1. VOC’s/CFC’s and Ozone Dan Gloudemans

2. Presentation Overview VOC’s Ozone Formation, natural/other VOC’s Destruction, natural/other CFC’s Measurement / EPA AQI Ozone hole/ Home Ozone exposure What is being done about Ozone? Clean Air Act OTC CARB/OTC Ozone in the Midwest?

3. Brief VOC overview Organic Compound – contains carbon and hydrogen Ie: octane, butane…, sugar VOC = Volatile Organic Compound, organics that evaporate easily VOC’s are compounds that lead to the formation of ground level Ozone – “smog” VOC’s can be found in anything from paints to deodorant

4. Good/Bad Ozone – “Good up high, bad nearby” Ozone is beneficial in Stratosphere blocks many ultra violet rays (λ < 320 nm) But is very harmful in Troposphere it is a highly reactive gas that can affect the normal functioning of the lungs

5. Formation of Ozone (O3) “natural” Ozone first formed - ~500 million years ago, after release of Oxygen Ozone formation – atomic Oxygen Most natural ozone formation occurs in the Tropics “Chapman reactions” So called after S. Chapman who is famous for his paper 'A theory of upper-atmosphere ozone, Mem. Roy. Meteorol. Soc.' in 1930 which set out the first theoretical explanation of the ozone layer in the stratosphere.

6. … Other formation of Ozone - Groundlevel Photochemical reaction of NOx (collectively NO and NO2) with VOC’s in the presence of sunlight

7. Destruction of Ozone - “natural” Ozone destruction by UV radiation – very similar fashion Ozone concentration highest in the poles!

8. …Other Destruction of Ozone CFC’s among others Organic molecules – H’s replaced with Halogens Cl and F

9. Measurement of Ozone Reported in Dobson Units (DU) Imagine all ozone on the surface of the earth evenly (vs. reality of the strato/troposhpere) 1 DU = 0.01 mm of Ozone 300 DU a typical value Thus, 300 DU = 3 mm O3 spread evenly across earth

10. AQI – Air Quality Index Measures presence of 5 pollutants ground-level ozone particle pollution carbon monoxide sulfur dioxide nitrogen dioxide 0-500 Scale 100 is National Air quality standard ~200 – unhealthy to very unhealty – whole population could be affected >300 - Hazardous

11. The “Ozone Hole” Over Antarctica First noticed in 1970’s British Antarctic Survey (BAS) First discovered/measured in 1985 TOMS (Total Ozone Mapping Spectrometer). Findings thought faulty Eventually confirmed Graph shows measurements above the Halley Bay research station

12. Home Exposure to VOC’s EPA's Total Exposure Assessment Methodology (TEAM) Found that VOC level are often 2 to 5 times higher indoors The relative danger varies greatly Length and level of exposure nose and throat discomfort, headache, allergic skin reaction, nausea, fatigue, dizziness.

13. What is being done about Ozone? US adopted Montreal Protocol in 1987 – limit CFC’s States most dangerous phased out by 2000 Clean Air Act All class I substances outlawed by Jan 1 2000 chlorofluorocarbon-11 (CFC–11) chlorofluorocarbon- 12 (CFC–12) + others All class II substances outlawed by Jan 1 2030 hydrochlorofluorocarbon-21 + various other Ozone “Action Days” Days > 90F, little or no wind Encourage to reduce emmisions, and protect

14. OTC – Regional effort OTC = Ozone Transport Commission Several northeastern states (13 total) Created under Clean Air Act (CAA) amendments in 1990 Focus on Ground Level Ozone - specifically NOx emissions - during May – Sept “Ozone Season” NOx Budget Program – sell or store unused allowances Regional emissions trading program

16. OTC - Progress

17. OTC – but room for More progress

18. CARB/OTC California Air Resource Board In addition to NOx, these two regulate VOC emmisions Consumer Products

19. Wisconsin Ozone? Yes! Southeastern Wisconsin During Action Days Combining errands Fueling car gas tanks at night Mowing lawns after 6:00 p.m Properly inflating vehicle tires Carpooling, biking, walking or riding the bus to work

20. Midwestern Ozone problem areas US EPA, Region 5 What about Minnesota?

21. Questions?

22. References EPA – “air Now” How VOCs Contribute To Formation Of Ground-Level Ozone. Chemical & Engineering News, 1/24/2005, Vol. 83 Issue 4, p26, 1/3p; (AN 16120478) How VOCs Contribute To Formation Of Ground-Level Ozone. Chemical & Engineering News; 1/24/2005, Vol. 83 Issue 4, p25, 3p, 1c “SMOG, POLICY AND CHEMISTRY.” Chemical & Engineering News http://www.dnr.state.wi.us/org/aw/air/ozone/OzActionNotice.htm