12AlkenesHydrocarbons containing carbon to carbon double bonds
13Saturated vs. Unsaturated Saturated – organic compound in which all carbon atoms are joined by single covalent bonds, contains the maximum number of hydrogen compoundsUnsaturated – organic compound with one or more double or triple carbon-carbon bonds
14AlkynesHydrocarbon containing carbon to carbon triple bonds
15Ch 25.3 IsomerismIsomer – same molecular formula, different structural formula
27The graph below shows the relationship between boiling point and molar mass at standard pressure for pentane, hexane, heptane, and nonane.Octane has a molar mass of 114 grams per mole. According to this graph, what is the boiling point of octane at standard pressure?State the relationship between molar mass and the strength of intermolecular forces for the selected alkanes.
28Allow 1 credit. Acceptable responses include, but are not limited to: Allow 1 credit for 124°C ± 2°C.Allow 1 credit. Acceptable responses include, but are not limited to:As molar mass increases, there are stronger intermolecular forces.The forces are greater between heavier molecules.
29The compound 1,2-ethanediol can be mixed with water The compound 1,2-ethanediol can be mixed with water. This mixture is added to automobile radiators as an engine coolant. The cooling system of a small van contains 6690 grams of 1,2-ethanediol. Some properties of water and 1,2-ethanediol are given in the table below.Identify the class of organic compounds to which 1,2-ethanediol belongs.State, in terms of molecular polarity, why 1,2-ethanediol is soluble in water.In the space in your answer booklet, calculate the total number of moles of 1, 2-ethanediol in the small van’s cooling system. Your response must include both a correct numerical setup and the calculated result.
30Acceptable responses include, but are not limited to: Allow 1 credit. Acceptable responses include, but are not limited to: alcoholAcceptable responses include, but are not limited to:Water and 1,2-ethanediol molecules are both polar.Both molecules have similar polarity.• Allow 1 credit for a correct numerical setup. Acceptable responses include, but are not limited to:• Allow 1 credit for 108 mol or for a response consistent with the student’s numerical setup.
31A gasoline engine burns gasoline in the presence of excess oxygen to form carbon dioxide and water. The main components of gasoline are isomers of octane. A structural formula of octane is shown below.One isomer of octane is 2,2,4-trimethylpentane.In the space in your answer booklet, draw a structural formula for 2,2,4-trimethylpentane. Explain, in terms of the arrangement of particles, why the entropy of gasoline vapor is greater than the entropy of liquid gasoline.
32The arrangement of molecules in the vapor state are more random or disordered. Particles in the vapor state are farther apart and move more freely.
33Chapter 26 Functional Groups Halide (Halocarbons)AlcoholsEthersAldehydesKetonesCarboxylic AcidsEsters
34Halide (Halocarbons)Organic compounds covalently bonded with fluorine, chlorine, bromine, or iodineNaming: number – halide prefix – name1- ChlorohexaneR – X (X = any halogen)
35Alcohols Organic compounds with an –OH group - OH group = Hydroxyl groupNaming: number – name – ol ending2 - butanol
36Primary, Secondary, Tertiary Alcohols Primary Alcohol – only 1 carbon attached to the primary C – OHR – CH2 – OHSecondary Alcohol – 2 carbons attached to the primary C – OHR – CH – OHRTertiary Alcohol – 3 carbons attached to the primary C – OHR – C – OH
37Ethers Organic compound in which oxygen is bonded to two carbon groups R – O –RNaming: name each group on each side of the oxygen, then use alphabetical order and ends with etherCH3CH2OCH3Ethyl methyl ether
38AldehydesOrganic compound in which the carbon of the carbonyl group is bonded with at least one hydrogenR-CH-ONaming: name the longest chain, drop the e ending, add alH – C = OHMethanal
39KetonesOrganic compound in which the carbon of the carbonyl group is bonded to two other carbonsR – C =ORNaming: Naming: name the longest chain, drop the e ending, add one
40Carboxylic Acids Organic compound with a carboxyl group R – C =O OH Naming: Drop the e add oic acidRCOOH
41Esters Carboxylic acid with the OH replaced by an OR R – C = O O – R Naming: drop the e, add oate
42Dehydration Synthesis The linking of two organic compounds by removing water from functional groups.
