I thought I saw a blue jay this morning. But the smog was so bad that it turned out to be a cardinal holding its breath. Michael J. Cohen

Air Pollution in Shanghai, China, in 2004

China Smog Documentary

Air Pollution Chapter 18

Core Case Study: South Asia’s Massive Brown Cloud Asian Brown Cloud – Causes – Chemical composition – Areas impacted Air pollution connects the world Steps taken in China and India to reduce air pollution

The Atmosphere Consists of Several Layers Atmosphere varies in – Density – Atmospheric pressure – Temperature

Air Movements in the Troposphere Play a Key Role in Earth’s Weather and Climate Troposphere – 75–80% of the earth’s air mass – Closet to the earth's surface – Chemical composition of air – Rising and falling air currents: weather and climate – Involved in chemical cycling

The Stratosphere Is Our Global Sunscreen Stratosphere – Similar composition to the troposphere, with 2 exceptions Much less water O 3, ozone layer, filters UV – Location

Air Pollution Comes from Natural and Human Sources Air pollution (What is a pollutant?) Natural sources – Dust blown by wind – Pollutants from wildfires and volcanoes – Volatile organics released by plants – Withdrawing groundwater Human sources: mostly in industrialized and/or urban areas – Stationary sources – Mobile sources

Some Pollutants in the Atmosphere Combine to Form Other Pollutants Primary pollutants Secondary pollutants

Donora, PA at noon 11/29/1948

What Are the Major Outdoor Air Pollutants? 1. Carbon oxides – Carbon monoxide (CO) – Carbon dioxide (CO 2 ) – Sources – Human health and environmental impact

What Are the Major Outdoor Air Pollutants? 2. Nitrogen oxides (NO) and nitric acid (HNO 3 ) – Sources – Acid deposition – Photochemical smog – Human health and environmental impact 3. Sulfur dioxide (SO 2 ) and sulfuric acid (H 2 SO 4 ) Sources Industrial smog Human health and environmental impact

What Are the Major Outdoor Air Pollutants? 4. Particulates – Suspended particulate matter (SPM) Fine Ultrafine – Sources – Human health and environmental impact

What Are the Major Outdoor Air Pollutants? 5. Ozone (O 3 ) – see lab – Sources – Human and environmental impact 6. Volatile organic compounds (VOCs) – Hydrocarbons and terpenes – Sources – Human and environmental impact

Science Focus: Detecting Air Pollutants Chemical instruments - Satellites Nanotechnology Biological indicators – Lichens EPA Habitable Planet

Natural Capital: Lichen Species, Vulnerability to Air Pollutants

Chemical Reactions That Form Major Outdoor Air Pollutants EPA

A Model of How Pollutants That Make Up Photochemicals Are Formed

Photochemical Smog – Chemical composition – Sources VOCs + NO 2 + Heat + Sunlight yields – Ground level O 3 and other photochemical oxidants – Aldehydes – Other secondary pollutants Human health and environmental impact

Industrial Smog Chemical composition of industrial smog Reduction of this smog in urban cities of the United States China and smog – Human deaths

How Pollutants Are Formed from Burning Coal and Oil, Leading to Industrial Smog

Lead: A Highly Toxic Pollutant Does not break down in the environment Sources Human health and environmental impact – Most vulnerable Reduction of lead (Pb) – Unleaded gasoline – Unleaded paint Still problems – 2007: toys with Pb paint recalled – Global ban on lead in gasoline and paint

Solutions: Lead Poisoning, Prevention and Control

Several Factors Can Decrease or Increase Outdoor Air Pollution Outdoor air pollution may be decreased by – Settling of particles due to gravity – Rain and snow – Salty sea spray from the ocean – Winds – Chemical reactions

Outdoor air pollution may be increased by – Urban buildings – Hills and mountains – High temperatures – Emissions of VOCs from certain trees and plants – Temperature inversions – Grasshopper effect

Grasshopper effect...

Acid Deposition Acid deposition, acid rain – Formation – Local versus regional problems – Effects of prevailing winds – Buffers – Where is the worst acid deposition?

Natural Capital Degradation: Acid Deposition, Acid Rain

Current and Possible Future Acid Rain Problem Areas

Acid Deposition Has a Number of Harmful Effects Human respiratory disorders Aquatic ecosystems affected Release of toxic metals Leaching of soil nutrients Loss of crops and trees Damage to buildings, statues, and monuments know

Natural Capital Degradation: Air Pollution Damage to Trees in North Carolina, U.S.

Ocean Acidification

We Know How to Reduce Acid Deposition Prevention approaches Clean up – Add lime to neutralize acidified lakes and soil – Add phosphate fertilizer to neutralize acidified lakes

Indoor Air Pollution Developing countries – Indoor burning – Poor suffer the greatest risk Developed countries – Indoor air pollution is greater than outdoor air pollution Why? 11 of the common air pollutants higher inside than outside Greater in vehicles than outside Health risks magnified: people spend 70–98% of their time is indoors

Cont’d Who are at greatest risk from indoor air pollution? – Children under 5 and the elderly – Sick – Pregnant women – People with respiratory disorders or heart problems – Smokers – Factory workers

Cont’d Four most dangerous indoor air pollutants – Tobacco smoke – Formaldehyde – Radioactive radon-222 gas – Very small particles Sources of these pollutants Human health risks

Other possible indoor air pollutants – Pesticide residue – Pb particles – Living organisms and their excrements E.g., Dust mites and cockroach droppings – Airborne spores of molds and mildews Sick-building syndrome

Some Important Indoor Air Pollutants

Your Body’s Natural Defenses against Air Pollution Can Be Overwhelmed Respiratory system protection from air pollutants – Role of cilia, mucus, sneezing, and coughing Effect of smoking and prolonged air pollution exposure – Chronic bronchitis – Emphysema

Major Components of the Human Respiratory System

Normal Human Lungs and the Lungs of a Person Who Died of Emphysema

Air Pollution Is a Big Killer 3 Million deaths per year world-wide – Mostly in Asia – Main causes EPA: proposed stricter emission standards for diesel-powered vehicles Link between international trade and air pollution – Cargo ships and pollution

Premature Deaths from Air Pollution in the U.S.

Laws and Regulations Can Reduce Outdoor Air Pollution United States – Clean Air Acts: 1970, 1977, and 1990 Clean Air Acts: 1970, 1977, and 1990 EPA – National ambient air quality standards (NAAQs) for 6 outdoor criteria pollutants National ambient air quality standards (NAAQs) for 6 outdoor criteria pollutants – National emission standards for 188 hazardous air pollutants (HAPs) Toxic Release Inventory (TRI)

Cont’d Good news in U.S. – Decrease in emissions – Use of low-sulfur diesel fuel Cuts pollution Developing countries – More air pollution

We Can Use the Marketplace to Reduce Outdoor Air Pollution Emission trading or cap-and-trade program – Mixed reactions to program – SO 2 emissions down significantly – NO 2 will be tried in the future

There Are Many Ways to Reduce Outdoor Air Pollution 1980 –2006 – SO 2 emissions from U.S. electric power plants decreased by 66% – NO x emissions by 41% – Particulate emissions by 28% Older plants not governed by the same regulations New cars have better emissions

Rather than... “what can we do about the air pollution we produce?” How about... “How can we avoid producing the pollutant in the first place?”

Solutions: Stationary Source Air Pollution Solutions: Motor Vehicle Air Pollution, Prevention and Cleanup

Reducing Indoor Air Pollution Should Be a Priority Greater threat to human health than outdoor pollution What can be done? – Prevention – Cleanup