Ch Chemical Bonding Covalent Bonds ____________ electrons between two atoms in order to fill the outer energy level (or shell) Each bond involves the sharing of _____ _________ of electrons. Single Bonds= __ e - ’s Double Bonds= __ e - ’s Triple Bonds=__ e - ’s Sharing one pair 246

Ways to Represent Covalent Bonds in Compounds (1)“Circled Arrows” for bonds. a) H 2 H ___ 1s H ___ 1s b) F 2 F …___ ___ ___ ___ 2s 2p F …___ ___ ___ ___ 2s 2p ↑ ↑ ↓ ↑ ↓↑ ↓↑↑ ↓ ↑ ↓↑ ↓↑↑

c) NH 3 N …___ ___ ___ ___ 2s 2p d) H 2 O O …___ ___ ___ ___ 2s 2p H ___ 1s H ___ 1s H ___ 1s ↓ ↑ ↑↑↑ ↑↑↑ ↓ ↑ ↑↑↑↓ H ___ 1s ↑ H ___ 1s ↑

Ways to Represent Covalent Bonds in Compounds (2) “Dots” for bonds. (Lewis Structures) a) H 2 H · + · H  b) F 2 :F · + · F:  c) N 2 : N · + · N :  (triple bond) d) NH 3.. · · · · H H:HH:H :F:F: ·· :N::N: H:N:HH:N:H

Ways to Represent Covalent Bonds in Compounds (3) “Lines” for bonds. a) H 2 b) F 2 c) N 2 d) NH 3 e) H 2 O.. ¨ ׀ H ׀ H H–H :F–F: :N≡N: H–N–H H–O:

↓ ↑ ↑ Coordinate Covalent Bonds Both of the electrons that make the bond come from the ________ _______________. – Example: CO (carbon monoxide) same element C …___ ___ ___ ___ 2s 2p ↑ O …___ ___ ___ ___ 2s 2p ↓↑ ↑ ↑↓↑ :C O:.. Two of the bonds are “normal”, and the third bond is a coordinate covalent bond. :C O: ← – –

Carbon’s Hybrid Orbital C …___ ___ ___ ___ (Before) 2s 2p ↓ ↑↑ ↑ C …___ ___ ___ ___ (After: 4 covalent bonds available) ↑↑↑ ↓ Practice Problem: Draw CH 4 using arrows, dots, and lines for bonds. 2sp 3 ↑↑↑↑ C …___ ___ ___ ___ H ___ 1s H ___ 1s H ___ 1s H ___ 1s ↑↑↑↑ ↑

The 7 Diatomic Elements Some elements will covalently bond to themselves to form a molecule composed of ____ atoms. These elements are never found in nature as single atoms. Instead, they will be bonded as a ________ when they are in the “_________________” state. The 7 diatomic elements are the gases H, O, N, and all of the _________________, (Group 7A). H 2, O 2, N 2, Cl 2, Br 2, I 2, F 2 “HONClBrIF” two elemental pair halogens

Air contains N 2 and O 2 molecules.

The decomposition of two water molecules

Octet Rule Atoms want ___ e - ’s in their outer shell when forming compounds. This will mean ___ dots around them all together. This is the stable e - configuration of a __________ _______! Important exception: Hydrogen = only needs __ to be full (like He). Other Exceptions: PCl 5 (___ e - ) SF 6 (___ e - ) BF 3 (___e - ) 8 8 noble gas

Resonance Resonance is the ability to draw 2 or more different e - dot notations that obey the octet rule. Examples: O 3 (ozone) and SO 2 Practice Problem: Draw the resonance structures for CO 3 -2.

VSEPR Theory: Molecular Shapes Most shapes are based on a __________________. Examples: CH 4 CCl 4 Removing the top of the tetrahedral makes the ________________ shape. Examples: NH 3 PCl 3 tetrahedral pyramidal

VSEPR Theory: Molecular Shapes Removing one side of the pyramid makes the _____________ shape. Examples: H 2 O H 2 S If there are only two atoms bonded, it is ______________. Examples: O 2 HCl CO 2 (linear because of its double bonds.) bent linear

VSEPR Theory: Molecular Shapes Another we will need to know is called “trigonal planar”. “Trigonal” means that the central atom is bonded to ___ other atoms. “Planar” means that the 3 atoms all lie in the same ______________. Example: BF 3 (Notice that Boron will only have ___ e - ’s around it. The missing pair of electrons will make it planar instead of ________________.) 3 plane 6 pyramidal

VSEPR Theory: Molecular Shapes Finally, the last 2 shapes occur when there are 5 or 6 regions of electrons are around the central atom. (These molecules are also exceptions to the octet rule!) - ___________________ (5 electron domains) - __________________ (6 electron domains) Examples: PCl 5 and SF 6 Trigonal bipyramid Octahedral

