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ISOTOPES AVERAGE ATOMIC MASS
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ISOTOPES Atoms of the same element with different mass numbers
Atoms with the same number of protons, but different numbers of neutrons. ISOTOPES OF CHLORINE 35Cl 37Cl Chlorine Chlorine - 37
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FACTS ABOUT ISOTOPES Almost each element is found in the Universe as a mixture of isotopes Every isotope is found in nature in a fixed percentage called Isotopic Abundance Example: Magnesium can be found as a mixture of three isotopes 79% Magnesium-24, 10% Magnesium-25 and 11% Magnesium-26
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FACTS ABOUT ISOTOPES These percentages are different for each element
Each element has a particular number of isotopes The isotope notation includes the name or symbol of the element followed by the atomic mass. Example: Magnesium-25 or Mg-25
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FACTS ABOUT ISOTOPES The existence of isotopes explains the fact that atomic mass is a decimal for most elements Isotopes of one element have the same chemical behaviour but slightly different physical properties Example: boiling point or melting point
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FACTS ABOUT ISOTOPES They have lots of real life applications e.g. medical There are almost 2000 isotopes found The isotopes of radioactive elements are called Radioisotopes
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LEARNING CHECK Naturally occurring carbon consists of three isotopes, 12C, 13C, and 14C. State the number of protons, neutrons, and electrons in each of these carbon atoms. 12C C 14C #p _______ _______ _______ #n _______ _______ _______ #e _______ _______ _______
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AVERAGE ATOMIC MASS Where: Aav = average atomic mass
Atomic mass is the weighted AVERAGE ATOMIC of all the atomic masses of the isotopes of that atom correlated with their isotopic abundances. Where: Aav = average atomic mass (%) = isotopic abundance
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PRACTICE ONE Cl-35 is about 75.5 % and Cl-37 about 24.5% of natural chlorine. Calculate the average atomic mass for Chlorine.
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PRACTICE TWO Assume that the element 108Uno is synthesized and that the sample contains 25.2% 272Uno (271.4 amu), 30.8% 273Uno (272.3 amu) and 44.0% 275Uno (274.2 amu). Calculate the average atomic mass of Uno.
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CALCULATING ISOTOPIC ABUNDANCE
Steps: Assign variables for the isotopic abundances; x and y Write the equation for isotopic abundances: x + y = 1 Write the equation for the Average atomic mass: AAV = A1X1 + A2X2 Set both equation as a linear system and solve for x and y by substitution
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PRACTICE THREE Boron exists as two naturally occurring isotopes:
B-10.01a.m u and B-11.01a.m.u. Calculate the isotopic abundance of each isotope of Boron.
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PRACTICE FOUR Silver (Atomic weight ) has two naturally-occurring isotopes with isotopic weights of and What is the percentage abundance of each isotope in Silver?
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