On-Line Physical Measurements Terry A. Ring Department of Chemical Engineering University of Utah
Types of Instruments Flow Measurement Level Measurement Temperature Measurement Pressure Measurement Density Measurement Concentration –Analytical Instrumentation –Chemical Sensors Safety, Weight and Misc.
On-Line Connections Analogue Signal –mV, mA, Volts, Amp, Watts, other Amplification to Industrial Std Scales –4 to 20 mA –+ 5 to -5 V Digitization –Step size = Scale/(2^N) –N = bits in a byte of A-to-D board –Calculation Precision 8, 10, digits or 32 digits of binary words are common
Flow Measurement Orifice plates Pitot tubes Rotary Flowmeters Mass Flowmeters – Coriolis, Thermal Magnetic Flowmeters Sight Flow Indicators – paddle Variable-area Flowmeters – rotameters Venturi Tubes V-cone Flowmeter Many, many others
Sight Flow Meter
Rotameters
Turbine Flow Meter
Thermal Mass Flow Meter
Orifice Plate / Venturi Meter
Level Measurement Float Level Devices Level Gauges Differential Pressure Level Detectors Slip tubes and Dipsticks Ultrasonic Level Detectors Laser Level Detectors Load Cells on Tanks Many, many others
Temperature Measurement Filled-bulb, Glass-stem thermometer Thermocouples Thermistors Resistance Temperature Detectors (RTDs) - platinum resistance thermometer Pyrometers Fiber-Optic Thermometers Others
Thermocouples
Thermocouple Fermi – Dirac Distribution µ=Fermi Level or 50% fill level µ=Chemical Potential of electron
V=I*R
RTD’s Based on the electrical resistance of a conductor increasing with temperature Most accurate, reproducible and stable thermal element available Relatively expensive Very precise Fragile but can be industrially hardened
Thermistors Semiconductors made from mixtures of pure oxides (Mn, Ni, Cu, Zn, Fe, etc.) sintered at > 1800 o F Very good for narrow span measurement Output highly non-linear, not good for wide span applications, fragile unless industrially hardened Small size, fast response Lack of stability at higher temperatures
Pressure Measurement Bourdon pressure sensors - C Bourdon - Spiral Bourdon - Helical Bourdon Differential pressure instruments Electronic pressure sensors - strain gauge transducers - piezoelectric sensor Manometers Diaphragm sensors
Pressure Measurement Absolute Gauge Vacuum
Piezoelectric Sensor Pressure Sensor
Liquid Density Measurement Hydrometers Weighing a fixed volume Oscillating Coriolis Densitometers Hydrostatic Densitometers Radiation Densitometers – liquid/sludge Vibrating Densitometers – Liq/sludge/gas
Hydrostatic Densitometers Process Piping ρ=ΔP/(g h)
Radiation Densitometer hυhυ Radiation β or γ Light X-rays Beer’s Law I/Io= exp(-kcL)
Chemical Sensors Gas Analysis –Electrochemical Analysis CO sensor alcohol sensor –Ion mobility
Drift Cell Analysis time the ions spend in the drift cell t d can be obtained in terms of P/V. L = length of cell V= Voltage vd = drift velocity K o = mobility P, T = Pressure and Temperature, subscript o is on-line conditions, without subscript is inside instrument (typically vacuum) Create Ions by Plasma Mobility depends on MW and Charge
On-Line Analytical Instruments –Infra Red –Gas Chromatography –Liquid Chromatography –Ultra Violet –Visible –Mass Spectrometer Mw 1 to 60 or 1 to 300. –How would each of these work? Time delays
Spectroscopy
Liquid / Gas Chromatography
Mass Spectroscopy Mw= gm/mole Capillary Vac Process
Safety, Weight and Misc. Relief Valves Rupture Discs Leak Detectors - Anemometers – air and gas flows Boroscopes – inspect remote or limited- access locations – reactors, process lines, etc. (fiberscopes) Weighing – Electronic Load Cells
On-Line Connections Analogue Signal –mV, mA, Volts, Amp, Watts, other Amplification to Industrial Std Scales –4 to 20 mA –+ 5 to -5 V Digitization –Step size = Scale/(2^N) –N = bits in a byte of A-to-D board –Calculation Precision 8, 10, digits or 32 digits of binary words are common
Keep it Running Well KNOW YOUR EQUIPMENT Accuracy and Precision UNDERSTAND THE LIMITATIONS OF YOUR EQUIPMENT CALIBRATE AS MUCH AS IS REASONABLE Maintain Equipment so it will Perform Reliably