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Chapter 2 Atoms, Molecules and Ions

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1 Chapter 2 Atoms, Molecules and Ions
Copyright © The McGraw-Hill Companies, Inc.  Permission required for reproduction or display.

2 Chapter 2 (p.49-68) Atomic number , mass number and isotopes.
The periodic table . Molecules and ions . Chemical formulas . Naming compounds . Tables – 2.3 – – 2.6 – 2.7 Examples – 2.3 – 2.4 – 2.5 – 2.6 – 2.7 – 2.8 – 2.9

3 {لاَ يَعْزُبُ عَنْهُ مِثْقَالُ ذَرَّةٍ فِي السَّمَاوَاتِ وَلاَ فِي الأَرْضِ وَلاَ أَصْغَرُ مِن ذَلِكَ وَلاَ أَكْبَرُ إِلاَّ فِي كِتَابٍ مُّبِينٍ} (سبأ: 3). Atomic Structure Elements: are composed of extremely small particles called atoms. Atom: is the basic unit of an element that can enter into chemical combination Atom consist of: Electron (e) (-ve charge) Proton (p) (+ve charge) Neutron (n) (neutral) Out of the nucleus Inside the nucleus

4 mass p = mass n = 1840 x mass e- 2.2

5 Cathode Rays Experiment for Discovering Electrons By Joseph John Thomson (1856-1940)

6 Anode Rays Experiment for Discovering Protons By Goldshtien

7 Atomic number, Mass number and Isotopes
Atomic number (Z) = number of protons or electrons in nucleus Mass number (A) = number of protons + number of neutrons = atomic number (Z) + number of neutrons A Mass Number X Element Symbol Z Atomic Number Examples: C 12 6 Kr 83 36

8 Give the number of protons, neutrons, and electrons
Example 2.1 Give the number of protons, neutrons, and electrons in each of the following species: elements Atomic Number (Z) 11 8 6 80 Mass Number (A) 20 22 17 14 200 No. of electrons (e) No. of protons (p) No. of neutrons (n) 9 120 Na 20 11 Na 22 11 O 17 8 C 14 6 Hg 200 80

9 Isotopes Isotopes are atoms of the same element (X) with different numbers of neutrons (mass number) Examples of Isotopes

10 Do You Understand Isotopes?
How many protons, neutrons, and electrons are in C 14 6 ? 6 protons, 6 electrons, 8 (14 - 6) neutrons How many protons, neutrons, and electrons are in C 11 6 ? 6 protons, 6 electrons, 5 (11 - 6) neutrons Define the element X 63 29 ? The element with atomic number 29 is cupper (Cu) and its mass number is 63 2.3

11 Allotropes Allotrope is one of two or more distinct forms of an element as O2 , O3 Examples of Allotropes * Oxygen O=O (O2) and Ozone O3 * Diamond and Graphite

12 Allotropes Allotropes are different structural forms of the same element and can exhibit quite different physical properties and chemical behaviors.

13 Diamond and Graphite Graphite Diamond

14 Chemistry In Action Natural abundance of elements in Earth’s crust
Natural abundance of elements in human body 2.4

15 increasing in atomic number
Periodic Table is a chart in which elements having similar chemical properties are grouped together in this table the elements are arranged by increasing in atomic number Alkali Earth Metal Noble Gas Halogen Alkali Metal Group Period 2.4

