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**II. Solution Concentration (p. 480 – 488)**

Ch. 14 – Mixtures & Solutions II. Solution Concentration (p. 480 – 488)

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**A. Concentration The amount of solute in a solution**

Describing Concentration % by mass - medicated creams % by volume - rubbing alcohol ppm, ppb - water contaminants molarity - used by chemists molality - used by chemists

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**SAWS Water Quality Report - June 2000**

A. Concentration SAWS Water Quality Report - June 2000

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**substance being dissolved**

A. Molarity Concentration of a solution substance being dissolved total combined volume

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A. Molarity 2M HCl What does this mean?

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**B. Molarity Calculations**

LITERS OF GAS AT STP Molar Volume (22.4 L/mol) MASS IN GRAMS MOLES NUMBER OF PARTICLES Molar Mass (g/mol) 6.02 1023 particles/mol Molarity (mol/L) LITERS OF SOLUTION

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**B. Molarity Calculations**

How many grams of NaCl are required to make 0.500L of 0.25M NaCl? 0.500 L sol’n 58.44 g NaCl 1 mol NaCl 0.25 mol NaCl 1 L sol’n = 7.3 g NaCl

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**B. Molarity Calculations**

Find the molarity of a 250 mL solution containing 10.0 g of NaF. 10.0 g NaF 1 mol NaF 41.99 g NaF = 0.95 M NaF .25 L sol’n

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C. Dilution Preparation of a desired solution by adding water to a concentrate. Moles of solute remain the same.

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C. Dilution What volume of 15.8M HNO3 is required to make 250 mL of a 6.0M solution? GIVEN: M1 = 15.8M V1 = ? M2 = 6.0M V2 = 250 mL WORK: M1 V1 = M2 V2 (15.8M) V1 = (6.0M)(250mL) V1 = 95 mL of 15.8M HNO3

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D. Molality mass of solvent only 1 kg water = 1 L water

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D. Molality Find the molality of a solution containing 75 g of MgCl2 in 250 mL of water. 75 g MgCl2 1 mol MgCl2 95.21 g MgCl2 0.25 kg water = 3.2m MgCl2

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D. Molality How many grams of NaCl are req’d to make a 1.54m solution using kg of water? 0.500 kg water 1.54 mol NaCl 1 kg water 58.44 g NaCl 1 mol NaCl = 45.0 g NaCl

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**E. Preparing Solutions 1.54m NaCl in 0.500 kg of water**

500 mL of 1.54M NaCl mass 45.0 g of NaCl add water until total volume is 500 mL mass 45.0 g of NaCl add kg of water 500 mL water 45.0 g NaCl 500 mL mark volumetric flask

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E. Preparing Solutions Copyright © NT Curriculum Project, UW-Madison (above: “Filling the volumetric flask”)

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E. Preparing Solutions Copyright © NT Curriculum Project, UW-Madison (above: “Using your hand as a stopper”)

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**E. Preparing Solutions 250 mL of 6.0M HNO3 by dilution**

measure 95 mL of 15.8M HNO3 95 mL of 15.8M HNO3 combine with water until total volume is 250 mL 250 mL mark Safety: “Do as you oughtta, add the acid to the watta!” or AA – add acid! water for safety

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**Solution Preparation Mini-Lab**

Turn in one paper per team. Complete the following steps: A) Show the necessary calculations. B) Write out directions for preparing the solution. C) Prepare the solution. For each of the following solutions: 1) mL of 0.50M NaCl 2) 0.25m NaCl in mL of water 3) mL of 3.0M HCl from 12.0M concentrate. (don’t actually prepare this one!)

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