RBP CHEMICAL TECHNOLOGIES DOT/HAZARDOUS MATERIALS (DOT/HAZMAT) TRAINING HAZARDS COMMUNICATION (HAZCOM) TRAINING SECURITY AWARENESS TRAINING

INTRODUCTION DOT/HAZMAT TRAINING THE HAZARDOUS MATERIALS TABLE SHIPPING PAPERS PACKAGING AND PACKAGE MARKING LABELING PLACARDING LOADING AND STORAGE HAZMAT EMERGENCIES

WHY ARE WE HERE? To review the D.O.T. regulations requiring that hazmat employees: Are familiar with the requirements of the regulations Are able to identify hazardous materials Know specific requirements that apply to their job Know how to respond to emergencies, protect themselves and prevent accidents

WHAT ARE THE REGULATIONS? Hazardous Materials Regulations (HMR) Training Requirements (HM-126F) Hazardous Materials Table (Part of HMR)

WHAT DO THEY TELL US? How to determine if the materials you are going to ship are hazardous How to describe them How to package them How to ship them How to communicate these hazards to the world: LABELING MARKING SHIPPING DESCRIPTIONS SHIPPING PAPERS PLACARDS Who needs to be trained

WHAT’S A HAZARDOUS MATERIAL? Any substance or material capable of posing an unreasonable risk to health, safety and property when transported in commerce These materials are located in the HAZARDOUS MATERIALS TABLE

WHAT’S A HAZMAT EMPLOYEE? A person who directly affects the safe transport of hazmat: Manufactures packaging Selects or purchases packaging, labeling, etc. Fills packages with hazardous materials Prepares shipping papers and emergency response data Handles and ships finished hazmat packages Drives transport vehicles containing hazardous materials Provides emergency response information

INTRODUCTION - QUESTIONS What’s the purpose of this training? To know how to package and ship chemicals safely To comply with HM-126F To communicate hazards to others All of the above What’s a hazardous material? Something that’s harmful to property Something that’s harmful to people Something that’s harmful to health None of the above

THE HAZARDOUS MATERIALS TABLE DOT/HAZMAT TRAINING INTRODUCTION THE HAZARDOUS MATERIALS TABLE SHIPPING PAPERS PACKAGING AND PACKAGE MARKING LABELING PLACARDING LOADING AND STORAGE HAZMAT EMERGENCIES

THE HAZARDOUS MATERIALS TABLE WHAT IS IT? The Hazardous MaterialS Table is found in the HMR and lists materials that the Research and Special Programs Administration (RSPA) has determined to be hazardous.

THE HAZARDOUS MATERIALS TABLE Contains all the necessary information to identify the requirements that apply to each shipment of each hazardous material: Column 1 – Symbols Column 2 – Proper Shipping Descriptions And Names Column 3 – Hazard Class Or Division Column 4 – Identification Numbers Column 5 – Packing Group Column 6 – Labeling Requirements Column 7 – Special Provisions Column 8 – Packaging Authorizations Column 9 – Quantity Limitations Column 10 – Vessel Stowage

THE HAZARDOUS MATERIALS TABLE WHO USES IT? Anyone with the responsibility of determining: What the hazards of a material are The proper packaging, labeling, placards The proper shipping descriptions Any transportation restrictions Who would that be at RBP? Mike Mohs Dan Dietrich Jerry Groth Shipping

THE HAZARDOUS MATERIALS TABLE WHAT DO I NEED TO KNOW ABOUT IT? THAT IT EXISTS THAT ALL HAZMAT SHIPPING IS BASED ON IT

HAZMAT TABLE - QUESTIONS What’s a hazardous materials table? A bench top in the chem lab The morning breakfast table A list of substances that pose a risk to health, safety and property All of the above What’s the purpose of the Hazardous Materials Table? To confuse everyone The source of information on classifying, packaging and shipping materials.

HAZMAT TABLE - QUESTIONS Who uses the hazardous materials table? Everyone Anyone who makes, handles, packages or ships hazardous materials Those who determine shipping descriptions and packaging, labeling, shipping requirements

SHIPPING PAPERS DOT/HAZMAT TRAINING INTRODUCTION THE HAZARDOUS MATERIALS TABLE SHIPPING PAPERS PACKAGING AND PACKAGE MARKING LABELING PLACARDING LOADING AND STORAGE HAZMAT EMERGENCIES Q&A. QUIZ

SHIPPING PAPERS Properly completed shipping papers must accompany every shipment of hazardous materials Whenever a hazardous material is transported, its description must appear on the shipping paper. A Bill of Lading is the most common (RBP) Hazardous Waste Manifest Multiple entries can be made on one shipping document. Hazardous and non-hazardous materials can both be listed on the same document.

