Data collection and dedicated maps on contaminants EMODnet Chemistry 3 Steering committee 16 May 2017 Data collection and dedicated maps on contaminants giordano.giorgi@isprambiente.it ISPRA EMODnet Chemistry 3 Kick-off meeting, 17-19 May 2017 1

Data collection ISPRA role in chemical marine monitoring in Italy ISPRA supports the Italian Ministry of Environment for the implementation of WFD and MSFD. ISPRA also coordinates and collects monitoring data from the SNPA – National System for Environmental Protection that is made of ARPA – Regional Environmental Agencies. ISPRA will collect and made available on EMODNet Chemistry platform chemical marine monitoring data from two flows: MSFD Italian monitoring programme ex art. 11 by ARPAs and CNR EIONET/SOE monitoring programme by APRA for EEA EMODnet Chemistry 3 Kick-off meeting, 17-19 May 2017 2

Data collection MSFD monitoring programme Contaminants in water 1,2-dichloroethane 1,2,3-trichlorobenzene 1,2,4-trichlorobenzene 1,3,5-trichlorobenzene 4-nonylphenol, branched Alachlor Chloroalkanes C10-13 Aldrin Anthracene Atrazine Benzene Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene Cadmium Chlorfenvinphos Chlorpyrifos DDT total Di (2-ethylhexyl) phthalate (DEHP) Dichloromethane Dieldrin Diuron Endosulfan Endrin Hexachlorobenzene (HCB) Hexachlorobutadiene (HCBD) Hexachlorocyclohexane (HCH) Fluoranthene Indeno(1,2,3-cd)pyrene Isodrin Isoproturon Mercury Naphthalene Nickel Para-tert-octylphenol DDT, p,p' Pentachlorobenzene Pentachlorophenol Lead Simazine Tributyltin cation 1,1,2,2-tetrachloroethene Tetrachloromethane Trichlorobenzenes (all isomers) 1,1,2-trichloroethene Trichloromethane Trifluralin MSFD monitoring programme Nutrients and contaminants (priority substances) in water for coastal waters (ARPA) and marine waters beyond 12 miles (CNR) Nutrients and Physico-chemical parameters in water Temperature (water) Salinity Electrical conductivity Dissolved oxygen Oxygen saturation pH Chlorophyll a Secchi depth Nitrate Nitrite Ammonium Total phosphorus Orthophosphates Total nitrogen Silicate EMODnet Chemistry 3 Kick-off meeting, 17-19 May 2017 3

Data collection MSFD monitoring programme Contaminants (priority substances) in sediment and biota for coastal industrial plants and ports (ARPA) and marine waters beyond 12 miles (CNR) Nutrients load from aquaculture, uwwtps and riverine input Beach litter from more than 50 beach sites in Italy collected according to category list extracted from TG Litter guidelines and OSPAR with minor aggregation Microplastics from surface manta net trawling distinguished by colors (white, black, red, blue, green, transparent, other) and forms (sphere, filament, fragment, sheet) Contaminants in sediment and biota Aldrin alpha-Hexachlorocyclohexane (α-HCH) Anthracene Arsenic Benzo(a)pyrene Benzo(b)fluoranthene Benzo(g,h,i)perylene Benzo(k)fluoranthene beta-Hexachlorocyclohexane (β-HCH) Cadmium Chromium Chromium VI DDD DDE DDT Dieldrin Fluoranthene gamma-Hexachlorocyclohexane (γ-HCH) lindane Hexachlorobenzene (HCB) Hexachlorobutadiene (HCBD) Indeno(1,2,3-cd)pyrene Lead Mercury Naphthalene PCBs Pentabromodiphenylether Sum of PCDDs, PCDFs and dioxin-likePCBs Tributyltin cation EMODnet Chemistry 3 Kick-off meeting, 17-19 May 2017 4

Data collection EIONET/SOE monitoring programme Contaminants (priority substances and River Basin Specific Pollutants) in water, sediment and biota for coastal water (ARPA) Nutrients for coastal water (ARPA) EMODnet Chemistry 3 Kick-off meeting, 17-19 May 2017 5

Maps on contaminants General context Produce specific maps on contaminants that could be a useful tool in environmental impact assessment analysis requested by many EU directives and Regional Sea Conventions agreements. For a selection of specific contaminants and associated matrix, available data will be quality controlled and validated, and maps will be produced from the validated data. For such selection the priority substance list extracted from EU Directive 2013/39/EU (EQSD) has been compared with contaminants included in the EMODnet Chemistry tender EMODnet Chemistry 3 Kick-off meeting, 17-19 May 2017 6

Maps on contaminants Proposed list of contaminants: Matrix Water Pesticides and biocides: DDT, HCB Antifoulants: TBT, TPT Heavy metals: Mercury, cadmium, lead Hydrocarbons: Anthracene, Fluoranthene Sediments Pesticides and biocides: DDT Antifoulants: TBT Heavy metals: Mercury, cadmium, lead Hydrocarbons: Anthracene, Naphthalene Biota Total DDT Hydrocarbons: Fluoranthene Hexachlorobenzene Mercury and its compounds Benzo(a)pyrene EMODnet Chemistry 3 Kick-off meeting, 17-19 May 2017 7

Maps on contaminants Proposed type of maps Above or below LOQ. green points: below LOQ, yellow points: above LOQ LOQ above or below EQS threshold values. Green points: LOQ below EQS threshold values, Red points: LOQ above EQS threshold values Concentration values above or below EQS threshold values. Green points: concentration values below EQS threshold values, Red points: concentration values above EQS threshold values matrix monitored. Blue points: water, Yellow points: sediments, Green points: biota species monitored. Blue points: Mytilus, Yellow points: Oysters, Red points other species. For sediments, availability of a normalizer. (TOC or Loss on ignition for organic substances, Li, Al or clay-silt fraction for metals). blue points: normalizer available, yellow points: No normalizer available grainsize of the sediment for metals or organic content for organic substances. Scale of colors EMODnet Chemistry 3 Kick-off meeting, 17-19 May 2017 8