Chapter 13. Nonferrous Alloys [ 계보: 무기재료금속재료비철재료] Objectives of Chapter 13 Explore the properties and applications of Cu, Al, and Ti alloys in load-bearing applications. [Nonferrous alloy(비철금속)의 분류] 경량금속과 그 합금: Al, Mg, Be, Ti 내화금속과 그 합금: Nb, Mo, Ta, W 귀 금 속과 그 합금: Au, Ag, Pd, Pt, Rh 기타 비철금속 : Cu, Ni, Co 의 특징과 응용에 대하여 공부함.

Chapter 13. Nonferrous Alloys

Chapter 13. Nonferrous Alloys [Al, Cu, Be, Ti, Ni, Co, Au, W,…]

Chapter 13. Nonferrous Alloys

Chapter 13. Nonferrous Alloys Chapter Outline ⇒ 비강도 개념 13.1 Aluminum Alloys 13.2 Magnesium and Beryllium Alloys 13.3 Copper Alloys 13.4 Nickel and Cobalt Alloys 13.5 Titanium Alloys 13.6 Refractory and Precious Metals Basic oxygen furnace (전로) 비강도 = 강도/ 밀도 (13-1)

Chapter 13. Nonferrous Alloys

Chapter 13. Nonferrous Alloys

Chapter 13. Nonferrous Alloys 비철재료의 중요성: 높은 비강도 지각에서 비철재료의 존재량

Chapter 13. Nonferrous Alloys (Tm) Density(g/cc) ** 비중과 밀도를 구분해서 설명하세요.

Chapter 13. Nonferrous Alloys Section 13.1 Aluminum Alloys Hall-Heroult process - An electrolytic process by which aluminum is extracted from its ore. Temper designation - A shorthand notation using letters and numbers to describe the processing of an alloy. H tempers refer to cold-worked alloys; T tempers refer to age-hardening treatments. Al (2.7g/cc, Tm = 660℃, FCC) Example 13.1 확인요망

Chapter 13. Nonferrous Alloys Hall-Heroult process [가장 경제적인 Al 제조 공정] Al2O3 (alumina) melted to Na3AlF6 (molten cryolite) Al+3 + 3e-1 ⇒ Al (cathode) 2O-2 + C ⇒ CO2 + 4e-1 (anode) Figure 13.1 Production of aluminum in an electrolytic cell.

Chapter 13. Nonferrous Alloys 강화효과: 순수한 Al 에 비해서 age-hardened Al alloy는 elongation은 줄어들지만 tensile strength와 yield strength는 약 30배 증가함을 알 수 있음.

Chapter 13. Nonferrous Alloys (가공합금) ** Al의 표시법: 30계열과 40계열의 차이

Chapter 13. Nonferrous Alloys

Chapter 13. Nonferrous Alloys [40계열 Al의 특정: Si ??]

Chapter 13. Nonferrous Alloys 1xxx, 3xxx wrought alloys consist of single-phase except for small amounts of inclusions or intermetallic compounds. Figure 13.2 (a) FeAl3 inclusions in annealed 1100 aluminum ( 350). (b) Mg2Si precipitates in annealed 5457 aluminum alloy ( 75).

Chapter 13. Nonferrous Alloys Solid solution Solubility line Two phases Figure 13.3 Portion of the aluminum-magnesium phase diagram. (age hardening alloy의 전형적인 상태도)

Chapter 13. Nonferrous Alloys As the cooling rate increases Figure 13.4 (a) Sand-cast 443 aluminum alloy containing coarse silicon and inclusions. (b) Permanent-mold 443 alloy containing fine dendrite cells and fine silicon due to faster cooling. (c) Die-cast 443 alloy with a still finer microstructure ( 350).

