1. Organic Chemistry
Topic 10

2. Introduction
1. Organic Chemistry is one of the major branches of chemistry. It includes the study of:
All biological molecules
All fossil fuels
Nearly all synthetic materials
Many domestic and industrial products

3. Organic compounds
An organic compound is one that contains carbon, and usually hydrogen, in covalently bonded structures. Other elements, such as oxygen, nitrogen, sulfur and chlorine , are often also present.
Carbon is the key element in organic compounds because it can form 4 covalent bonds with other carbon atoms or with other elements, especially hydrogen.
Carbon has the ability to form chains and rings; this is known as catenation

4. Definitions and conventions used in organic chemistry

5. Types of reactants

6. Types of Reactions

7. Types of reactions

8. Types of bond breaking

9. Depicting organic reaction mechanisms

10. Depicting organic reaction mechanisms

11. Classification system
Because There are so many organic molecules (at least 10 million different organic molecules), It is useful to classify them into families according to their properties.
Organic compounds are classified into families of compounds called homologous series.

12. Homologous series
Successive members of a homologous series differ by a –CH2 group. For example, the following are members of a family of compounds called alkanes.
The same increment applies to successive members of each homologous series.

13. Homologous series
Members of a homologous series can be represented by the same general formula. For example, in alkanes, the general formula is C n H2n
In alcohols, the general formula is C n H2n + 1 OH, for example,

14. Homologous series
Members of a homologous series show gradual change in physical properties. For example, the length of the carbon chain affects the boiling point of the alkanes as follows:
Notice that the longer then chain, the higher the boiling point. This occurs because as the molecular size increases, London forces increase.
Other physical properties that show this gradual trend are density and viscosity.

15. Homologous series
Members of a homologous series have the same properties because they have the same functional group. For example, alcohols have an –OH functional group, which may be oxidized to form organic acids. Carboxylic acids have –COOH functional group, which their acidic properties.
So, if we know the characteristics of the functional group, then we can predict the properties of the members of the homologous series.

16. Homologous series

17. Formulas for organic compounds
Empirical Formula – a formula that shows the simplest whole number ratio of the atoms in a compound.
Molecular Formula - a formula that shows the actual number of atoms of each element in a molecule.
For example: the molecular formula for ethane is C2H6. Its empirical formula is CH3.
Structural formula - a formula that shows how the atoms are bonded to each other in a molecule.

18. Structural Formulas

19. Structural Formulas

20. Chemical formulas

21. Isomers
Isomers are compounds with the same formula, but different structures. In other words, the atoms are connected differently. For example:
Ethyl Alcohol C2H6O Ch3CH2OH
Dimethyl Ether C2H6O CH3OCH3

22. Nomenclature of alkanes
Alkanes are saturated hydrocarbons because they contain only single bonds. The term hydrocarbon refers to compounds that are made of carbon and hydrogen.
The name of organic compounds have three parts: prefix, parent, and suffix,
Prefix – where is the functional group and the other substituents (branches) located?
Parent – how many carbons?
Suffix – what family does the molecule belong to?
The alkanes family suffix is –ane.

23. Alkanes
To name straight chain alkanes, count the number of carbon atoms and add the family suffix – ane.
No. of Carbons Structure Name
CH Methane
CH3CH ethane
CH3CH2CH Propane
CH3CH2CH2CH Butane
CH3CH2CH2CH2CH Pentane
CH3CH2CH2CH2CH2CH Hexane
CH3CH2CH2CH2CH2CH2CH3 Heptane
CH3CH2CH2CH2CH2CH2CH2CH3 Octane
CH3CH2CH2CH2CH2CHCH2CH2CH3 Nonane
CH3CH2CH2CH2CH2CH2CH2CH2CH2CH3 Decane

24. Alkanes
Substituents that branch off the main chain are called alkyl groups.
Alkyl group – the part of an alkane that remains when a hydrogen atom is removed.
For example: CH4 is methane CH3 is methyl
C2H6 is ethane -- CH2CH3 is ethyl
CH3CH2CH3 is propane -- CH2CH2CH3 is propyl and i
CH3CHCH3 is isopropyl

25. Alkanes
Step 1 : find the longest continuous chain of carbons and name it according to the number of carbon atoms it contains.
Step 2: number the carbon atoms in the main chain, beginning at the end nearer to the first branch.
Step 3: Identify the branching substituents and number each according to the carbon to which it is attached.
Step 4.: Write the name as a single word, using hyphens to separate numbers from prefixes and commas to separate numbers. If two or more different substituents are present, list them in alphabetical order. If two or more identical substituents are present, use of the prefixes, di, tri, tetra, etc.