16 Periodic Table in Latin
1 H 1.0 Hydrogenium 2 He 4.0 Helium 3 Li 6.9 Litium 4 Be 9.0 beryllium ATOMIC MASS NUMBER 5 B 10.8 Borum 6 C 12.0 Carboneum 7 N 14.0 Nitrogenium 8 O 15.9 Oxygenium 9 F 18.9 Fluorum 10 Ne 20.1 Neon 11 Na 22.9 Natrium 12 Mg 24.3 Magnesium 13 Al 27.0 Aluminium 14 Si 28.0 Silicium 15 P 30.9 Phosphorus 16 S 32.0 Sulphur 17 Cl 35.4 Chlorum 18 Ar 39.9 Argon 19 K 39.0 Kalium 20 Ca 40.0 Calcium 21 Sc 44.9 Scandium 22 Ti 47.8 Titanium 23 V 50.9 Vanadium 24 Cr 51.9 Chromium 25 Mn 54.8 Manganum 26 Fe 55.8 Ferrum 27 Co 58.9 Cobaltum 28 Ni 58.6 Niccolum 29 Cu 63.5 Cuprum 30 Zn 65.3 Zincum 31 Ga 69.7 Gallium 32 Ge 72.6 Germanium 33 As 74.9 Arsenicum 34 Se 78.9 Selenium 35 Br 79.9 Bromum 36 Kr 83.8 Krypton 37 Rb 85.4 Rubidium 38 Sr 87.6 Strontium 39 Y 88 .9 Yttrium 40 Zr 91.2 Zirconium 41 Nb 92.9 Niobium 42 Mo 95.9 Molybdaenum 43 Tc 98.9 Technetium 44 Ru 101.0 Uthenium 45 Rh 102.9 Rhodium 46 Pd 106.4 Palladium 47 Ag 107.8 Argentum 48 Cd 112.4 Cadmium 49 In 114.8 Indium 50 Sn 118.7 Stannum 51 Sb 121.7 Stibium 52 Te 127.6 Tellurium 53 I 126.9 Iodium 54 Xe 131.2 Xenon 55 Cs 132.9 Caesium 56 Ba 137.3 Barium 71 Lu 174.9 Lutetium 72 Hf 178.4 Hafnium 73 Ta 180.9 Tantalum 74 W 183.8 Wolframium 75 Re 186.2 Rhenium 76 Os 190.2 Osmium 77 Ir 192.2 Iridium 78 Pt 195.0 Platinum 79 Au 196.9 Aurum 80 Hg 200.5 Hydrargyrum 81 Tl 204.3 Thallium 82 Pb 207.2 Plumbum 83 Bi 208.9 Bismuthum 84 Po Polonium 85 At 209.9 Astatium 86 Rn 222.0 Radon 87 Fr 223.0 Francium 88 Ra 226.0 Radium 103 Lr 261.1 Lawrencium 104 Rf Rutherfordium 105 Db 262.1 Unnilpentium 106 Sg 263 Unnilhexium 107 Bh 264.1 Unnilseptium 108 Hs 265.1 Unniloctium 109 Mt 268 Unnilennium 110 Uun 269 Ununnilium 111 Uuu 272 Unununium 112 Uub 277 Ununbium 114 Uuq 289 Ununquadium 116 Uuh Ununhexium 118 Uuo 293 Ununoctium Periodic Table in Latin 1 2A 3A 4A 5A 6A 7A 2 3 8B 3B 4B 5B 6B 7B 1B 2B 4 5 6 7 57 La 138.0 Lanthanum 58 Ce 140.1 Cerium 59 Pr 140.9 Praseodymium 60 Nd 144.9 Neodymium 61 Pm Promethium 62 Sm 150.3 Samarium 63 Eu 151.2 Europium 64 Gd 157.2 Gadolinium 65 Tb 158.9 Terbium 66 Dy 162.9 Dysprosium 67 Ho 164.9 Holmium 68 Er 168.2 Erbium 69 Tm 168.9 Thulium 70 Yb 173.0 Ytterbium 89 Ac 232 Actinium 90 Th 121.0 Thorium 91 Pa 231.0 Protactinium 92 U 238.0 Uranium 93 Np 237.0 Neptunium 94 Pu 244.0 Plutonium 95 Am 243.0 Americium 96 Cm 247.0 Curium 97 Bk Berkelium 98 Cf 251.0 Californium 99 Es 252.0 Einsteinium 100 Fm 257.0 Fermium 101 Md 258.0 Mendelevium 102 No 259.1 Nobelium Metals Metalloids Nonmetals