Chapter 13. Nonferrous Alloys Section 13.2 Magnesium and Beryllium Alloys Magnesium alloys are used in aerospace applications, high-speed machinery, and transportation and materials handling equipment. Instrument grade beryllium is used in inertial guidance systems where the elastic deformation must be minimal; structural grades are used in aerospace applications; and nuclear applications take advantage of the transparency of beryllium to electromagnetic radiation. Beryllium is expensive, brittle, reactive, and toxic. Mg (1.74g/cc, Tm = 650℃, HCP): 바다물의 마그네슘염화물(Magnesium chloride)로부터 전해에 의해서 추출됨 Be (1.85g/cc, Tm = 1290℃, hex): E = 4.2x106 psi로 steel 보다 큰 E값 가짐  변형이 엄격히 제한되는 곳 사용

Chapter 13. Nonferrous Alloys ** Lever rule를 정의하세요. Figure 13.5 The magnesium-aluminum phase diagram. b T a c

Chapter 12. Ferrous Alloys 합금의 상평형-개론 합금의 상평형 - 단일성분계 : 압력과 온도에 의해 결정 (모든 相들은 같은 조성을 가짐) - 합금 : 1기압의 고정된 압력하에서 조성과 온도변화를 주로 고려함. 공정반응의 상태도 (Eutectic Phase Diagram) - 합금 상태 : 조성 XO at 온도 T2 - XB : 합금에서 B 원자의 몰분율 상태도에서 평형상태를 가정할 경우 예상되는 점: (1) 존재하는 相 : α, β (2) 相들의 조성 : α - Xα, β - Xβ (3) 각 상들의 부피분율 (Lever rule 이용) (4) 평형상태에서의 응고 조직 ㄱ. 합금상태 : 조성 XO at 온도 T1 ⇒ 100% α ㄴ. Quench (급속냉각) to T2 ⇒ 등온변태 (Isothermally transform) T2 온도에서 상변태 발생 경로: αss → α + β (석출반응, Precipitation rx.) (ss : Super Saturated Solid Solution) T1 T2 Xα Xo Xβ

Chapter 13. Nonferrous Alloys

Chapter 13. Nonferrous Alloys Section 13.3 Copper Alloys Blister copper(조동) - An impure form of copper obtained during the copper refining process. Applications for copper-based alloys include electrical components (such as wire), pumps, valves, and plumbing parts, where these properties are used to advantage. Brass(황동) - A group of copper-based alloys, normally containing zinc (Zn) as the major alloying element. Bronze(청동) - Generally, copper alloys containing tin (Sn), can contain other elements. Cu (8.9g/cc, Tm = 1083℃, FCC): 건식제련(pyrometallurgical process) : Cu ore ⇒ Cu sulphide 변환

Chapter 13. Nonferrous Alloys ** Annealed Cu와 cold worked Cu 및 age hardened Cu의 비교!

Chapter 13. Nonferrous Alloys 많은 동합금의 경우 single phase 조직을 유지하면서도 많은 양의 합금원소를 고용한다. (Cu-40%Zn, Cu-10%Sn, Cu-9%Al, Cu-3%Si...) ⇒ Solid-solution-strengthened alloys Figure 13.6 Binary phase diagrams for the (a) Cu-Zn, (b) Cu-Sn, (c) Cu-Al, and (d) Cu-Be systems. ** Cu-Be: 베릴륨 동합금 ⇒Age-hardenable alloys

Chapter 13. Nonferrous Alloys Section 13.4 Nickel and Cobalt Alloys Nickel and cobalt alloys are used for corrosion protection and for high-temperature resistance, taking advantage of their high melting points and high strengths. Superalloys - A group of nickel, iron-nickel, and cobalt-based alloys that have exceptional heat resistance, creep resistance, and corrosion resistance. Ni (8.9g/cc, Tm = 1453℃, FCC): 높은 융점과 높은 강도, 내부식성(STS 재료), 슈퍼알로이 재료  우수한 크립특성 Co (8.8g/cc, Tm = 1495℃, HCP  FCC:고온): 높은 융점과 높은 강도, 마모저항 재료, 보철기구(prosthetic), 슈퍼알로이 재료

Chapter 13. Nonferrous Alloys

Chapter 13. Nonferrous Alloys Monel: 60Ni-40Cu 염수와 고온에서 강도와 내식성 우수함. Small amounts of Al and Ti ⇒ Age-hardening by the precipitation of γ’, a coherent Ni3Al or Ni3Ti precipitate. The precipitates resist overaging at temperatures up to 425oC. Figure 13.7 The effect of temperature on the tensile strength of several nickel-based alloys.

Chapter 13. Nonferrous Alloys Figure 13.8 (a) Microstructure of a superalloy, with carbides at the grain boundaries and γ΄ precipitates in the matrix ( 15,000). (b) Microstructure of a superalloy aged at two temperatures, producing both large and small cubical γ΄ precipitates ( 10,000).

