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1B. Looking at Water & Its Contaminants

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1 1B. Looking at Water & Its Contaminants
Learning more about the chemistry of water and how substances interact with water

2 Do Now: (day 1) Read Article on pg. 25 and write a paragraph summary addressing: water tests that were performed Concerns Other important information

3 Do Now (cont.) Concerns Other Information
Dissolved oxygen (DO) levels – will test Microorganisms – none present Dissolved matter – must consider amounts & effect of temperature on solubility – will test Suspended particles – will test Other Information No illness – water conservation tips – more water trucked in – 3 day crisis expected

4 Now what? Water experts agree that the fish kill was caused by something either dissolved or suspended in the Snake River. How can you determine the exact cause? Knowing properties of water & properties of substances that may be found in it will help. Knowing language of chemistry will help you communicate your findings. 4

5 Objectives SWBAT compare and contrast surface tension between water and alcohol SWBAT define matter and discuss the physical properties of water. SWBAT calculate density

6 1B.1 PHYSICAL PROPERTIES OF WATER
6

7 Mini- group activity- WKST U1B2
PREDICTION: How many drops of water can a penny hold without spilling over?

8 Surface Tension

9 Water is very common… on Earth
70% of Earth’s surface covered by oceans – average depth of 3 km (2 mi) Unmatched by any planet or moon in our solar system 9

10 Matter MATTER: IS ANYTHING THAT HAS MASS & OCCUPIES SPACE.
WATER IS MATTER.

11 Let’s think about… What states of matter can be observed in this winter scene?

12 Water has Physical Properties
Matter can be distinguished by its properties. Physical properties are those can be observed and measured without changing the chemical makeup of the substance Ex.- color, odor, density, melting point, boiling point, freezing point. 12

13 Water has Physical Properties
Density – Water’s density is 1.00 g/cm3 or 1.00 g/mL at 25oC – varies by temperature Ex. Mini-lab Freezing Point – 0oC at normal atmospheric conditions Any others? 13 13

14 Do Now (day 2) What physical property of water explains the “sheeting action” under the swimmers right arm?

15 Objectives SWBAT identify physical properties of substances
SWBAT differentiate between mixtures and substances and heterogeneous and homogenous mixtures SWBAT create a concept chart of all types of solutions

16 Unit 1B.2 p2 Think-Pair-Share WKST

17 “Pure” Water “Pure” water is water with absolutely nothing else dissolved or suspended in it Properties of pure water Clear Colorless Odorless Tasteless 17

18 Substances Dissolve in Water
Aqueous solutions – water based solutions SOLUTE- substance that is being dissolved SOLVENT- substance that dissolves the solute (usually water, in aqueous solutions it is water) 18

19 Substances Dissolve in Water
Sample Solute Solvent Salt Water Coffee lemonade 19

20 1B.3 MIXTURES & SOLUTIONS 20

21

22 Matter is divided into a mixture or a substance
two or more substances coming together but keeping their individual properties “Foul Water” was a mixture of water, used coffee grinds, oil, garlic powder, salt Substance: Definite composition, not physically able to separate

23 Types of Mixtures Homogeneous Mixture: Heterogeneous Mixture:
Composition is the same or uniform throughout Heterogeneous Mixture: Composition is not the same or uniform throughout.

24 2 Types of Heterogeneous Mixtures
Suspension – heterogeneous mixture containing large, solid particles that can settle out or be separated by filtration Colloid – heterogeneous mixture containing particles too small to settle out – cloudy – Tyndall effect 24

25 Solutions A solute dissolves in a solvent to make a solution
All solutions are homogeneous mixtures A solute dissolves in a solvent to make a solution Solutions are clear but not necessarily colorless A conductivity test indicates the presence of dissolved charged particles 25

26 Types of Substances Elements: Compounds: One type of atom
Two or more types of atoms chemically bonded together

27 Do Now What are the two major types of mixtures?
What is the difference between a suspension and a colloidal dispersion?

28 Objectives SWBAT review the differences between types of mixtures.
SWBAT create a concept chart of substances and mixtures and provide examples of each. SWBAT differentiate between symbol, element, compound, and molecule.

