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Are chemical compounds consisting of a carbonyl adjacent to an Ether linkage. They are derived by reacting an oxoacid with a hydroxyl compound.

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Presentation on theme: "Are chemical compounds consisting of a carbonyl adjacent to an Ether linkage. They are derived by reacting an oxoacid with a hydroxyl compound."— Presentation transcript:

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4 Are chemical compounds consisting of a carbonyl adjacent to an Ether linkage. They are derived by reacting an oxoacid with a hydroxyl compound.

5 are ubiquitous, they are present fats and oils, pheromones, fragrances, DNA, explosives, and plastics.

6 NameChemical StructureFlavor or Fragrance Propyl acetatePears Octyl acetateOranges Isoamyl acetateBanana Ethyl ButyratePineapple Butyl acetateApple Methyl trans- cinnamate Strawberry

7 Esters are one of a number of compounds known collectively as ACID DERIVATIVES.

8 In an ester, the hydrogen in the -COOH group is replaced by an alkyl group (or possibly some more complex hydrocarbon group).

9 Example 1: Methyl Propanoate Propanoic Acid

10 The hydrogen in the -COOH group is replaced by an alkyl group - in this case, a methyl group.

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12 1.) Methyl formate (C 2 H 4 O 2 ) Methyl methanoate 2.) Methyl propanoate (C 4 H 8 O 2 ) Methyl propionate

13 3.) Propyl Formate (C 4 H 8 O 2 ) Propyl Methanoate 4.) Ethyl ethanoate (C 4 H 8 O 2 ) Ethyl acetate

14 Alcoholysis of acyl chlorides and acid anhydides. Alcohols react with acyl chlorides and acid anhydrides to give esters: RCOCl + R'OH → RCO 2 R' + HCl (RCO) 2 O + R'OH → RCO 2 R' + RCO 2 H

15 Transesterification Transesterification, which involves changing one ester into another one, is widely practiced: RCO 2 R' + CH 3 OH → RCO 2 CH 3 + R'OH

16 Carbonylation Alkenes undergo "hydroesterification" in the presence of metal carbonyl catalysts. Esters of propionic acid are produced commercially by this method: C 2 H 4 + ROH + CO → C 2 H 5 CO 2 R

17 Keywords: 1.Kinetics (Chemical) 2.Carl ‐ Zeiss spectrophotometer. KINETIC AND MECHANISTIC STUDY OF OXIDATION OF ESTER BY K2Cr2O7

18 We found out that the oxidation of esters occurs in two ways: Hydrolysis followed by the oxidation of alcohol, or direct oxidation of esters. No conclusive evidence was provided iin support of either of the two pathways.

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20 www.chemguide.co.uk/ester#1 2272/vqw?.html www.wikipedia.org/ester

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