Determine the type of compound, Ionic (m/nm) or Covalent (nm/nm) & then follow rules Na2O K3PO4 Cu(OH)2 N2S MgCl2 Example: Write the name for the following compounds

99 Write the name for the following compounds
Answers Na2O K3PO4 Cu(OH)2 N2S MgCl2 Sodium oxide Potassium phosphate Copper (II) hydroxide Dinitrogen monosulfide Magnesium chloride Example: Write the name for the following compounds

100 Section 2.3—Writing Chemical Formulas
We need to be able to read the formulas for chemicals in the antacids!

101 Reminders from Section 2.2
Your Reference sheet has a list of: Common polyatomic ions Use your periodic table is used to determine the charges of common elements when they form ions You must memorize the 10 prefixes for covalent compounds

102 Binary Ionic Compounds
containing two elements—one metal and one non-metal formed by attraction between + and - ions + Cation - Anion Ionic Compound

103 How to Write Formulas for Binary Ionic Compounds
These compounds: End in “-ide” (except “hydroxide and cyanide”) Do NOT contain covalent prefixes To write these formulas: Write the symbol & charge of the first element (the metal, cation) Write the symbol & charge of the second element (the non-metal, anion) Add more of the cations and/or anions to have a neutral compound Use subscripts to show how many of each type of ion is there.

104 Example #1 Sodium chloride

105 Na+1 Cation Sodium chloride Anion Cl-1 NaCl

106 NaCl Example #1 Sodium chloride +1 + -1 = 0 Na+1Cl-1 Cation Anion Na+1
The compound is neutral…no subscripts are needed. Cl-1 NaCl

107 Example #2 Calcium bromide

108 Example #2 Ca+2 Cation Calcium bromide Anion Br-1

109 CaBr2 Example #2 Calcium bromide +2 + -1 = +1 Ca+2 Br-1 Cation Anion
Ca+2 Br-1 Br-1 Br-1 = 0 CaBr2 The subscript “2” is used to show that 2 anions are needed.

110 A Simple Method to Writing Binary Ionic Formulas
The Criss - Cross Method: Write the symbol & charge of the first element (the metal, cation) Write the symbol & charge of the second element (the non-metal, anion) Cross ONLY the charge numbers down diagonally to make subscripts IF they are not equal to each other Simplify subscripts if you can Ca +2 Br-1  Ca1Br2  CaBr2

111 Write the following chemical formulas
Self Check Cesium chloride Potassium oxide Calcium sulfide Lithium nitride Example: Write the following chemical formulas

112 Write the following chemical formulas
Answers Cesium chloride Potassium oxide Calcium sulfide Lithium nitride CsCl K2O CaS Li3N Example: Write the following chemical formulas

113 Ternary Ionic Compounds
compound containing at least one polyatomic ion Either in the front, the back or in both places + Cation - Polyatomic Anion Polyatomic Ionic Compound

114 How to Identify & Name Ternary Ionic Compounds
These compounds: Do not end with “-ide” (except hydroxide & cyanide) Do not use covalent prefixes To write these formulas: Write the symbol & charge of the cation & anion Add additional cations or anions to have a neutral compound Use subscripts to show the number of ions When using subscripts with a polyatomic ion, you must put the polyatomic ion in a parenthesis with the subscript on the outside

115 Example #3 Sodium carbonate

116 Na+1 Cation Sodium carbonate Polyatomic Anion CO3-2

117 Na2CO3 Sodium carbonate +1 + -2 = -1 Na1+ CO32- Cation Polyatomic
Anion Na+ Na+ CO32- = 0 CO3-2 Na2CO3 The subscript “2” is used to show that 2 cations are needed.

118 Example #4 Magnesium nitrate

119 Mg+2 Cation Magnesium nitrate Polyatomic Anion NO3-1

120 Mg(NO3)2 Mg+2 Magnesium nitrate Mg+2NO31- +2 + -1 = 1 NO3-1 Cation
Polyatomic Anion = 0 NO3-1 The subscript “2” is used to show that 2 anions are needed. Mg(NO3)2 Use parenthesis when adding subscripts to polyatomic ions

121 Write the following chemical formulas
Self Check Sodium nitrate Calcium chlorate Potassium sulfite Calcium hydroxide Example: Write the following chemical formulas

