ATOMIC STRUCTURE, NUCLEAR CHEMISTRY & UNIT 6 What is an Atom? ATOMIC STRUCTURE, NUCLEAR CHEMISTRY & UNIT 6
Democritus He asked this question: If you break a piece of matter in half, and then break it in half again, how many breaks will you have to make before you can break it no further? Democritus thought that it ended at some point, a smallest possible bit of matter. He called these basic matter particles, atoms.
History of the Atom Aristotle – famous philosopher Believed all substances made of 4 elements Blending these in different proportions to get all substances Fire – hot air – light Earth – cool, heavy Water – wet
History of the Atom Late 1700s – John Dalton Teacher who summarized results of his experiments and those of others Combined idea of elements with that of atoms
Dalton’s Atomic Theory All matter is made of tiny, indivisible particles call atoms Atoms of the same element are identical Atoms of different elements combine in whole number ratios to form compounds Chemical reactions involve the rearrangement of atoms. No atoms are created or destroyed.
Atoms Smallest particle of an element that still retains the properties of that element
JJ Thompson In 1897, Thompson discovered the first component part of the atom: the electron, a particle with a negative electric charge. In 1904, he proposed an initial model of an atom, since nicknamed "Thompsons pudding". He imagined the atom as a sphere full of an electrically positive substance mixed with negative electrons "like the raisins in a cake".
Thomson’s Experiment Voltage source Vacuum tube Metal Disks
Thomson’s Experiment Voltage source - + Vacuum tube Metal Disks
Thomson’s Experiment Voltage source - +
Thomson’s Experiment Voltage source - +
Thomson’s Experiment Voltage source - +
- + Thomson’s Experiment Voltage source Passing an electric current makes a beam appear to move from the negative end to the positive end
- + Thomson’s Experiment Voltage source Passing an electric current makes a beam appear to move from the negative end to the positive end
- + Thomson’s Experiment Voltage source Passing an electric current makes a beam appear to move from the negative end to the positive end
- + Thomson’s Experiment Voltage source Passing an electric current makes a beam appear to move from the negative end to the positive end
Thomson’s Experiment Voltage source - + By adding an electric field…
- + Thomson’s Experiment Voltage source By adding an electric field… +
- + Thomson’s Experiment Voltage source By adding an electric field… +
- + Thomson’s Experiment Voltage source By adding an electric field he found that the moving pieces were negative
Millikan’s Experiment Atomizer Oil droplets - + Oil Telescope
Millikan’s Experiment X-rays X-rays give some electrons a charge.
Millikan’s Experiment From the mass of the drop and the charge on the plates, he calculated the mass of an electron
Other Particles Proton – positively charged pieces 1840 times heavier than electrons, discovered by E. Goldstein Neutron – no charge but the same mass as a proton, by J. Chadwick Where are these pieces?
Rutherford’s Experiment Ernest Rutherford – English physicist Believed in the plum pudding model of the atom
Rutherford’s Experiment Wanted to see how large the positive particles are Used radioactivity Shot alpha particles at gold foil Alpha particles – positively charged pieces,
Rutherford’s Experiment When an alpha particle hits a fluorescent screen it glows
Fluorescent Screen Lead block Uranium Gold Foil
Rutherford’s Experiment He expected the alpha particles to pass through without changing direction very much Because… The positive charges were thought to be spread out evenly Not enough to stop the alpha particles
What he expected
Because
He thought the mass was evenly distributed in the atom
Since he thought the mass was evenly distributed in the atom
What he got
How he explained it Atom is mostly empty. Small dense, positive piece at center. Alpha particles are deflected by it if they get close enough. +
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Density and the Atom Since most of the particles went through, it was mostly empty space Because the alpha particles turned so much, the nucleus was heavy Small volume, big mass, big density The small dense positive area is the nucleus
The Nucleus
Structure of the Nuclear Atom Unit 6 – Part 2 Structure of the Nuclear Atom
Subatomic Particles Name Symbol Charge Relative Mass Actual Mass (g) Electron e- -1 1/1840 9.11 x 10-28 Proton p+ +1 1 1.67 x 10-24 Neutron n0
Counting the Pieces Atomic Number – the number of protons in the nucleus All protons are alike so… # of protons determines kind of atom The same as the number of electrons in a neutral atom
Counting the Pieces Mass number = # of protons + # of neutrons Protons and neutrons account for most of the mass of an atom
X Symbols Mass number Atomic number Contain the element symbol, mass number, and atomic number Mass number X Atomic number
F Symbols 19 9 Find: # of protons # of neutrons # of electrons Atomic # Mass # F 19 9
Br Symbols 80 35 Find: # of protons # of neutrons # of electrons Atomic # Mass # Br 80 35
Symbols If an element has 91 protons and 140 neutrons, what is the Atomic # Mass # # of electrons Complete symbol
Isotopes Dalton was wrong Atoms of the same element can have different numbers of neutrons This means different mass numbers Called isotopes
Naming Isotopes Can also put mass # after name of the element Carbon-12 Carbon-14 Uranium-235
Atomic Mass There are different kinds of oxygen atoms. More concerned with the average atomic mass
Atomic Mass Based on the abundance of each in nature Do not use grams because numbers would be too small
Measuring Atomic Mass Use the atomic mass unit (amu) One twelfth of a carbon-12 atom Each isotope has its own atomic mass Determine average from % abundance
Calculating Averages Multiply atomic mass by % abundance then add results
Atomic Mass - Example Calculate the atomic mass of copper if copper has two isotopes. 69.1% has a mass of 62.93 amu and the rest has a mass of 64.93 amu.
Atomic Mass – Example 2 Magnesium has 3 isotopes. 78.99% has a mass of 23.9850. 10.00% has a mass of 24.9858. The rest has a mass of 25.9826 amu. What is the atomic mass?
Atomic Mass Is not a whole number because it is an average The number on the periodic table