Polar and Nonpolar Bonds Even though the electrons in a covalent bond are shared, sometimes the attraction for the bonded pair, (the _____________________), is uneven. This gives rise to 3 bond types. nonpolar covalent bonds: ____________ sharing of the e - pair polar covalent bonds: ________________ sharing of the e - pair ionic bonds: a ___________ of e - ’s from the metal to the nonmetal How To Determine the Bond Type Bond type is based on the electronegativity _____________ between the two bonded atoms. (See p.403 for electronegativity values.) electronegativity equal unequal transfer difference

Figure 12.4 The three possible types of bonds. nonpolar polar ionic

How To Determine the Bond Type 0 to 0.4 = ______________ covalent bond 0.5 to 2.0 = _____________ covalent bond Above 2.0 = _______________ bond Practice Problems: Determine the type of bond that forms between the atoms in the following compounds. a) CO 2 b) NaClc) CH 4 nonpolar polar ionic = polar covalent2.1 = ionic0.4 = nonpolar covalent

Polarity of Molecules One side is slightly (__) and the other side is slightly (__). Polar molecules are also known as _______________. Polarity depends on the __________ and symmetry of the molecule. symmetrical molecules (looks the same on all sides)= ___________ asymmetrical molecules = ___________ Polar molecules are moved by ____________ charges. (DEMO!) +– dipole shape nonpolar polar static

Molecular Polarity Practice Problems: Determine if the following molecules are polar or nonpolar based on their shape. a) CH 4 b) NH 3 c) H 2 O d) HCl e) BF 3 symmetrical tetrahedral asymmetrical pyramid asymmetrical bent asymmetrical linear symmetrical trigonal planar nonpolar polar Dipole of NH 3 Dipole of H 2 O

Bond Dissociation Energy This is the energy needed to ___________ the bond. Generally, the longer the bond, the _____ energy it takes to break it. Single bonds take ________ energy to break than double bonds and triple bonds require the _________ energy to break. When bonds form, energy is _____________. (Breaking bonds requires the addition of energy.) released less most break

Bond Dissociation Energy

Intermolecular Attractions The __________ attractions between one molecule and another are called _______ ______ ________ forces. They cause gas particles to stick together and _______________ at low temperatures. weak Van der Waals condense

Dispersion Forces There are two types of intermolecular forces: (1) ____________________ forces: (the weaker type) – caused by random _______________ motion – generally _____________ with ________ electrons in the molecule Dispersion electron strongermore − exist between all types of molecules − This force causes Br 2 to be a liquid and I 2 to be a solid at room temperature.

Dipole Interaction Forces (2) ____________ interactions: (the stronger force) – caused by the attraction of the (__) side of one polar molecule and the (__) side of a different polar molecule Dipole + –

Hydrogen Bonds “________________ Bonds” are a special type of dipole interaction. They occur between the hydrogen of one polar molecule and the ____, ___ or ___ of another polar molecule. Hydrogen Bonding in Water Hydrogen N O F

Hydrogen Bonds The ladder rungs in a DNA molecule are hydrogen bonds between the base pairs, (AT and GC).

Hydrogen Bonds in DNA

Ionic Bonding & Ionic Compounds Ionic Bonds Form when ___________ transfer their _____________ electrons to a _______________. The forces of attraction between the ____________ (+) and the _____________ (-) bind the compound together. How to Represent an Ionic Bond (1)Electron Configuration: Na 1s 2 2s 2 2p 6 3s 1 Cl 1s 2 2s 2 2p 6 3s 2 3p 5 metalsvalence nonmetal cation anion Na… ___ 3s ↑ Cl… ___ ___ ___ ___ 3s 3p ↓ ↑ ↑ ↑↓↓↓

How to Represent an Ionic Bond 2) Electron Dot Notations: Na + Cl  [ ] [ ] Practice Problems: (1) Draw the electron dot notation for the formation of an ionic compound between sodium and oxygen. (2) Draw the electron configuration notation for the formation of an ionic compound between magnesium and fluorine. Na +1 Cl -1

Practice Problems: 3) a) Draw the electron dot notation for a potassium atom. b) Draw the electron dot notation for a potassium ion. (4) a) Draw the electron dot notation for a sulfur atom. b) Draw the electron dot notation for a sulfur ion. K [K +1 ] S [ S -2 ]

Properties of Ionic Compounds and Covalent Molecules Ionic:  _______________ of electricity when dissolved water or melted.  formed between __________ and _________________  have _________ melting points  usually ________ soluble in water form ___________________ solids Conductors metalsnonmetals high very ionic crystalline (dissolved salt)

Figure Polar water molecules interacting with positive and negative ions of a salt.

Crystalline Patterns

Properties of Ionic Compounds and Covalent Molecules Molecular: ________________ of electricity formed between two _______________ usually have ________ melting points solubility in water _______: (polar =dissolve; nonpolar = insoluble) For a compound to to conduct electricity it must have: (1) Charged Particles (________) (2) Particles Free to Move (___________ or __________ phase) Insulators nonmetals low varies ions liquidaqueous

Demonstration good conductor poor conductor nonconductor Pure H 2 O great conductor