29 Create a concept chart and write an example of each category.
This could be used as a smartboard file

30 1B.4 PARTICULATE VIEW OF MATTER
30

31 Particulate Level To understand the macroscopic (large scale & readily observed) properties of water, you have to understand water’s behavior at the particulate level – the level of small particles – the level of atoms and molecules 31

32 Substances Atoms – “building blocks of matter”
Elements – made of one kind of atom Represented by symbols (H, O, Ne) & sometimes formulas (H2, O2) Molecules – made of atoms joined together – atoms can be the same or different Compounds – made of different elements combined together Represented by formulas (H2O, KCl) 32

33 Matter Substances Mixtures Homogeneous Compounds Heterogeneous
Elements Compounds Mixtures Homogeneous Solutions Heterogeneous Colloids Suspensions Refer to your text and/or handout for details. 33

34 MODELS: REPRESENTATIONS OF ATOMS & MOLECULES
These pictures are one kind of model (space filling model). 34

35 Models of Water “Seeing and Imagining Water”
Visit the online site for 1B 35

36 Modeling Matter 1B.5 PICTURES IN THE MIND 36

37 Drawing Models Sample Problem: Draw a model of two gaseous compounds in a homogeneous mixture. What do you need to know to draw your model? What is a homogeneous mixture? What might a gaseous compound look like? How many compounds are in this mixture? There is more than one drawing possible. 37

38 Do Now Describe the picture: 1. What type of mixture is this?
2. How many compounds? 3. What state of matter?

39 Objectives SWBAT classify pictures as homogeneous, heterogeneous, gas, solid, or liquid. SWBAT identity the number of different compounds in a substance or mixture SWBAT draw different mixtures and answer questions related to those pictures

40 Drawing Models Which of the following drawings best represents a homogeneous mixtures of two gaseous compounds? 40

41 Drawing Models The best answer is “b.” Not homogeneous
2 types of molecules are uniformly mixed Atoms are colored to represent different elements 3 different compounds, not 2 “b” & “c” are space-filling models. “a” is a ball-and-stick model. Both are acceptable. 41

42 Drawing Models Finish the 7 questions for the B.5 Pictures in the Mind modeling matter activity on pp 42

43 Homework Pg. 50 #1-4, 6-8, 10

44 Do Now Name 4 elements Where can you find each one?

45 Objectives SWBAT understand the requirements for the mole day project
SWBAT determine numbers of atoms in a formula SWBAT identify elements on the periodic table and understand how to write their symbols SWBAT research and create a poster about a particular element

46 1B.6 SYMBOLS, FORMULAS, & EQUATIONS
46

47 Symbols, Formulas, & Equations
The international language of chemistry includes symbols, formulas, & equations. Symbols are like letters. Formulas are like words. Equations are like sentences. 47

48 The “letters” Symbols – Elements
Elements are organized on the Periodic Table of Elements Each element is represented by a symbol Capital letter Capital letter & lower case letter Find some of these symbols on the Periodic Table. 48

49 The Periodic Table of Elements contains much more useful information than just symbols. You will be learning more about this table throughout this course. People use aluminum to make a variety of products, including foil, cans, & lightweight construction materials. 49

50 Silicon has properties that lie between those of metals and nonmetals
Silicon has properties that lie between those of metals and nonmetals. It is classified as a metalloid. One of its primary uses is in electronic devices. 50

51 Sulfur is a nonmetal used in products such as fungicides and rubber of automobile tires.
51

52 The “words” Formulas Formulas represent specific chemical substances.
Formulas are made of symbols. Formulas may include subscripts. A subscript refers back to the symbol immediately before it. A “1” is “understood” & not written. 52

53 Examples CO CO2 NH3 H2O H2SO4 1 carbon & 1 oxygen 1 carbon & 2 oxygens
1 nitrogen & 3 hydrogens H2O 2 hydrogens & 1 oxygen H2SO4 2 hydrogens, 1 sulfur, & 4 oxygens

54 Diatomic Elements Most elements exist as individual atoms and are represented with symbols. Some elements exist as 2 bonded atoms of the same element. For example, hydrogen is a diatomic gas, so is always written as H2 when it is an uncombined element. 54

55 The 7 diatomic elements are all gases, but not all gases are diatomic.
7 “GEN-U-INE DIATOMICS” The names of all diatomic elements end in GEN or INE, and U should remember them! The 7 diatomic elements are all gases, but not all gases are diatomic. Where are the 7 diatomic elements found on the Periodic Table? 55

56 The “sentences” Equations
Equations give the details of chemical reactions Chemical reactions involve the breaking & making of chemical bonds, causing atoms to be rearranged into new substances. The new substances have different properties from those of the original materials. 56

57 The “sentences” Equations
The original substances (reactants) are written first. Then, an arrow points to the new substances that are made (products). reactants  products hydrogen + oxygen  water 2H2 + O2  2H2O Note that this equation is “balanced.” The total number for each kind of atom is the same for both reactants & products. 57

58 Do Now During yesterday’s class, we used a metaphor in chemistry. Tell me what the following stood for and provide an example of each. Letters= Ex. Words= Ex. Sentences= Ex.

