Arcs – a critical sink in the global C cycle? Interesting features Ca, Mg rich compositions Fast kinetics in volc rocks Tectonically active Wet High erosion.

Slides:



Advertisements
Similar presentations
Phase Diagram for Water
Advertisements

Carbonate System and pH
Carbon exchange Photosynthesis Respiration Decay Soil Organic Matter Vegetation Weathering & Runoff Rock Formation Sedimentary Rock Coal, Oil and Gas Phytoplankton.
High-Mass Star-Forming Regions in the G333 Cloud Indra Bains & the DQS team.
Lecture 19 The Ocean Nitrogen Cycle Sinks/Sources Sink - Denitrification Reactions Distributions Source - Nitrogen Fixation Reactions Distributions The.
Reading: Chapter 4 Lecture 24. Forces Stabilizing Climate, Carbonate-Silicate Cycle.
Impact of Changes in Atmospheric Composition on Land Carbon Storage: Processes, Metrics and Constraints Peter Cox (University of Exeter) Chris Huntingford,
5.1 Weathering.
Today's lecture More Aqueous Geochemistry First a look back at calcite solubility as a function of pH and Temperature.
The Inorganic Carbon Cycle GyörgyVÁRALLYAY György VÁRALLYAY Research Institute for Soil Science and Agricultural Chemistry of the Hungarian Academy of.
A new database of infrared mineral spectra for astrophysics by Anne M. Hofmeister Many thanks to Janet Bowey, Angela Speck, and Mike Barlow Star sapphire.
METO 637 Lesson 21. Mars Much of the surface is very old and cratered but there are also younger rift valleys, ridges, hills and plains. No plate tectonics.
Figure 3. The MJO-related vertical structures of MACC CO. CO are averaged between 15ºN – 15ºS. Rainfall is averaged between 5ºN – 5ºS. ABSTRACT. We report.
Lecture 9: Ocean Carbonate Chemistry: Carbonate Reactions
Lecture 9 – What Controls the Composition of Seawater
1 Evolution of Oxygen in the Atmosphere “Early” reactions driven by high energy sunlight H 2 O --- h,  H + OH CO h,  CO + O Recombination reactions.
Oceanic Carbon Cycle Upwelling brings nutrients (e.g. PO 4 ) to euphotic zone Photosynthesis (Dissolved Inorg  Particulate Organic Matter) Recycling.
Impacts of Climate Change on Physical Systems PPT
Lecture Goals To review how pH and alkalinity work.
Principles of Mass Balance
Brief Notes on AIRS May 9, 2007 Group Meeting. Atmospheric InfraRed Sounders (AIRS) 650 – 2670 cm – 2670 cm channels 2378 channels Objectives:
Chemical Weathering Definition: transformation/decomposition of one mineral into another Mineral breakdown carbonate dissolves primary minerals --> secondary.
Factors that Affect the Rate of Chemical Weathering.
GEOLOGIC CARBON CYCLE Textbook chapter 5, 6 & 14 Global carbon cycle Long-term stability and feedback.
Biogeochemical cycles - The Hydrosphere The hydrosphere contains all the water on earth. Ocean represent 97% of it so we will focus mainly on oceans, but.
The Geologic Record and the Environment. Geologic Time Evidence suggests Earth is approximately 4.6 billion years old! Earth’s history is divided into.
I am not Mark Pagani Louis Derry - Cornell. 1 gigaton = 1x10 9 tons = 1x10 15 g (1 petagram, Pg) 5×10 4 Tmol 3.2×10 6 Tmol 5.5×10 9 Tmol ≈ 6-8 Tmol/yr.
The Biogeochemical Carbon Cycle: CO 2,the greenhouse effect, & climate feedbacks Assigned Reading: Kump et al. (1999) The Earth System, Chap. 7.
Weathering The Chemical and physical breakdown of material (rock).
Climate--The average weather over years and longer… Chapter 1 frontispiece. Satellite view looking east from Patagonia over southern Argentina and the.
The Chemistry of Extrasolar Planetary Systems J. Bond, D. O’Brien and D. Lauretta.
Atmospheric Composition & Air Quality (MAQ-34806) Lecturers: Maarten Krol Wouter Peters.
Another example: Carbonic Anhydrase. Zn Active site in  -carbonic anhydrase.
Geological Features. Grand Canyon This feature was formed over many years of erosion and weathering. Also from the course of the Colorado River itself,
