Announcements in class 2/5/07 Movie Wed. Don’t miss it! Material will be on the exam. Only one showing. Problem Set 4 is posted online. Print it out yourself. PS 4 is due in class Monday, 2/12/07 PS 5 will be posted Mon. 2/12 and due Wed. 2/21
Outline f-ratio Phosphorous Cycling Carbon Cycling
Nitrate Phytoplankton Upwelling Mixing Vertical Flux N 2 Fixation Rivers Deposition PON DIN Euphotic Zone
f-ratio Upwelling Zone 0.8 Gyre 0.1 Global Average < 0.5 New Production New + Regenerated Production
Sediment traps to catch sinking particles
Sustainable yields
Nitrate Phytoplankton Upwelling Mixing Vertical Flux N 2 Fixation Rivers Deposition PON DIN Euphotic Zone Fishing
New Production Oligotrophic gyres Upwelling regions
↑Annual ↓Perennial r-selected K-selected
Chemical Forms – P PO 4 3- (Phosphate) Organic
The cycling of Phosphorus Dissolved InorganicParticulate Organic uptake excretion Runoff upwellingsinking decomposition Balance maintained via weathering of rock
Chemical Transformations – P Assimilation PO 4 3- → Organic Phytoplankton or other autotrophs Remineralization Organic → PO 4 3- Heterotrophs Excretion Organic → Dissolved Heterotrophs and Autotrophs
Experimental Lakes Area Lake 227
Lake 226 C, N, P Eutrophic algal blooms C, N
Lake 227
Oligotrophic LakeEutrophic Lake micrograms/liter phosphorus> 15 micrograms/liter phosphorus
Chemical forms of Carbon Inorganic –CO 2 –bicarbonate ion HCO 3 - –carbonate ion CO 3 2- Organic (fixed …) Dissolved (DIC and DOC) Particulate (biomass and detritus)
Carbonate Equilibrium CO 2 «» HCO 3 - «» CO 3 2- dissolved bicarbonate carbonate CO 2 ↑ HCO 3 - ↑ CO 3 2- ↑ pH ↓ Ocean pH 8.2
Source NASA
Source R. Rohde
C Cycle “Food Web” Diagram P Z B Dissolved Inorganic Carbon Dissolved Organic Carbon Main Thermocline CO 2 Dissolved Inorganic Carbon Dissolved Organic Carbon Deep Remineralization Sinking Particles
Pteropod Foraminifera Coccolithophore
Carbon Solubility Pump –Solubility of CO 2 is greater in cooler water –Deep water formation ↑DIC –C pumped from atmosphere to ocean Biological Pump –POC and PIC sinking, DOC downwelling –C pumped from surface ocean to depth
Deep Water Formation Source: USC
Thermohaline circulation
Saharan Dust Storm Over the Atlantic
The Cycling of Silicon Dissolved InorganicParticulate Organic uptake Runoff upwellingsinking dissolution Balance maintained via weathering of rock