UNITED NATIONS DEVELOPMENT PROGRAMME HCFC PHASEOUT IN PU SHOESOLES -demonstration/execution in Mexico-

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UNITED NATIONS DEVELOPMENT PROGRAMME HCFC PHASEOUT IN PU SHOESOLES -demonstration/execution in Mexico-

UNDP DEMO PROJECTS TechnologyAppl.StatusOutcome Sc. CO 2 (Colombia) RPFCompleteOK but higher conductivity Hydrocarbons (Egypt) RPFOngoingPreblended: OK/CP Direct: OK/NP-CP Methyl Formate (Brazil) (Mexico) (China) RPF FPF ISF XPS Complete Ongoing OK; density limitation OK Not recommended Open Methylal (Brazil) (Mexico) RPF FPF ISF Complete OK; density limitation OK Very good HFO-1234ze (Turkey) XPSAbortedOpen

TECHNOLOGIES EVALUATED METHYL FORMATE ALL-WATER-BASED HFCs METHYLAL (ML)

SHOE SOLES WITH MF CAN REPLACE HCFC-141b WITH SAME PROPERTIES FLAMMABILITY AT SYSTEM HOUSE TO BE ADDRESSED SAFE FOR ENDUSERS LOW GWP ISSUES WITH PREBLENDING

SHOESOLES WITH HFCs ALREADY APPLIED EMISSIVE (HFC-134a; HFC-245fa) HIGH IOCs/LOW ICCs CURRENT USE VERY LOW HIGH GWP

SHOESOLES WITH WATER ALREADY APPLIED PREFERRED TECHNOLOGY WHEN USING POLYESTERS DENSITY AND SKIN ISSUES IN POLYETHERS LOW GWP

SHOESOLES WITH ML CAN REPLACE HCFC-141b WITH SAME OR BETTER PROPERTIES WIDE-SPREAD MARKET ACCEPTANCE FLAMMABILITY AT SYSTEM HOUSE TO BE ADDRESSED SAFE FOR ENDUSERS LOW GWP

Property All types R-095R-096R-099QZCT15 Test Method TypeSPORTTRAVELRIGID SEMI- RIGID Blowing Agent 141bML Density (kg/m 3 ) < D-792 Tear resistance (kgf/cm) >6* n/a D-624 Abrasion Resistance (mg, maximum) < D-1044 Flex Resistance (%, 30,000 cycles) <200*00n/a D-1052 s SHOESOLES WITH ML

TECHNOLOGIES APPLIED METHYLAL/- 3 SYSTEM HOUSES WATER - 15 ENDUSERS - 1 DISTRIBUTOR WATER/- 2 SYSTEM HOUSES UNDECIDED