DEA - Università degli Studi di Brescia TCAM model configuration for POMI simulations C. Carnevale, G. Finzi, E. Pisoni, M. Volta Dipartimento di Elettronica.

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DEA - Università degli Studi di Brescia TCAM model configuration for POMI simulations C. Carnevale, G. Finzi, E. Pisoni, M. Volta Dipartimento di Elettronica per lAutomazione Università degli Studi di Brescia

DEA - Università degli Studi di Brescia Land use Topography MM5 output PROMETEO TCAM Chimere output BOUNDY Boundary and Initial condition 3D concentration fields POEM-PM Emission inventories Emission Fields 3D wind and temperature fields Turbolence and Boundary Layer parameters VOC speciation Profiles Temporal Profiles System Evaluation Tool GAMES: Gas Aerosol Modelling Evaluation System PM size and chemical speciation Profiles

DEA - Università degli Studi di Brescia Meteorological data pre-processing PROMETEO Grid projection Grid rescaling Turbolence parameters

DEA - Università degli Studi di Brescia Emission data pre-processing POEM-PM Temporal Modulation VOC speciation VOC lumping PM10 speciation

DEA - Università degli Studi di Brescia Boundary Condition data pre-processing Boundy TCAM-grid boundary extraction (Temporal interpolation) Gas chemical mechanisms linking Aerosol chemical and size classes linking

DEA - Università degli Studi di Brescia Eulerian 3D model Terrain-following coordinate system Horizontal Transport Module: Chapeau Function + Forester Filter Vertical Transport Module: Crank-Nicholson hybrid solver based on the vertical diffusivity coefficient Deposition Module –Dry deposition: resistance-based approach –Wet deposition: scavenging approach for both gas and aerosol species TCAM: Transport and Depostion Module

DEA - Università degli Studi di Brescia Chemical Mechanism –CBIV 90 –SAPRC 90/97 –COCOH 97 Numerical Solver –QSSA (explicit) –IEH (hybrid) Species: 95 Reactions: 187 Fast-Species (12): LSODE (implicit) Slow-Species: Adams-Bashforth (explicit) TCAM: Gas chemical module

DEA - Università degli Studi di Brescia Chemical Species: 21 –12 inorganics –9 organics Size Classes: <10 (from 0.01 m to 50 m) –Fixed moving approach Involved Phenomena: –Condensation/Evaporation –Nucleation –SO 2 aqueus chemistry Shell Core TCAM: Aerosol module

DEA - Università degli Studi di Brescia TCAM configuration overview Grid resolution: –D1: 5x5km2 (?) or 10x10km2 –D2: 2.5x2.5km2 (?) or 5x5km2 Vertical resolution –First level: 20 mt (top) –Last level: 4000 mt a.g.l. (top) Chemistry –Gas: COCOH species, 187 reactions, LSODE) –Aerosol: 21 species, 10 (?) size classes, SCAPE2