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ULAANBAATAR CITY’S AIR POLLUTION – SOURCE APORTIONMENT - MANAGEMENT
S.Lodoysamba, National University of Mongolia
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Contents Air pollution of Ulaanbaatar City,
What is main sources of pollution, Management of mitigation of UB air pollution 1
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Management of air pollution mitigation
Starts from measurements, Air pollution concentration, Identification and apportionment of pollution sources, Modeling, Health impact study, Air pollution mitigation scenarios, Health benefit calculation Planning a target, Activity Monitoring Ends with measurement. 2
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Main Air Quality Indicators
- Sulfur Dioxide (SO2) - Nitrogen Dioxide (NO2) PM (Particulate Matter) PM10 PM 2.5 - Carbon Monoxide (CO) - Ozone (03)
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Particulate Matter Distribution
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Health Effect of PM 5
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Methodology Position of sampler: UB City- Nuclear Research Center
Zuun Ail 3 Horoolol Duration: – Flow rate of sampler: 16 l/мin (18-14) Height of sampling: 1.6м, 6m, 4m Sampling frequency: Twice a week Sampler: GENT Sampler with Polycarbonate filters Type of analysis: PIXE ВС measurement: Reflectometer Number of samples: 400 ( ) Data interpretation was made using software EPA PMF1.1(USA) PIXE analysis were done in the New Zealand Institute of Geosciences and Nuclear Sciences, 30 elements are analysed
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Height of sampling head from the ground (m)
Used samplers Sampling site number Characteristics Site position PM size fraction Height of sampling head from the ground (m) Remarks 1 Kosa Monitor (Japanese make), Measures PM10 and PM2.5. Beta absorption.. Continuous monitoring. Gives hourly values. 106o54,704 47o55,220 PM10 and PM2.5 20 2, 3 GENT Sampler, Schulberger Model 250, Measures PM and PM2.5. Polycarbonate (nuclepore) filters. 106o58,311 47o54,811 PM and PM2.5 1.6;6 Elemental analysis, Black carbon determination 4, 7, 8 Dust Trak-8520, measures PM2.5 or PM10. Laser light scattering. Continuous monitoring; Gives hourly values. 106o54,159 47o54,719 PM2.5 3;2;3 5 Rotary Bebicon, Type 35RC- 28SD5 (Japanese make). Measures PM10, 15 l/min, filter. 106o52,967 47o53,64 PM10 3 Replaced by EcoTech monitor (beta absorption) from Nov.2008 6 Partisol FRM-Model 2000, Measures PM10, 16.7 l/min, filter (nuclepore). 106o52,167 47o55,582 4
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Projects RCA/ IAEA PROJECT IMPROVED INFORMATION ABOUT URBAN AIR QUALITY MANAGEMENT, RAS/7/013, CHARACTERIZATION AND SOURCE IDENTIFICATION OF PARTICULATE AIR POLLUTION IN THE ASIA REGION RAS/7/015, АГААРЫН ЧАНАР БА БОХИРДОЛЫН ЗӨӨГДЛИЙГ СУДЛАХ Шинжлэх ухаан, технологийн сэдэв, АГААРЫН БОХИРДЛЫН ҮҮСГҮҮР, ТЭДНИЙ БОХИРДОЛД ОРУУЛЖ БУЙ ХУВИЙГ РМ2,5, РМ10 АРГААР ТОДОРХОЙЛОХ СУДАЛГАА Шинжлэх ухаан, технологийн сэдэв, ESTABLISHMENT OF AN AIR QUALITY MONITORING AND HEALTH IMPACT BASELINE (AMHIB) FROM AIR POLLUTION IN ULAANBAATAR (UB) CITY, MONGOLIA. World Bank Contract , TA (MON) : ULAANBAATAR CLEAN AIR Evaluation of Air pollution mitigation in Ulaanbaatar City and its Health Impact Measuring and sharing PM2.5 through Social Media
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Sampling Sites
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PM10, PM2.5 Concentrations PM10 PM2.5 Months NAMHEM (1) NRC (2)
Zuun ail (3) CLEM (5) 3 khoroolol (6) Average Jun-08 28.9 160.2 154.3 120.0 187.3 130.2 Jul-08 7.2 126.7 112.5 17.6 56.4 64.1 Aug-08 238.0 179.1 27.9 85.4 132.6 Sep-08 8.0 221.4 131.4 38.8 70.4 94.0 Oct-08 37.7 223.1 127.6 79.6 161.2 125.8 Nov-08 128.5 365.8 673.2 112.9 800.8 416.2 Dec-08 277.5 180.2 926.8 61.4 693.5 427.9 Jan-09 173.7 200.1 1850.0 65.8 932.3 644.4 Feb-09 115.4 302.1 1007.3 86.0 463.7 394.9 Mar-09 62.5 205.2 488.6 63.7 358.2 235.6 Apr-09 34.0 316.0 300.2 59.8 272.8 196.5 May-09 32.5 501.2 739.3 33.6 183.1 297.9 Annual average 82.3 253.3 557.5 63.91 355.4 262.5 Months NAMHEM (1) NRC (2) Zuun ail (3) 6 buudal (4) Bayan hoshuu (7) Airport (8) Average Jun-08 16.9 29.0 25.5 84.6 169.3 65.1 Jul-08 1.2 21.7 13.3 12.1 Aug-08 5.7 64.9 48.7 39.7 Sep-08 8.0 18.8 37.9 37.3 47.0 37.6 31.1 Oct-08 38.1 46.3 38.7 281.3 498.3 184.7 181.2 Nov-08 81.4 121.6 330.6 527.3 567.5 406.3 339.1 Dec-08 224.5 106.9 575.5 1205.1 1421.2 892.9 737.7 Jan-09 138.3 121.3 1291.1 858.5 1536.1 514.5 743.3 Feb-09 99.6 141.4 358.1 342.4 971.3 413.3 387.7 Mar-09 45.3 80.1 345.5 179.3 321.0 207.3 196.4 Apr-09 25.2 128.8 119.6 93.9 137.3 91.8 99.4 May-09 24.3 279.3 370.8 41.9 58.9 52.9 138.0 Annual average 59.1 96.7 296.3 365.2 617.6 297.1 288.6
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PM 10 Concentration
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PM 10 Concentration Time Series
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PM 2.5 Concentration
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PM 2.5 Concentration Time Series
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Monthly Average Concentrations
PM10 PM2.5
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Monthly Average Concentrations
Average Concentration Calculated Average Concentration Measured Site No Site name PM2.5 PM10 2 NRC 96.7 253.3 3 Zuun ail 296.3 557.5 4 6 Buudal 365.2 - 6 3 khoroolol 355.4 7 Bayanhoshuu 617.6 8 Airport 297.1 Average all stations 334.6 388.7 Area РМ10 (mg/m3) РМ2.5 Exceedence Central part UB 300 150 6 Ger area UB 7-18
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Monthly Average Concentrations
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Polluted Ulaanbaatar 18
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Who is polluting the Ulaanbaatar air?