59 Objectives SWBAT define protons, neutrons, and electrons and determine the number of them in a given element. SWBAT draw out Lewis Diagrams of different atoms

60 Determining Electron, Proton, and Neutron Number

61 Parts of the Atom Proton- Neutron- Electron-
In nucleus, positive charge and a mass of 1 Neutron- In nucleus, neutral charge and a mass of 1 Electron- Outside nucleus, negative charge and no mass + -

62 Complete the chart Part of Atom Charge Mass Proton Neutron Electron

63 So… if this is an atom… What makes atoms different?
How is carbon different from oxygen? Different numbers of protons

64 O Oxygen 8 Element Atomic Symbol Number 15.99 Atomic Mass (Oxygen)
(number of protons) Atomic Mass (number of protons and neutrons)

65 N C Ne Practice Problems
9.01 4 N 7 C 12.02 Ne 20 Complete the missing information and include the number of protons, neutrons, and electrons. Worksheet

66

67 Do Now Draw out the atom, F (atomic #_____)

68 Objectives SWBAT draw out Lewis Diagrams of different atoms
SWBAT identify ions as cations and anions and be able to determine the formula for ions and be able to name them. SWBAT work in groups to answer questions as a conclusion to activity

69 1B.7 SYMBOLS, FORMULAS, & EQUATIONS
Developing Skills, p. 36 #1-3 1B.7 SYMBOLS, FORMULAS, & EQUATIONS 69

70 Lewis Dot Structure Drawing representing the outer most (valence) electrons EX. Worksheet

71

72 1B.8 THE ELECTRICAL NATURE OF MATTER
72

73 Static cling is best seen when the humidity is low.
Rubbing a balloon against your hair results in static electricity. Clothes taken out of the drier often show static cling. The shock that you sometimes receive after you walk across a rug & touch a doorknob is another example of matter’s electrical nature. What causes these phenomena? Static cling is best seen when the humidity is low. 73

74 Attraction & Repulsion
The electrical properties of matter can be summarized as follows: What are these positive and negative particles? 74

75 # of (+) protons = # of (-) electrons
Subatomic Particles Every neutral (uncharged) atoms contains an equal number of positively charged protons (+) and negatively charged (-) electrons. # of (+) protons = # of (-) electrons Positive-Negative attractions between the protons in one atoms the electrons in another atom hold atoms together in bonds. Most atoms also contain neutral particles having no charge (0) called neutrons. 75

76 Do Now Draw the Lewis Dot Diagrams for the following Atoms: Ca Li F

77 Objectives SWBAT identify cations and anions
SWBAT calculate the number of protons, neutrons, and electrons in different ions SWBAT name and determine the formula for several ions

78 1B.9 IONS & IONIC COMPOUNDS
78

79 Ions and Ionic Compounds
Recall: Molecules make up one kind of compound. Ions make up another kind of compound. Ions are electrically charged atoms (or groups of atoms). Ions are formed when neutral atoms gain or lose electrons. 79

80 Ions Ions are electrically charged atoms (or groups of atoms).
Ions are formed when neutral atoms gain or lose electrons. 80

81 Ions Recall: What charge do electrons carry?
Negative When atoms gain negative electrons, they form negative ions. When atoms lose negative electrons, they form positive ions. 81

82 Ions For example, sodium (Na) is # 11 on the Periodic Table.
It has 11 (+) protons and 11 (-) electrons. If it lost 1 (-) electron, it would have 11 (+) protons and 10 (-) electrons. It has one more proton than electrons, so it has a charge of -1. The symbol for a sodium ion is Na1+ or just Na+. (The 1 is understood.) 82

83 Ions For another example, chlorine (Cl) is # 17 on the Periodic Table.
It has 17 (+) protons and 17 (-) electrons. If it gained 1 (-) electron, it would have 17 (+) protons and 18 (-) electrons. It has one less proton than electrons, so it has a charge of +1. The symbol for a chloride ion is Cl1- or just Cl-. (The 1 is understood.) 83

84 Do Now List the number of protons, electrons, and neutrons in each ion
Do any of these atoms have complete valence shells?

