The History of the Modern Periodic Table

History of the Periodic Table Dmitri Mendeleev – first to organize elements according to their properties Mendeleev ordered the elements according to increasing atomic mass

Henry Mosely British Scientist 1911 Re-ordered the periodic table in order of Proincreasing atomic number instead of mass. blems with the Mendeleev table disappeared.

History of the Periodic Table Periodic Law: The physical & chemical properties of the elements are periodic functions of their atomic numbers.

History of the Periodic Table Periodic Table: arrangement of elements in order of their atomic numbers so that elements with similar properties fall in the same column.

Periodic Table Geography

The horizontal rows of the periodic table are called PERIODS.

The vertical columns of the periodic table are called GROUPS, or FAMILIES. The elements in any group of the periodic table have similar physical and chemical properties!

Alkali Metals (yellow)

Alkali Metals 1 st column on the periodic table (Group 1) not including hydrogen. Very reactive metals, always combined with something else in nature (like in salt). Soft enough to cut with a butter knife

Alkaline Earth Metals (Blue)

Alkaline Earth Metals Second column on the periodic table. (Group 2) Reactive metals that are always combined with nonmetals in nature. Several of these elements are important mineral nutrients (such as Mg and Ca

Transition Metals (orange!)

Transition Metals Elements in groups 3-12 Less reactive harder metals Includes metals used in jewelry and construction. Metals used “as metal.”

Halogens (green)

Halogens Elements in group 17 Very reactive, volatile, diatomic, nonmetals Always found combined with other elements in nature. Used as disinfectants and to strengthen teeth.

Noble Gases (Red)

The Noble Gases Elements in group 18 VERY unreactive, monatomic gases Do not combine with other elements Used in lighted “neon” signs Have a full valence shell.

The Odd Ones

Hydrogen Hydrogen belongs to a family of its own. Hydrogen is a diatomic, reactive gas. Hydrogen is promising as an alternative fuel source for automobiles

Boron Family Elements in group 13 Aluminum metal was once rare and expensive, not a “disposable metal.”

Carbon Family Elements in group 14 Contains elements important to life and computers. Carbon is the basis for an entire branch of chemistry. Silicon and Germanium are important semiconductors.

Nitrogen Family Elements in group 15 Nitrogen makes up over ¾ of the atmosphere. Nitrogen and phosphorus are both important in living things. Most of the world’s nitrogen is not available to living things. The red stuff on the tip of matches is phosphorus.

Metalloids Along the stair step line of the periodic table Boron, Silicon, Germanium, Arsenic, Antimony, Tellurium Have characteristics of both metals and nonmetals

The periodic table is the most important tool in the chemist’s toolbox!

Metals, Nonmetals, and Metalloids Metallic character increases down and to the left on the table and nonmetallic character increases up and to the right on the table.

Atomic Radii Increase

Valence Electrons electrons available to be lost, gained, or shared in the formation of chemical compounds usually in the outermost s and p orbitals for main group elements (Families 1 & 2, and Families 13-18)

Valence Electrons for each group Group 1: valency +1 Group 2: +2 Group 3: +3 Group 4: 4 Group 5: -3 Group 6: -2 Group 7: -1 Group 8: 0 stable. does not like to react with others. With each electron shell wanting to gain up to 8 electrons on outer shell

An electron configuration shows the number of electrons in each orbital in a particular atom. Keep this in mind about the number of valence electrons and the Roman numeral column number: The IA family has 1 valence electron; the IIA family has 2 valence electrons; the VIIA family has 7 valence electrons; and the VIIIA family has 8 valence electrons. So for the families labeled with a Roman numeral and an A, the Roman numeral gives the number of valence electrons.

Neutral Atoms vs. Ions Cations – form positive ions by losing electrons (metals) Anions – form negative ions by gaining electrons (nonmetals)

Ionization Energy Energy required to remove one electron from a neutral atom of an element. Increases left to right across the periodic table. Increases going from the bottom to the top of a group. For each successive electron in an atom that is removed, the ionization energy increases.

Ionization Energies Increase

Electron Affinity energy change that occurs when a neutral atom gains an electron Most atoms release energy when they acquire electrons.

Electronegativity measure of an atom’s ability to attract electrons in a chemical compound If electron affinity is high, electronegativity will be high.

Periodic Table Lanthanides Actinides Alkaline Metals Alkaline Earth Metals Transition Metals Noble Gases Halogens Metalloids Group 15 pnictogens Group 16 chalcogens Group 13 boron family Group 14 carbon family

Metals, Nonmetals, and Metalloids Metallic character increases down and to the left on the table and nonmetallic character increases up and to the right on the table.

Periodic Table w/ orbitals

Interactive Periodic Table mlhttp://center.acs.org/periodic/tools/PT.ht ml