1. NMR I Spin-spinové interakce, 1 H NMR

2. I S J  0 I S J = 0 A X A1A1 A2A2 A1A1 A2A2 BoBo E J = 0 J > 0 E4E3E2E1E4E3E2E1

3. A1A1 A2A2 A 1 = A 2 A2A2 A1A1 A 2 A 1 A X A1A1 A2A2 A1A1 A2A2 BoBo E J = 0 J < 0 E4E3E2E1E4E3E2E1 A1A1 A2A2 A 1 A 2 J = 0 J > 0J < 0

4. 1singlets 1 1 dubletd 1 2 1triplet t 1 3 3 1kvartetq 1 4 6 4 1pentetp

5. t dd dd

6. q dt td ddd

7. 1 H NMR

8. X  (X-CH 3 ) elektronegativita Li1,0 R 3 Si01,8 H0,42,1 CH30,82,5 NH22,363,0 OH3,383,5 I2,162,5 Br2,702,8 Cl3,053,0 F4,254,0 1 H NMR - alkany

9. 7.08 6.55 6.70 7.08 6.55 1 H NMR - areny

10. 7.55 8.15 7.70 7.55 8.15 1 H NMR - areny

11. 1 H NMR – alkeny  = 4 – 7.5 Alkyny  = 2 – 3 Aldehydy  = 9 – 11 Vyměnitelné protony (OH, SH, NH)

13. + D 2 O

14. 500 MHz 3 J = 6.8 Hz

16. 500 MHz 3 J = 6.8 Hz

17. 100 MHz 3 J = 6.8 Hz

18. 100 MHz

19. 500 MHz

20. 800 MHz