SHIPPING PAPERS When both a hazardous and a non hazardous material are listed, the hazardous material must be: Listed FIRST Shown in contrasting color and highlighted on multi-sheet forms. Identified with an “X” or “RQ” in the “HM” column.

SHIPPING PAPERS

SHIPPING PAPERS Entry must be legible and in English Entry may not contain code numbers or abbreviations Each entry for each hazardous material must include the BASIC DESCRIPTION: Proper shipping name (Column 2, Hazmat Table) Hazard class (Column 3, Hazmat Table) Identification Number (Column 4, Hazmat Table) Packing Group (Column 5, Hazmat Table)

SHIPPING PAPERS Shipping paper must: Contain the name of the shipper Indicate multiple pages, for example “page 1 of 4”. Show emergency response number Contain Shipper’s Certification Include the total quantity of material Accompany the shipment (give to the driver) Be readily available in driver’s compartment

SHIPPING PAPERS

SHIPPING PAPERS, QUESTIONS What does RBP use for a shipping document? ________________ Can hazardous and non-hazardous materials be listed on the same shipping document (Y/N)? Name one item that must be on a shipping paper for every material shipped.______________________________ Who gets the shipping paper when the shipment leaves RBP? Where is it kept? ______________________________

PACKAGING AND PACKAGE MARKING DOT/HAZMAT TRAINING INTRODUCTION THE HAZARDOUS MATERIALS TABLE SHIPPING PAPERS PACKAGING AND PACKAGE MARKING LABELING PLACARDING LOADING AND STORAGE HAZMAT EMERGENCIES

PACKAGING AND PACKAGE MARKING Hazmat packaging must be designed to safely contain the material The more hazardous the material, the more strict the packaging requirement: Packing Group I – Great Danger Packing Group II – Medium Danger Packing Group III – Minor Danger All packagings must be tested prior to use. Performance Oriented Packaging, “POP”

PACKAGING AND PACKAGE MARKING Performance Oriented Packaging (POP) requirements apply to: Bulk – Greater than 119 gallons, Example: Totes Non-bulk – Less than or equal to 119 gallons Examples: Drums, Bottles, Carboys New and reused packaging Specification and non-specification packaging All packaging must be marked

PACKAGING AND PACKAGE MARKING

PACKAGING AND PACKAGE MARKING

PKG & MARKING - QUESTIONS What type of package can be used to ship a hazardous material? Strong sturdy boxes or containers Boxes or container that have been tested for the material being shipped. Only new boxes or containers All of the above Can a material with a severe hazard rating be shipped in a package rated for a mildly hazardous material? _____ Only non-bulk packages need to be marked (T/F) _____ What is POP packaging? Specification packaging for carbonated beverages What they pack firecrackers in Performance Oriented Packaging

LABELING DOT/HAZMAT TRAINING INTRODUCTION THE HAZARDOUS MATERIALS TABLE SHIPPING PAPERS PACKAGING AND PACKAGE MARKING LABELING PLACARDING LOADING AND STORAGE HAZMAT EMERGENCIES

LABELING Hazardous Material Warning labels are color-coded so that the hazards can be quickly recognized. Labels correspond to the placards that must appear on bulk packaging, freight containers, transport vehicles or rail cars that contain a hazardous material. Labels are NOT required on bulk packages with placard(s).

LABELING

LABELING Labels must include both the hazard class and the division of hazard, if required, according to the Hazardous Materials Table (Col. 6). Example: 5.1 for Oxidizer The first label listed is the primary hazard of the material. This label MUST contain the hazard class number. Additional labels indicate subsidiary hazards. These labels DO NOT contain the hazard class number. Labels must be visible. Example: Stretch wrapped skids of items.

LABELING

LABELING

LABELING - QUESTIONS How do you recognize a hazard from the label? By the color By the symbol on the label By the wording on the label By the number at the bottom of the label All of the above You can use two (or more) labels on one package (T/F). Labels do not need to be visible on all materials shipped as long as information is on the paperwork and the driver understands what he is shipping (T/F) Labels are NOT required on bulk packages (T/F)

PLACARDING DOT/HAZMAT TRAINING INTRODUCTION THE HAZARDOUS MATERIALS TABLE SHIPPING PAPERS PACKAGING AND PACKAGE MARKING LABELING PLACARDING LOADING AND STORAGE HAZMAT EMERGENCIES

PLACARDING Hazmat placards are similar to the shape, color and design of hazmat warning labels. They serve the following purposes: To alert the public to the potential dangers of hazardous materials. To guide emergency personnel in their actions during a hazmat incident.