122 Write the following chemical formulas
Answers Sodium nitrate Calcium chlorate Potassium sulfite Calcium hydroxide NaNO3 Ca(ClO3)2 K2SO3 Ca(OH)2 Example: Write the following chemical formulas

123 Transition Metals metal that has more than one possibility for cationic charge

124 How to Identify & Name Ionic Compounds with Transition Metals
These compounds: Will have roman numerals To write these formulas: Same as binary ionic or polyatomic ionic. The roman numerals tell the charge of the metal (cation)

125 Example #5 Iron (III) oxide

126 Fe+3 Cation Iron (III) oxide Anion O-2

127 Fe2O3 +3 + -2 = -1 Iron (III) oxide O-2 Fe+3 Fe+3 O2- Cation Anion
Fe+3 Fe+3 O2- O2- Anion = 0 O-2 The subscript “2” and “3” are used to show the numbers of atoms needed. Fe2O3

128 Example #6 Copper (II) nitrate

129 Cu+2 Cation Copper (II) nitrate Polyatomic Anion NO3-1

130 Cu(NO3)2 +2 + -1 = 1 Copper (II) nitrate Cu+2 Cu+2 NO31- NO3-1 Cation
Polyatomic Anion = 0 NO3-1 Use parenthesis when adding subscripts to a polyatomic ion Cu(NO3)2

131 Write the following chemical formulas
Self Check Iron (II) nitrate Copper (I) chloride Lead (IV) hydroxide Tin (II) oxide Example: Write the following chemical formulas

132 Write the following chemical formulas
Answers Iron (II) nitrate Copper (I) chloride Lead (IV) hydroxide Tin (II) oxide Fe(NO3)2 CuCl Pb(OH)4 SnO Example: Write the following chemical formulas

133 Binary Covalent Compounds
compound made from two non-metals between atoms that share electrons Non metal Non metal Covalent compound

134 How to Identify & Name Binary Covalent Compounds
These compounds: Use covalent prefixes To write these formulas: Write the symbols of the first and second element Use the covalent prefixes (assume the first element is “1” if there’s no prefix) as the subscripts to show number of atoms. Atoms do not form charges when bonding covalently…you DO NOT need to worry about charges with this type! NOR CRISS CROSS METHOD!

135 Dinitrogen Tetraoxide
Example #7 Dinitrogen Tetraoxide

136 Dinitrogen Tetraoxide
N2O4

137 Example #8 Silicon dioxide

138 Silicon dioxide SiO2 “Di-” = 2 Si O
“Mono-” is not written for the first element Si Silicon dioxide O “Di-” = 2 SiO2

139 CAUTION!!! “di” and “bi” do not mean the same thing! di- bi-
Stands for “2” in covalent compounds Means there’s a hydrogen in the polyatomic anion Carbon dioxide = CO2 Sodium biphosphate = Na2HPO4

140 Write the following chemical formulas
Self Check Carbon monoxide Sulfur tetraiodide Trichlorine pentasulfide Example: Write the following chemical formulas

141 Write the following chemical formulas
Answers Carbon monoxide Sulfur tetraiodide Trichlorine pentasulfide CO SI4 Cl3S5 Example: Write the following chemical formulas

142

143 Self Check: Mixed Practice
Magnesium hydroxide Copper (II) nitrate Iron (III) oxide Nitrogen dioxide Sodium bicarbonate Example: Write the following chemical formulas

144 Write the following chemical formulas
Answers Magnesium hydroxide Copper (II) nitrate Iron (III) oxide Nitrogen dioxide Sodium bicarbonate Mg(OH)2 Cu(NO3)2 Fe2O3 NO2 NaHCO3 Example: Write the following chemical formulas

145 Section 2.4 We need to know how acids behave when talking about ant-acids!

146 What is an Acid? – Arrhenius Definition
A substance that produces hydrogen ions (H+1) when dissolved in water. H+1 immediately reacts with water to make the hydronium ion, H3O+1 H O water H O +1 H +1

147 How do Acids produce Hydronium?
- water acid Hydrogen cation with some anion

148 How do Acids produce Hydronium?
- +1 H O

149 How do Acids produce Hydronium?
- +1 H O Hydronium ion Anion

150 How to Identify an Acid H2SO4 HCl H2CO3 HNO3 HC2H3O2
Look for a hydrogen ion, “H+” as the first element in an aqueous covalent compound. H2SO4 HCl H2CO3 HNO3 HC2H3O2

