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Published byMolly Fitzgerald Modified over 9 years ago
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Solutions
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Types of Mixtures Heterogeneous – unevenly mixed Homogeneous – evenly mixed
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Solution Components Solute – what is being dissolved Solvent – what is doing the dissolving May be combinations of gases, liquids, and solids
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Suspensions Particles of solute are too large to stay in solution and settle out unless constantly mixed
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Colloids Particles of solute are small enough to be kept moving by the motion of the solvent particles but big enough to scatter light EX – fog, mayonnaise Tyndall effect
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Electrolytes vs. Nonelectrolytes Electrolytes dissociate in solution and conduct an electric current Non-electrolytes do not
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Factors Affecting Rate of Solution 1. Temperature 2. Stirring 3. Increasing surface area clip
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The Solution Process
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Factors Affecting the Rate of Dissolution Increasing surface area Agitating the solution (stirring) Heating the solvent
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Solubility There is a limit to how much solute will dissolve in a given amount of solvent As more solute is added, there is a greater likelihood that solute molecules/ions will collide and recrystalize Solution equilibrium – the physical state in which the opposing processes of dissolution and crystallization of a solute occur at equal rates
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Unsaturated vs Saturated A solution that contains the maximum amount of dissolved solute is said to be SATURATED A solution that contains less solute than a saturated solution under the same conditions is said to be UNSATURATED
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Supersaturated Solutions A solution that contains more dissolved solute than a saturated solution contains under the same conditions is said to be SUPERSATURATED
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Solubility Values The amount of a substance required to form a saturated solution with a specific solvent at a given temperature
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“Like Dissolves Like” Polar solvents can dissolve ionic or polar compounds Non-polar solvents can dissolve non-polar compounds Depends on bonding and intermolecular forces between solvent and solute
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Liquid Solutes & Solvents Oil and water are said to be IMMISCIBLE because they cannot dissolve in each other Liquids that can dissolve each other are said to be MISCIBLE (benzene/carbon tetrachloride or oil/gas)
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Pressure Effects on Solubility Effects mainly gasses As pressure increases solubility increases Henry’s Law – the solubility of a gas in a liquid is directly proportional to the partial pressure of that gas on the surface of the liquid
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Temperature Effects on Solubility In general, as temperature increases solubility of solids increase As temperature increases solubility of gases decreases
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Heats of Solution Change in the amount of heat generated as a solute is SOLVATED (surrounded by solvent molecules) If ΔH greater than start endothermic If ΔH less than start exothermic
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