43Etherification a) requires 2 alcohols b) H2SO4 is the dehydrating agent. It removes H from one alcohol molecule and OH from the other to form H2O.
44Esterification a) requires an alcohol and a carboxylic acid b) forms an ester, named for the alcohol and acid that formed it.
46FermentationFermentation of glucose or fructose in corn, barley, grapes, apples, etc. forms ethanol:The reaction proceeds until the alcohol content reaches 13%, at which point the yeast dies. Further increases in concentration may be yielded by distillation. Used in alcoholic beverages where, in the synthesis of acetic acid (by catalytic oxidation) and it is used as a solvent.
47Saponification The production of soap. a) Requires a glycerol ester (fat) and sodium hydroxide (strong base)b) The glycerol ester is dissolved in ethanol, and the NaOH is mixed in.c) The mixture is heated slowly until it thickens.d) The alcohol solvent is now evaporated off.e) The resultant mixture is glycerol plus the sodium salts of the long-chain acids. The salts represents the soap.f) The salts may be precipitated out of the glycerol by adding NaCl and filtering out the glycerol. The resulting lump is soap.
49PolymerizationPOLYMER - an extremely large molecule made by connecting many smaller molecules together. The basic molecules used as "building blocks" of the polymer are called monomers.Monomer molecule = Apolymerization18 A -> A-A-A-A-A-A-A-A-A-A-A-A-A-A-A-A-A-ACan be abbreviated as 18 A -(-A-)-18, which represents a chain of A monomers 18 units long.
50Types of Polymers:1) Addition Polymers - formed by addition polymerization reaction: the monomer’s double bond opens, allowingthe monomer units to join end to end. The name of the polymer is found by putting a “poly” in front of the monomer’sname. For example, propylene monomer forms polypropylene.
51Polyvinyl Chloride1. Formed from Vinyl Chloride monomer (chloro ethane)2. The double bond breaks, and VC monomer units join end to end.3. Used for water pipes, record albums, raincoats, shower curtains, wire insulation, vinyl siding
53Polystyrene1. Formed from styrene monomer (phenyl ethane, basically ethene with a benzene attached to it)2. The double bond breaks, and styrene monomer units join together.3. Used for plastic model kits, styrofoam
55Polytetrafluoroethene (teflon) 1. Formed from tetraflouro ethene monomer2. The double bond breaks, and TFE monomer units join together.3. Used for no-stick pans.4. Accidentally discovered in 1938 by Roy Plunkett.
57Types of Polymers:2) Condensation Polymers - formed by dehydration synthesis of difunctional monomer units. H and OH are removedfrom the ends of the monomer units, allowing them to join together. Water is given off as a byproduct.
58Polyester1. Formed from monomer units that have an alcohol functional group on one end and a carboxylic acid functionalgroup on the other end.2. The opposing ends undergo dehydration synthesis, and form the polymer.
60Types of Polymers: 3) Rubber a) cis- Polyisoprene (tires), polybutadiene (tires), polychloropropene (Neoprene...wire covering, automotive drive belts,wetsuit material)), Nitrile (automotive hoses and gaskets)1. Formed by addition polymerization2. The resultant macromolecule is tacky and not very strong. It generally has a low melting point.3. In order to make this stuff serviceable, it must by toughened up. This is done by a process whereby the polymer chains are cross-linked with sulfur. This toughens up the rubber. This process was discovered accidentally by Charles Goodyear in This process is called vulcanization.Unfortunately, when heat is applied to rubber so treated, it does not melt, but burns, releasing CO, CO2 and SO2.