PLACARDING Unless excepted, each: Bulk package Freight container Unit load device Transport vehicle Rail car Containing any quantity of a hazardous material must be placarded on each side and each end with the placards specified in Part 172, Subpart F.

PLACARDING

PLACARDING

PLACARDING - QUESTIONS Placards are different from labels in what ways? They are bigger They typically contain only the hazard class number They are used on bulk, freight, tankers, etc. All of the above The hazard class number on the placard must match the number in the shipping description (T/F). Semi trailers containing non-bulk packaging never need to be placarded (T/F)

LOADING AND SECUREMENT DOT/HAZMAT TRAINING INTRODUCTION THE HAZARDOUS MATERIALS TABLE SHIPPING PAPERS PACKAGING AND PACKAGE MARKING LABELING PLACARDING LOADING AND SECUREMENT HAZMAT EMERGENCIES

LOADING AND SECUREMENT The responsibility for complying with the provisions for loading, storage, and transportation of hazardous materials generally lies with the carrier. HOWEVER You know more about RBP chemicals than the driver does. There are two requirements that are of special importance. It’s up to the shipper (Us, RBP) to ensure the hazardous materials are properly loaded.

LOADING AND SECUREMENT SEPARATION DISTANCES: These are established for transporting radioactive materials and are also required for people and cargo compartment dividing partitions. SEGREGATION: Certain hazardous materials cannot be carried on the same load. (cyanides or cyanide mixtures cannot be transported with acids.) A Segregation Table provides a reference for segregating certain hazardous materials.

LOADING AND SECUREMENT

LOADING - QUESTIONS It’s up to the driver to make sure hazardous materials shipped by RBP are properly loaded, secured, and placarded? (T/F) Any chemical can be shipped with any other chemical (T/F) What is the segregation table for? Are there any RBP products that require segregation when shipped?

HAZMAT EMERGENCIES DOT/HAZMAT TRAINING INTRODUCTION THE HAZARDOUS MATERIALS TABLE SHIPPING PAPERS PACKAGING AND PACKAGE MARKING LABELING PLACARDING LOADING AND SECUREMENT HAZMAT EMERGENCIES

HAZMAT EMERGENCIES Those who handle hazardous materials must know: The basic description & technical name of the material Immediate hazard(s) to health Risks of fire and exposure Who to contact How to clear the area How to isolate a spill Preliminary first aid and fire fighting methods Emergency response phone numbers

HAZMAT EMERGENCIES The emergency response information must: Be printed in English Always be available Be available away from the package containing the hazmat. For example: On the shipping papers Attached to the shipping papers: Emergency Response Guide MSD Sheets. (Not an MSDS Sheet) In the truck cab, with the driver

EMERGENCIES - QUESTIONS Why is it important to keep response information separate from the hazardous material? The first step in responding to an emergency is: Isolate the spill Read the MSDS Clear the area Contact emergency response personnel What’s the second step? (Pick a letter)

RBP CHEMICAL TECHNOLOGIES DOT/HAZARDOUS MATERIALS (DOT/HAZMAT) TRAINING HAZARDS COMMUNICATION (HAZCOM) TRAINING SECURITY AWARENESS TRAINING

HAZARD COMMUNICATION Manufacturers or Suppliers are responsible for communicating the hazards of their materials (MSDS’s and labels) End users (employers) are responsible for communicating these hazards to their employees and having the information available. Employees are responsible for following the safety procedures for the hazardous materials they use.

HAZARD COMMUNICATION HAZCOM is also called the “Right to Know” law. You have a right to know the hazards in your workplace A Good Hazcom Program Consists Of: HAZARDS: Determining what they are WRITTEN PROGRAM: Describing how things are done and where information is kept LABELS to communicate hazards MATERIAL SAFETY DATA SHEETS TRAINING of Employee

HAZARDS Health Hazards Physical Hazards Chemicals can enter the body by Inhalation, Absorption or Ingestion Types of health hazards: Irritant, Corrosive, Sensitizer, Teratogen/Mutagen, Carcinogen, Toxic Physical Hazards Flammable, reactive, oxidizer, explosive, compressed gas, unstable, water reactive

WRITTEN PROGAM Describes the overall program at RBP Lists of chemicals used How MSDS’s are managed How hazard labels (HMIS) are used How training is done How contractors are trained

HAZARD LABELS HMIS (Hazardous Material Identification System) Health Hazard (Acute)* Flammability* Reactivity* PPE * Scale of 0-4: 4 is the worst