151 Naming Binary Acids: Non-Oxygen Acids
These compounds have to : Start with “H” (more than 1 “H” is OK, too). Do not contain oxygen To name these compounds: Use “hydro____ic acid” Fill in the blank with the root of the anion’s name

152

153 Example #1 HBr(aq)

154 HBr(aq) Hydrobromic acid No oxygen Use “hydro___ic” Hydrogen cation
It’s an acid Hydrogen cation HBr(aq) Hydrobromic acid Bromine No oxygen Use “hydro___ic”

155 Naming Oxyacids: contain oxygen
These compounds have: Start with “H” (more than 1 “H” is OK, too). Must contain oxygen To name these compounds: Use “___ic acids” for “-ate” anions Use “___ous acids” for “-ite” anions Do not use “hydro” with these…the word “acid” is how you know it begins with hydrogen, not “hydro-”

156

157 Example #2 HNO2(aq)

158 HNO2(aq) Nitrous acid Use “___ous” acid Hydrogen cation nitrite ion
It’s an acid Hydrogen cation HNO2(aq) nitrite ion “-ite” ion Use “___ous” acid Nitrous acid

159 Example #3 HC2H3O2(aq)

160 HC2H3O2(aq) acetic acid Use “___ic” Hydrogen cation acetate ion
It’s an acid Hydrogen cation HC2H3O2(aq) acetate ion “-ate” ion Use “___ic” acetic acid

161 Write the name for the following acids
Self Check HF H2S H3PO4 Example: Write the name for the following acids

162 Write the name for the following acids
Answers HF H2S H3PO4 Hydrofluoric acid Hydrosulfuric acid Phosphoric acid Example: Write the name for the following acids

163 Writing the chemical formula for “Hydro-” acids
To write these formulas: Write the cation, H+1 Write the anion symbol and charge Balance the charges by adding the appropriate subscript to the hydrogen cation OR Criss Cross Method

164 Example #4 Hydrobromic acid

165 Does not contain oxygen
H+1 Hydrogen cation Hydrobromic acid Does not contain oxygen Br-1

166 Does not contain oxygen
H+1 Hydrogen cation Hydrobromic acid Does not contain oxygen H+1Br-1 Br-1 = 0 HBr The compound is neutral. Subscripts are not needed

167 Writing chemical formulas for “Oxyacids”
To write these formulas: Write the cation H+1 If it is an “-ic” acid, determine the polyatomic ion ending in “-ate” If it is an “-ous” acid, determine the polyatomic ion ending in “-ite” Add subscript to the hydrogen cation to balance charges OR use Criss Cross Method

168 Example #5 Carbonic acid

169 From the “___ate” anion
Hydrogen cation Carbonic acid From the “___ate” anion CO3-2

170 From the “___ate” anion
Hydrogen cation H+ CO32- = -1 Carbonic acid H+ H+ CO32- = 0 From the “___ate” anion CO3-2 H2CO3

171 Example #6 Chlorous acid

172 From the “___ite” anion
Hydrogen cation chlorous acid From the “___ite” anion ClO2-1

173 From the “___ite” anion
Hydrogen cation Chlorous acid H+ClO2-1 From the “___ite” anion ClO2-1 = 0 HClO2

174 Write the formula for the following acids
Self Check Phosphorous acid Hydroiodic acid Example: Write the formula for the following acids

175 Write the formula for the following acids
Answers Phosphorous acid Hydroiodic acid H3PO3 HI Example: Write the formula for the following acids

176 You Really Only Need to Know These Acids! Memorize them!
Hydrochloric acid HCl Sulfuric acid H2SO4 Carbonic acid H2CO3 Nitric acid HNO3 Acetic acid HC2H3O2

177 What is a Base? – Arrhenius Definition
A substance that produces hydroxide ions, OH-1 in water H2O NaOH(s) Na+1(aq) + OH-1(aq) H O water H O -1 +1 H Na O Na Hydroxide Ion

178 How to Identify a Base NaOH Ca(OH)2 NH3
Look for an ionic compound that has a metal paired with the hydroxide ion, “OH-” OR Look for the ammonia molecule NaOH Ca(OH)2 NH3 **Do not assume all compounds ending in OH are bases: CH3OH is not a base but an alcohol