Temperature Anomaly (  C) Annual Solar Radiation (W m -2 )
Plan 1.Fluxes and why the mantle matters 2.Earth’s buffer – ocean 3.Earth’s buffer – weathering 4.A question.
Introduction to Kinetics Lecture 14. Reading in Chapter 5 Read sections 5.1 through (p.160 to p. 199) and section 5.7 (p ). You won’t be.
Weathering: the physical and chemical modification of rocks… Physical Weathering: Tearing a page of paper to bits… …does NOT change the composition. It’s.
PH and Chemical Equilibrium. Acid-base balance Water can separate to form ions H + and OH - In fresh water, these ions are equally balanced An imbalance.
Carbon cycle theme #1 The Earth’s carbon cycle has a stabilizing mechanism against sudden addition of CO 2 to the atmosphere – About 50% of carbon emission.
Rapid soil CO 2 drawdown during incipient weathering of a granular basaltic landscape Joost van Haren, Katerina Dontsova, Greg Barron-Gafford, Peter Troch,
Arcs and global biogeochemical cycles Louis Derry Cornell University How does weathering, erosion and geothermal activity in arc terranes impact global.
Weathering, Erosion & Deposition ESS Weathering The breaking up of rock into smaller pieces.
Greenhouse Gas: Carbon Dioxide Thuan, Marko. Carbon Dioxide (CO 2 ) Colorless & odorless gas Ice Age (400 kyBCE) ppm Preindustrial (1700s)
Rate of Weathering- Rock Composition- Amount of Exposure (surface area)- The amount of exposure a rock is showing affects it’s rate of weathering because.
Carbonate Solubility Solubility Dissolution mechanisms Dissolution rate expressions Saturation state in the ocean T, P, and CO 2 release In situ [CO 3.
Kinetics State of reactionscan be described a couple of ways: State of reactionscan be described a couple of ways: Equilibrium – overall reactions (our.
Carbonate System and pH Why study the carbonate system? Why study the carbonate system? Involves carbonic acid – an example of an acid-base reaction Involves.
Location of Large Igneous Provinces:
III. Atoms, Elements and Minerals
The Global Oxygen Cycle
Chapter 8—Part 2 Basics of ocean structure The Inorganic Carbon Cycle/
Saturday, 14 February 2015: 8:30 AM-11:30 AM
Barton Springs Aquifer Geochemistry Jackson School of Geosciences
Climate Modeling Primer
The Rock Cycle.
Temperature, Salinity and Acidification
Temperature, Salinity and Acidification
6. Land plants C354H552O299N24P Redfield C106H263O110N16P
THERMOHALINE CIRCULATION
Ocean chemistry strongly linked to land (chemical weathering),
Carbon cycle theme The Earth’s carbon cycle has a stabilizing mechanism against sudden addition of CO2 to the atmosphere About 50% of carbon emission is.
Global Distribution of Karst
Surface Features Review
Elective Topics for Reading, Discussion, and Writing: Select your first choice Glacial eras, plate tectonics, mountain building and erosion, and the.
Plate Tectonics.
Earth Science Newspaper
Geologic carbon cycle Textbook chapter 5, 6 & 14 Global carbon cycle
Table 9. Water quality of DiSi- Mudawarra groundwater resources
Presentation transcript:

Arcs – a critical sink in the global C cycle? Interesting features Ca, Mg rich compositions Fast kinetics in volc rocks Tectonically active Wet High erosion rates Frequent resurfacing Underrepresented in our data and our thinking No big rivers Large groundwater fluxes (unmeasured!) Milliman: sed yields are ≈10x global average MgSiO 3 + 2CO 2 + 3H 2 O Mg HCO H 4 SiO 4 “MgCO 3 ” + SiO 2 + CO 2 net = -1 CO 2 per mol Ca or Mg weathered Climate sensitivity?

Arc rivers are different …. n=74 n=156

Basalt weathering shows strong climate sensitivity. (data mostly from Dessert et al., 2003) T dependence: exponent ≈ 0.08 is similar to laboratory Arrhenius rates, e.g. for labradorite. Is this too good to be true …?