MSDS’S Primary tool for communicating hazard information. Chemical Identity Physical/Chemical characteristics Routes of entry Permissible exposure levels (PEL) Carcinogen? Handling precautions Engineering controls (e.g. ventilation) Emergency & 1st aid procedures Preparation date (should be current) Contact information New requirements (ANSI) Environmental/transportation regulatory information

TRAINING Required for new employees, new job, new material(s) present Explanation of the Hazcom standard Where hazards are present Location of written programs, lists, MSDS’s How releases are detected Physical and health hazards in work areas Protection measures, including PPE Details of the Hazcom program

HAZARD COMMUNICATION QUESTIONS Who is responsible for Hazcom? The person who delivers the material The manufacturer The end user The employee All of the above B-D above All chemicals present some type of health hazard (T/F) What’s the primary tool for communicating hazards? A laptop and projector The MSDS Labels Training Program

HAZARD COMMUNICATION QUESTIONS What does HMIS stand for? Hazardous Materials Importance System Hazardous Materials Identification System Hazardous Materials Inventory System Holy Moly I’m Sure confused A good Hazcom program consists of: Hazard determinations A written program Labels & MSDS’s Training A video library All of the above A-D Above

RBP CHEMICAL TECHNOLOGIES DOT/HAZARDOUS MATERIALS (DOT/HAZMAT) TRAINING HAZARDS COMMUNICATION (HAZCOM) TRAINING SECURITY AWARENESS TRAINING

SECURITY AWARENESS TRAINING OBJECTIVE: Provide training to all employees to “Reduce the vulnerability of RBP and its employees to attack by those who target companies that handle and transport hazardous chemicals.* * From RBP’s Security Plan

SECURITY AWARENESS TRAINING Hazards at RBP Class 3 Flammables Class 5.1 Oxidizers Class 8 Corrosives Materials of possible interest to terrorists Oxidizers (HNO3, Sodium Chlorate, H2O2) Ammonium Salts Flammable solvents

SECURITY AWARENESS TRAINING BE AWARE OF THOSE AROUND YOU* BE AWARE OF WHAT’S AROUND YOU* BE AWARE OF NEW EMPLOYEES* REQUIREMENTS OF THE REGULATIONS* PROCEDURES FOR VISITORS AND ACCESS* RESTRICTIONS OF SENSITIVE INFORMATION* * From RBP’s Security Plan

BE AWARE OF THOSE AROUND YOU Be aware* of unusual behavior Be aware of highly stressed individuals Be on the lookout for unauthorized individuals on the premises Be aware if new transport drivers arrive When in doubt, verify When in doubt, notify supervision/mgt. *Aware means be vigilant, not overly suspicious.

BE AWARE OF WHAT’S AROUND YOU Be observant Be aware of new materials that are purchased Be aware of unusual package or container conditions (gassing, bulging, tipping, etc.) Be aware of suspicious vehicles on site It’s like the unattended suitcase thing in an airport When in doubt, notify supervision/mgt.

BE AWARE OF NEW EMPLOYEES If you don’t recognize someone, ask. When in doubt, notify supervision/mgt.

REQUIREMENTS OF THE REGULATIONS Security training Written security plan Vulnerability assessment Security assessment Personnel assessment and security Document control

PROCEDURES FOR VISITORS/ACCESS All visitors must be accompanied by an RBP employee Truck drivers are restricted to the shipping area* Unauthorized individuals should be questioned/challenged. Call management RBP’s truck is locked at all times during transit The RBP facility is protected by ADT. All entrances are closed and monitored during off-hours Fire & police tied into system Security system access limited *Except for MEA, H2O2, K2CO3 tanker drivers

RESTRICTION OF SENSITIVE INFORMATION Objective is to prevent access to sensitive security information by unauthorized personnel. This applies to the following at RBP RBP Security Plan ADT alarm system information Security procedures Training materials and records Formulas and lists of chemicals used at RBP

SECURITY AWARENESS QUESTIONS Every chemical at RBP could be used by a terrorist (T/F) RBP has an open door policy (T/F) Terrorists typically fit one stereotype (T/F) Be cooperative, answer any question you are asked (T/F) When should hazmat transport vehicles be locked? When are hazardous materials most vulnerable? The new drivers licenses make them immune to forgery (T/F) Just because you don’t know someone in the plant, he probably has a legitimate reason to be here, and can go on his way (T/F)

SECURITY AWARENESS BE AWARE BE PROTECTIVE THINK OF THIS PLANT AS YOUR “HOUSE”. TREAT PERIMETERS, ACCESS AND VISITORS THE SAME AS YOU WOULD AT HOME