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Ch 7 The Mole and Chemical Composition

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1 Ch 7 The Mole and Chemical Composition
What are some things that are sold by weight instead of by number? Which would need a larger package, a kilogram of pencils of a kilogram of drinking straws? If you counted one person per second, how many hours would it take to count the 6 billion people in the world?

2 Mole Unit to measure amount of substance whose particles are e same as the number of atoms in exactly 12 g of carbon-12 Avogadro’s number x 1023 Counting unit for large number of particles too small too see

3

4 Molar mass Mass in grams of one mole of a compound or element
Relate moles to mass

5 Moles of an element Use moles to count by weight.
? Moles of carbon are in 26g ?= 26 g C x 1mol C = 26 molC =2.2 12.0g C mol 2.2molC x 6.02x1023atoms=1.3x1023 1molC C atoms

6 Compounds ? Molecules CO2 in 0.75moles
?=0.75mol CO2x 6.02x1023molecule 1mol CO2 = 4.5x1023molecules CO2

7 Relative Atomic Mass Isotopes have different masses
Isotopes have different numbers of neutrons Periodic table – mass is average of all naturally occurring isotopes

8 Chemical Formulas and Moles
Formulas- what elements & how many of each Covalent compounds – how many of each element Ionic compounds – simplest ratio of cations to anions Polyatomic ions – simplest ratio of cations to anions

9 Molar Mass of a compound
molar mass of elements multiplied by subscript C12H22O11 C = 12.0g x 12 = 144.0g H = 1.0g x 22 = g O = 16.0g x 11 = 176.0g total = g

10 Formulas and Percentage Composition
Analyze compounds to find percentage composition Percent by mass of each element in a compound Empirical formula- simplest ratio among the atoms found in a compound C H3 = C2 H6 empirical molecular

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12 Step one

13 Step 2

14 Step 3

15 Summary

16 Percentage Composition

17 Find mass of one element
Calculate the mass of zinc in a g sample of zinc nitrate, Zn(NO3)2. Items Data Mass of zinc nitrate 30.00 g Formula of zinc nitrate Zn(NO3)2 Molar mass of zinc nitrate g/mol Mass of zinc in the sample ? g

18 Find % of Zn

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20 Determining Empirical Formulas

21 Empirical Formulas Determine the empirical formula for an unknown compound composed of 36.5% sodium, 38.1% oxygen, and 25.4% sulfur by mass.

22 Steps 1-4

23 Compute

24 Mole ratios From the calculations, the simplest mole ratio is 2 mol Na :3 mol O: 1 mol S. The simplest formula is therefore Na2O3S. Seeing the ratio 3 mol O : 1 mol S,

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26 Molecular Formula A compound is analyzed and found to have the empirical formula CH2O. The molar mass of the compound is found to be 153 g/mol. What is the compound’s molecular formula?

27 Plan

28 Compute

29 Comparing Formulas


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