1. EU Seveso II Directive 96/82/EC Named substances & Categories of substances 2.3 Activity workshop Angeliki Tsatsou Dritsa Chemist TA Key Expert 2 Zagreb 16-17 June 2011

2. EU Seveso II Scope I Scope: establishments where dangerous substances are present in excess of some specific quantity thresholds Establishments: the whole area under the control of the Operator where dangerous substances are present Operator: operates/holds the establishment or has decisive economic & executive power in technical operation

3. EU Seveso II Scope II Presence of substance: actual, or anticipated or may generated during loss of control in an industrial process (raw material, product, by product, residue, intermediate, or those to be generated in an accident) Dangerous substance: a substance or mixture or preparation listed in Annex I of Seveso II

4. Named substances Annex I Part 1 Ammonium nitrate (note 1) Ammonium nitrate (note 2) Ammonium nitrate (note 3) Ammonium nitrate (note 4) Potassium nitrate (note 5) Potassium nitrate (note 6) Bromine Chlorine

5. Named substances Annex I Part 1 Nickel compounds in inhaled powder form (nickel monoxide, nickel dioxide, nickel sulphide, trinickel disulfide, dinickel trioxide) Ethyleneimine Fluorine Formaldehyde (concentration =>90% Hydrogen

6. Named substances Annex I Part 1 Hydrogen chloride (liqulified gas) Lead alkyls Liquefied extremely flammable gases (including LPG) Acetylene Ethylene oxide Methanol 4,4- Methylenebis (2-chloraniline) and/or salts, in powder form

7. Named substances Annex I Part 1 Methylisocyanate Oxygen Toluene diisocyanate Carbonyl dichloride (phosgene) Arsenic trichloride (phosphine) Phosphorous trihydride (phosphine) Surphur dichloride Sulphur trioxide Poly chlorodibenzofuransans and polychlorodibenzodioxins (including TCDD, calculated in TCDDD equivalent

8. Named substances Annex I Part 1 CARCINOGENS at concentration above 5% by weight: Amino biphenyl and/or its salts Benzotrichloride Benzedrine and/or its salts Bis(chloromethyl0ether Chloromethylether 1,2-Dibromoethane Diethyl sulphate Dimethyl sulphate

9. Named substances Annex I Part 1 CARCINOGENS at concentration above 5% by weight: Dimethylcarbamoyl chloride 1,2-dibromo-3-chloropropane 1,2-Dimethyly hydrazine Dimethyl nitrosamine Hexamethyl phosphoric triamide Hydrazine 2-Naphthylamine and/or salts 4-Nitrodiphenyl 1,3 Propanesultone

10. Named substances Annex I Part 1 Petroleum products (a)Gasolines and naphthas (b)Kerosenes (including jet fuels) (c)Gas oils (including diesel fuels, home heating oils and gas blending streams

11. Categories of substances and preparations Annex I Part 2 1. VERY TOXIC 2. TOXIC 3. OXIDIZING 4. EXPLOSIVE (Note 2, UN/ADR 1.4) 5. EXPLOSIVE (Note 2, UN/ADR 1.4) 6. FLAMMABLE (Note 3 (a) 7. HIGHLY FLAMMABLE (Note 3 (b) (1) 8. EXTREMELY FLAMMABLE ( Note 3(c))

12. Categories of substances and preparations Annex I Part 2 9. DANGEROUS FOR THE ENVIRONMENT risk phrases i) R50 “ very toxic to aquatic environment” including R50/53 ii) R51/53 “ toxic to aquatic organisms; may cause long adverse effects in the aquatic environment” 10. ANY CLASSIFICATION not covered by dose given and in combination with phrases: (i) R14 “ reacts violently with water” (including R14/15) (ii) R 29 “ in contact with water, liberates toxic gas”

13. Seveso II substances information resources Substances Dangerous for the Environment Substances dangerous to the aquatic environment in the context of the Council Directive 96/82/EC http://mahb.jrc.it/index.php?id=55

14. Seveso II substances information resources Substances Dangerous for the Environment Substances Dangerous to the Aquatic Environment in the context of the Council Directive 96/82/EC http://mahb.jrc.it/index.php?id=55

15. Seveso II substances information resources Carcinogens Single exposure carcinogenic substances in the context of the Council Directive 96/82/EC: http://mahb.jrc.it/index.php?id=56&dirview=4&file view=30&eclist=-4-E-http://mahb.jrc.it/index.php?id=56&dirview=4&file view=30&eclist=-4-E-

16. Seveso II substances classification Seveso II substances and preparations are currently classified according to following Directives, as amended: -Dangerous Substances Directive-DSD, 67/548/EEC - Dangerous Preparations Directive DPD, 99/45/EC

17. Seveso II substances classification Seveso II substances and preparations, after 2015, will be classified according to the new EU Regulation 1272/2008/EC as amended Annex VI of the above Regulation includes Seveso II substances with harmonized classification

18. Seveso II substances classification Special cases (e.g. wastes) and mixtures that cannot be classified conventionally: their classification is done by EU legislation pertinent to their nature (e.g. EU Waste Code)

19. Seveso II substances classification Hazard classification of chemicals: According to their intrinsic properties which potentially harm Health and the Environment

20. Thank you for your attention