Chapter 13. Nonferrous Alloys [Turbine blade에서 공냉 원리] Figure 13.9 A turbine blade designed for active cooling by a gas. (b) The high-temperature capability of superalloys has increased with improvements in manufacturing methods (for Example 13.7). ** Single XL, one directional solidified, conventional polycrystalline를 구분해서 설명하세요. [원자배열 측면에서 ]

Chapter 13. Nonferrous Alloys Section 13.5 Titanium Alloys Titanium’s excellent corrosion resistance provides applications in chemical processing equipment, marine components, and biomedical implants such as hip prostheses. (also: heat exchanger) Titanium is an important aerospace material, finding applications as airframe and jet engine components. Titanium alloys are considered biocompatible (i.e., they are not rejected by the body). By developing porous coatings of bone-like ceramic compositions known as hydroxyapatite, it may be possible to make titanium implants bioactive (i.e., the natural bone can grow into the hydroxyapatite coating). Ti (4.5g/cc, Tm = 1668℃) HCP,  882℃  BCC,: 진공상태에서 제조, 높은 비강도, 뛰어난 내식성( <TiO2 피막, 535℃)

Chapter 13. Nonferrous Alloys Figure 13.10 Portions of the phase diagrams for (a) Ti-Sn, (b) Ti-Al(α-stablizer), (c) Ti-Mo(β-stablizer), and (d) Ti-Mn (eutectoid Rx.).

Chapter 13. Nonferrous Alloys ** Ti, Al, Ni, Cu, steel의 kg당 가격은 얼마일까?

Chapter 13. Nonferrous Alloys Figure 13.11 The effect of temperature on the yield strength of selected titanium alloys.

Chapter 13. Nonferrous Alloys Figure 13.12 (a) Annealing of an α titanium alloy and (b) microstructure of rapidly cooled alpha titanium ( 100). Both the grain boundary precipitate and the Widmanstätten plates are alpha. ⇒ Good fatigue resistance Cf) Furnace cooling ⇒ platelike α-structure ⇒ better creep resistance

Chapter 13. Nonferrous Alloys Figure 13.13 Annealing of an α-β titanium alloy. (a) Annealing is done just below the α–β transformation temperature, (b) slow cooling gives equiaxed α grains ( 250), and (c) rapid cooling yields acicular α grains ( 2500). ⇒ Good fracture toughness

Chapter 13. Nonferrous Alloys Figure 13.14 When the β-phase is quenched from a high temperature, (a) Heat treatment and (b)microstructure of the α-β Ti alloys. (x250) Q&T: α＇ ⇒ α + β precipitates Age hardened: βss ⇒ β + α precipitates Primary α (large white grains) Dark β matrix with needles of α formed during aging Heat treated α-β alloys ⇒ Improved strength and fracture toughness. ⇒ Airframes, rockets, jet engines, etc.

Chapter 13. Nonferrous Alloys Section 13.6 Refractory and Precious Metals Refractory metals(내화금속) – These include tungsten, molybdenum, tantalum, and niobium (or columbium), have exceptionally high-melting temperatures (above 1925oC) and, consequently, have the potential for high-temperature service. Applications of Refractory metals include filaments for light bulbs, rocket nozzles, nuclear power generators, tantalum- and niobium-based electronic capacitors, and chemical processing equipment. Precious Metals(귀금속) - These include gold, silver, palladium, platinum, and rhodium. From an engineering viewpoint, these materials resist corrosion and make very good conductors of electricity.

Chapter 13. Nonferrous Alloys Nanosized particles of Pt/Rh/Pd loaded onto a ceramic honeycomb are used as catalysts in automobiles. CO ⇒ CO2; NOx ⇒ N2 + O2

Chapter 13. Nonferrous Alloys 단원 정리를 위한 숙제 1. 경량금속(light metals)을 정의하고, 대표적인 경량금속의 예를 4가지 이상 들라. 2. Al, Mg, Be, Cu, Ti, Ni 금속에 대한 density, melting point, Structure를 쓰라. 3. 내화금속(refractory metals)을 정의하고, 대표적인 금속의 종류를 들어보라. 4. 귀금속(precious metals)을 정의하고, 5. Cu, Al, Ti 금속 및 그 합금의 종류와 사용용도에 대해서 약술하라. ** 연습문제: 13-15[14-11]