85 Objectives SWBAT determine the formulas for ionic compounds
SWBAT name different ionic compounds

86 Ionic Compounds Oppositely charged ions connect together to form ionic compounds. For example, sodium ions (Na+) connect to chloride ions (Cl-) to make sodium chloride (NaCl), or table salt. 86

87 Sodium chloride consists of an equal number of positive and negative ions arranged in a 3-dimensional network called a crystal. A scanning electron micrograph shows the cubic structure of NaCl crystals. 87

88 A space-filling model of NaCl provides information about how the individual sodium ions & chloride ions are arranged within the salt crystal. What else does this model suggest about the sodium and chloride ions or sodium chloride? 88

89 If an ionic compound dissolves in water, the individual ions would separate from each other and spread out throughout the water. To show that they were now in an aqueous solution, an (aq) would be added after the symbols for the ions Na+(aq) Cl- (aq) 89

90 More about Ions Cation – positive ion Anion – negative ion
Monoatomic ions (or monatomic) Polyatomic ions Na+, Cl-, Mg2+, O2-, Al3+, N3- NH4+, CO32-, SO42-, PO43- 90

91 Common Ions See text p. 40 for a list of common ions. 91

92 Formulas for Ionic Compounds
2 Rules for Writing Formulas for Ionic Compounds 1. Cation first, then anion 2. Correct formula will be neutral, with the fewest number of each ion needed to make the total electrical charge zero No charges are shown in the formula. 92

93 Practice Problems NaCl CaCl2
One Na1+ and one Cl1- cancel each other out. = 0 CaCl2 One Ca2+ needs two of the Cl1- to cancel it out. = 0 Note: Negative monoatomic ions change their ending to “ide.” Examples above are sodium chloride and calcium chloride.

94 Formulas Containing Polyatomic Ions
Formulas for compounds containing polyatomic ions follow the same rules If a subscript is needed, it follows the entire polyatomic ion, which is enclosed in parentheses For example, the calcium ion has a +2 charge, and the nitrate ion has a -1 charge 94

95 Formulas Containing Polyatomic Ions
For example, the calcium ion has a +2 charge (Ca2+), and the nitrate ion has a -1 charge (NO31+). Two nitrate ions are needed to balance out the charge on one calcium ion. The formula for calcium nitrate is: Ca(NO3)2. No charges are shown in the formula. Polyatomic ions do not change their endings. 95

96 Naming Ionic Compounds
1. Name the cation, then the anion 2. Have the last few letters changed to –ide (monoatomic ions only) Ex. KF, potassium fluoride Ex. Ca(NO3)2, calcium nitrate

97 Do Now Write the formula and name the following ionic compounds
1. Ca Br- 2. PO Ag+ 3. CO NH4+ 4. Al NO3- What does the word “ionic” mean?

98 Objectives SWBAT determine the formulas for several polyatomic and monoatomic compounds SWBAT explain what a mole is and present their projects SWBAT read fun facts about the mole

99 Developing Skills, p. 41 1B.10 IONIC COMPOUNDS 99

100 Investigating Matter, pp. 42-45
IB.11 WATER TESTING 100100

101 Do Now Explain what charge the following items typically carry and WHY! Lithium Chlorine Calcium

102 Figuring out Charges

103 Do Now 1. Draw the Lewis Dot diagram for Li+.
2. Draw a picture of a heterogeneous mixture of elements X and B.

104 Objectives 1. SWBAT start to review for the test by going over the answers review questions. 2. SWBAT read and think critically about the Riverwood Fish Kill. 3. SWBAT create 2 possible hypothesis about the Riverwood fish kill.

105 Take out questions: Pg. 51 #15-24

106 1B.12 PURE AND IMPURE WATER 106106

107 Pure vs. Clean Water In the U.S., we all have access to abundant, low cost, clean, but not pure water Even if the cost was not prohibitive, it would be impossible to have 100% pure water. Atmospheric gases (e.g., O2, N2, CO2) will always dissolve in the water to some extent. 107107

108 IB.13 THE RIVERWOOD WATER MYSTERY
Making Decisions, p. 46 IB.13 THE RIVERWOOD WATER MYSTERY 108108

109 1B.14 WHAT ARE THE POSSIBILITIES?
109109

110 HOW DO YOU NARROW DOWN THE DATA TO GET THE ANSWER?
The cause of the fish kill may be related to something suspended in or dissolved in the water. What might it be? 110110

111 Chemistry at Work To learn about careers that require knowledge about what you are learning about in class right now, read text pp , Environmental Cleanup: It’s a Dirty Job… But That’s the Point 111111


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