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Published byNorman Hopkins Modified over 9 years ago
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Solutions Solubility Solubility Rules
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Water Most common solvent A polar molecule O - a hydrogen bond H +
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Hydrogen Bonds Attract Polar Water Molecules
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Solute and Solvent Solutions are homogeneous mixtures of two or more substances Solute The substance in the lesser amount Solvent The substance in the greater amount
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Nature of Solutes in Solutions Spread evenly throughout the solution Cannot be separated by filtration Can be separated by evaporation Not visible, solution appears transparent May give a color to the solution
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Types of Solutions air O 2 gas and N 2 gas gas/gas soda CO 2 gas in water gas/liquid seawater NaCl in water solid/liquid brass copper and zinc solid/solid (alloy)
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Solute and Solvent Identify the solute and the solvent. A. brass: 20 g zinc + 50 g copper solute= 1) zinc 2) copper solvent = 1) zinc 2) copper B. 100 g H 2 O + 5 g KCl solute = 1) KCl 2) H 2 O solvent = 1) KCl 2) H 2 O
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Solution A. brass: 20 g zinc + 50 g copper solute= 1) zinc solvent = 2) copper B. 100 g H 2 O + 5 g KCl solute = 1) KCl solvent = 2) H 2 O
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Identifying Solutes Identify the solute in each of the following solutions: A. 2 g sugar (1) + 100 mL water (2) B. 60.0 mL ethyl alcohol(1) and 30.0 mL of methyl alcohol (2) C. 55.0 mL water (1) and 1.50 g NaCl (2) D. Air: 200 mL O 2 (1) + 800 mL N 2 (2)
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Solution Identify the solute in each of the following solutions: A. 2 g sugar (1) B. 30.0 mL of methyl alcohol (2) C. 50 g NaCl (2) D. 200 mL O 2 (1)
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“Like dissolves like” A ____________ solvent such as water is needed to dissolve polar solutes such as sugar and ionic solutes such as NaCl. A ___________solvent such as hexane (C 6 H 14 ) is needed to dissolve nonpolar solutes such as oil or grease.
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Saturated and Unsaturated A saturated solution contains the maximum amount of solute that can dissolve. Undissolved solute remains. An unsaturated solution does not contain all the solute that could dissolve
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Unsaturated or Saturated? At 40 C, the solubility of KBr is 80 g/100 g H 2 O. Indicate if the following solutions are (1) saturated or (2) unsaturated A. ___60 g KBr in 100 g of water at 40 C B. ___200 g KBr in 200 g of water at 40 C C. ___25 KBr in 50 g of water at 40 C
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Solution At 40 C, the solubility of KBr is 80 g/100 g H 2 O. Indicate if the following solutions are (1) saturated or (2) unsaturated A. 2 Less than 80 g/100 g H 2 O B. 1 Same as 100 g KBr in 100 g of water at 40 C, which is greater than its solubility C. 2 Same as 60 g KBr in 100 g of water, which is less than its solubility
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Is it soluble? Which of the following solutes will dissolve in water? Why? 1) Na 2 SO 4 2) gasoline 3) I 2 4) HCl
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Solution Which of the following solutes will dissolve in water? Why? 1) Na 2 SO 4 Yes, polar (ionic) 2) gasoline No, nonnpolar 3) I 2 No, nonpolar 4) HClYes, Polar
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Solubility The maximum amount of solute that can dissolve in a specific amount of solvent usually 100 g. g of solute 100 g water
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Temperature and Solubility of Solids TemperatureSolubility (g/100 g H 2 O) KCl(s)NaNO 3 (s) 0°27.6 74 20°C34.0 88 50°C42.6114 100°C 57.6182 The solubility of most solids (decreases or increases ) with an increase in the temperature.
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Temperature and Solubility of Solids TemperatureSolubility (g/100 g H 2 O) KCl(s)NaNO 3 (s) 0°27.6 74 20°C34.0 88 50°C42.6114 100°C 57.6182 The solubility of most solids increases with an increase in the temperature.
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Temperature and Solubility of Gases TemperatureSolubility(g/100 g H 2 O) CO 2 (g)O 2 (g) 0°C0.340.0070 20°C0.170.0043 50°C0.0760.0026 The solubility of gases (decreases or increases) with an increase in temperature.
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Temperature and Solubility of Gases TemperatureSolubility(g/100 g H 2 O) CO 2 (g)O 2 (g) 0°C0.340.0070 20°C0.170.0043 50°C0.0760.0026 The solubility of gases decreases with an increase in temperature.
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Solubility of Gases A. Why would a bottle of carbonated drink possibly burst (explode) when it is left out in the hot sun ? B. Why would fish die in water that gets too warm?
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Solubility curves
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Summary
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