179 Naming & Writing Formulas for Metal Hydroxides
Follow the rules for ionic compounds. The most common exception to this is ammonia, NH3 NH3 (ammonia) is a base even though it doesn’t contain “-OH” as the anion

180 Example #7 NaOH

181 Sodium NaOH Sodium Hydroxide Hydroxide

182 Write the formula or name for each
Self Check Ca(OH)2 KOH Copper (II) hydroxide Lithium hydroxide Example: Write the formula or name for each

183 Write the formula or name for each
Answers Ca(OH)2 KOH Copper (II) hydroxide Lithium hydroxide Calcium hydroxide Potassium hydroxide Cu(OH)2 LiOH Example: Write the formula or name for each

184 What is an Acid according to Bronsted-Lowry?
Is a substance that is a proton or hydrogen donor Example: HCl + H2O  H3O+1 + Cl-1 acid base

185 What is a base according to Bronsted-Lowry?
Is a substance that is a proton acceptor Example: NH3 + H2O  OH- + NH4+ base acid conjugate conjugate base acid

186 Conjugate Acid-Base Pairs
Conjugate Acid- substance formed when a base gains a [H+] ion. Conjugate Base- substance formed when an acid loses a [H+] ion. Label the acid & base on the left side of the reaction & the conjugate acid & conjugate base on the right side. a) HNO H2O  H3O NO3− ______ ______ ______ ______ b) NH H2O  NH OH− _____ ______ ______ ______ acid base C.A. C.B. base acid C.A. C.B.

187 Characteristics of Acids & Bases
Produce H3O+1 (hydronium ion) in water Produce OH-1 (hydroxide ion) in water Tastes sour Tastes Bitter React with active metals to form hydrogen gas Feels slippery Neutralizes a base to form salt and water Neutralizes an acid to form salt and water Both forms ions when dissolved: conducts electricity: They are called ELECTROLYTES

188

189 Strength versus Concentration

190 strong acid – ALL acid molecules separate (dissociate) into [H+] ions in water; only ions present
Examples: HCl, HNO3, H2SO4 weak acid – Most acid molecules stay together, only a FEW separate into [H+] ions when in water; few ions present, mostly molecules Examples: HC2H3O2 (vinegar) , H2CO3

191 Strong Acid Weak Acid

192 Strong versus Weak Acids
How many hydronium ion – anion pairs can you find? - + - 3 + How many intact acid molecules can you find? + - 1 Strong acid Most of the acid molecules have donated the H+1 to water

193 Strong versus Weak Acids
+ How many hydronium ion – anion pairs can you find? 1 How many intact acid molecules can you find? - 3 Weak acid Only a few of the acid molecules have donated the H+1 to water

194 Strong Acids vs. Weak Acids

195 Concentrated versus Dilute
solvent solute DILUTE (low concentration) Very little solute (what’s being dissolved) particles in solution CONCENTRATED (higher concentration) Lots of solute (what’s being dissolved) particles in solution

196 Combinations of Concentration & Strength
Concentrated Dilute Strong A lot of acid/base added & all dissociates Not much acid/base added, but all of what’s there dissociates Weak A lot of acid/base added, but little dissociates Not much acid/base added and very little dissociates

197

198 Bases Strength & Concentration
Bases follow the same pattern as acids A common misconception is acids are dangerous but bases are not! Vinegar is an acid we eat…some of them are safe! Sodium hydroxide is a very caustic base…not all of them are less harmful than acids! The stronger and acid or base is & the more concentrated it is), the more dangerous it is for you!

199 The Power of the Hydrogen: pH
The pH scale to measure the acidity of a sample

200 Ways to measure pH Indicators change color based on pH
Liquid indicators – phenolphthalein or bromothymol blue Bromothymol Blue: Acid: turns Yellow Base: turns blue Phenolphthalein: Acid: stays clear Base: turns pink pH meters or pH probes Electronically determine pH and give a read-out Acid Base

201 Ways to measure pH Indicators change color based on pH
Paper with a liquid indicator on it (pH paper or Litmus paper) pH paper turns a color which matches to a pH number LITMUS PAPER (Mnemomic: See board!) Blue Litmus stays blue in a base but turns pink in an acid Red Litmus stays red in an acid but turns blue in a base

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