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Bonding in Transition Metal Compounds

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Presentation on theme: "Bonding in Transition Metal Compounds"— Presentation transcript:

1 Bonding in Transition Metal Compounds
Does the octet rule (or something like it) work for these compounds? Counting d electrons. CrO42- Ni(NH3)62+ Cr(H2O)5Cl2+

2 Counting d-electron Configurations

3 Does the octet rule (or something like it) work for these compounds?
Special Case: Counting d electrons for “organometallics” Fe(CO)5 Ni(CO)4 Cp2Fe Bz2Cr

4 Draw a Lewis Structure for Ni(NH3)62+

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6 Crystal Field Theory

7 Crystal Field Theory

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11 Donor-Acceptor MO Theory

12 Molecular Orbital Theory: Full

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15 Molecular Orbital Theory: Simple

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17 Counting d-electron Configurations

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20 MO diagrams with pi-bonding ligands

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