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Chemical Analysis Set-up
Experimental setup of the New Zealand Institute of Geosciences and Nuclear Sciences
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PMF mass vs Gravimetric mass
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Elemental Concentrations (ng/m3)
Elements Arithmetic Mean StdDev Median Maximum Minimum Samples > LODa S/N PM 2.5 51800 91400 28200 5700 BC 7290 10454 4242 94206 680 235 2.75 Na 290 425 112 2642 88 0.13 Mg 326 276 2083 31 200 0.62 Al 1150 1224 745 7627 227 0.81 Si 2305 1740 1871 10554 129 236 17.2 S 1969 3978 900 40079 125 17.55 Cl 139 133 849 12 2.14 K 324 239 243 1558 35 7 Ca 789 559 652 3194 50 11.92 Ti 37 33 28 156 191 0.27 Mn 15 14 11 65 178 0.18 Fe 523 388 416 2150 26 Cu 10 29 3 373 105 0.21 Zn 44 54 30 400 213 0.55 Pb 73 525 0.08
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PM 2.5 PROFILES
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Mass Contribution PM2.5 (Example NRC)
Source PM2.5 mass μg/ m3 Soil 5.0 (0.3)a Coal combustion 1 12.2(1.6) Coal combustion 2 11.5(0.9) Motor vehicles 1.9(0.2) Biomass burning 1.1 (0.1) Road dust 2.9 (0.2) Zinc 0.6(0.1)
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Pollution Source Apportionment
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Pollution Source Apportionment PM10
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Daily time Series of PM concentrations (Example TV site, GTZ station)
Working days Weekend
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Toxic Elements 29
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Time Series of Toxic Elements
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Air Quality Index Center UB Ger Area UB Concentrations AQI Ozone 14.3
mg/m3 6 PM2.5 150.0 200 PM10 300.0 173 CO 2214 21 SO2 18.1 10 NOx 30.0 Conditional pollutant Average of WORST two 187 Average of ALL 82 Concentrations AQI Ozone 14.3 mg/m3 6 PM2.5 500.0 500 PM10 625.0 582 CO 2214 21 SO2 18.1 10 NOx 30.0 Conditional pollutant Average of WORST two 541 Average of ALL 224
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Conclusion 1 Main pollution sources are:
PM10- Soil erosion, Combustion, Motor vehichle, Biomass burning, PM2.5- Coal combustion, Motor Vehicle+Road dust, Biomass burning, Soil Ulaanbaatar is most polluted capital city of the world; @ 50% of PM concentrations corresponds to ignition phase (cold start) and reloading of stoves; There is presence of toxic elements: Hg, Ni, V, F, Cl, Br, As in the air; Pb in the air is below the standard; AQI is 82 (Moderate) in the Central area and more than 200(Very unhealthy) in the Ger areas;
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What to do? 33
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STOVE EMISSION AND EFFICIENCY TESTING LABORATORY
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Testing stoves 35
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Data acquisition system
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SEET Lab. Diagram 37
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Operator room
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Gases 39
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Temperature Measurements
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Particle Measurement 41
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MONGOL STOVE
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BLUD Mode of Mongol Stove
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MODIFIED MONGOL STOVE
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GTZ-7.5 STOVE
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Conclusion 2 PM Emission can be reduced more than 99% using raw coal, The PM emissions are so low that for much of the time the improved stove substantially cleans the ambient air that passes through it. The chimney gases are usually cleaner than the outdoor air.
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Management ?
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Air Pollution Concentration reductions due to emission reduction scenarios.
PM emissions needs to be reduced with about 94% to reach Mongolias own air quality standards for PM10:
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Annual Health Benefits From Abatement Scenarios - benefits of different solutions accrue at different times.
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The Cost of Delaying Short Term Measures: The decisive Argument for the project!
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Some of the Lessons: Paid off to make a full-scale AQM study. Most critical argument for getting actual the projects through: - Health Impacts (physical & economic). - Cost effectiveness of abatement options, Cost of Inaction. - Comparing concentration levels with other countries/cities.
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Comparison of PM concentration at Zuun ail
Good News Comparison of PM concentration at Zuun ail
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Good, but not very good (NRC 2004-2012)
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Thank You for Your Attention!
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XRF Spectrometer SPECTRO Xepos, GENT, GRIMM Samplers
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