17 The monatomic gases are the single atoms of noble gases; He, Ne, Ar, Kr, Xe, Rn.
A molecule is an aggregate of two or more atoms in a definite arrangement held together by chemical forces. H2 H2O NH3 CH4 Molecule Polyatomic molecule: contains more than two atoms Diatomic molecule: contains only two atoms H2, N2, O2, Br2, HCl, CO, NO, KCl O3, H2O, NH3, CH4 ,NaOH

18 An ion is an atom, or group of atoms, that has a net positive or negative charge.
ion with a negative charge. If a neutral atom gains one or more electrons it becomes an anion. Cation: ion with a positive charge. If a neutral atom loses one or more electrons it becomes a cation. Monoatomic cation Polyatomic cation Monoatomic anion Cl-, Br-,S2- N3- Polyatomic anion OH-, PO43- Na+, K+, Mg2+ Al3+ NH4+

19 Cation Anion 11Na 17Cl 11 protons 11 protons 11 electrons 10 electrons

20 Do You Understand Ions? How many protons and electrons are in ? Al
27 13 3+ 13 protons, 10 (13 – 3) electrons How many protons and electrons are in ? Se 78 34 2- 34 protons, 36 (34 + 2) electrons 2.5

21 Complete the following table:
3- B 11 5 P 31 15 3- Au 196 79 Rn 222 86 26 18-3=15 54-26=28 26-2=24 86 2+

22 Different Ions of Some Elements
Metals tend to form cations Nonmetals tend to form anions 2.5

23 2.6

24 molecular empirical An empirical formula tells us which elements are
present and the simplest whole-number ratio of the atoms in a substance. A molecular formula shows the exact number of atoms of each element in the smallest unit of a substance. molecular empirical H2O, N2O, CH4, CH3OH, NH3, CO2 C6H12O6 CH2O O3 O N2H4 NH2 CH C6H6 2.6

25 Write the Molecular formula of Methanol and Chloroform, using the structural formulas below:
Cl H Molecular formula of Methanol Molecular formula of Chloroform CH4O CHCl3 or CH3OH

26 acetylene C2H2 CH glucose C6H12O6 CH2O nitrous oxide N2O caffeine
Write the empirical formulas for the following molecules if possible: Compounds Name Molecular Formula Empirical Formula acetylene C2H2 CH glucose C6H12O6 CH2O nitrous oxide N2O caffeine C8H10N4O2 C4H5N2O

27 The ionic compound NaCl
ionic compounds consist of a combination of cations and an anions the formula is always the same as the empirical formula the sum of the charges on the cation(s) and anion(s) in each formula unit must equal zero The ionic compound NaCl 2.6

28 SALT - a Cation and an Anion held together by an ionic bond.
opposites attract

29 Write the chemical formula of the following ionic compounds
2 x +3 = +6 3 x -2 = -6 Aluminum Oxide Al2O3 Al3+ O2- 1 x +2 = +2 2 x -1 = -2 Calcium bromide CaBr2 Ca2+ Br- 2 x +1 = +2 1 x -2 = -2 Aluminum Oxide Na2CO3 Na+ CO32-

30

31 1. An anion is defined as  A. a charged atom or group of atoms with a net negative charge. √ B. a stable atom. C. a group of stable atoms. D. an atom or group of atoms with a net positive charge. 2. Atoms of the same element with different mass numbers are called  A. ions. B. neutrons. C. allotropes. D. chemical families. E. isotopes. √ 3. How many neutrons are there in an atom of lead 82Pb whose mass number is 208?  A. 82 B √ C. 208 D. 290 E. none of them

32 4. An atom of the isotope sulfur-31 consists of how many protons, neutrons, and electrons? (p = proton, n = neutron, e = electron)  A. 15 p, 16 n, 15 e B. 16 p, 15 n, 16 e √ C. 16 p, 31 n, 16 e D. 32 p, 31 n, 32 e E. 16 p, 16 n, 15 e 5. A magnesium ion, Mg2+, has  A. 12 protons and 13 electrons. B. 24 protons and 26 electrons. C. 12 protons and 10 electrons. √ D. 24 protons and 22 electrons. E. 12 protons and 14 electrons. 6. A sulfide ion, S2- , has:  A. 16 protons and 16 electrons B. 32 protons and 16 electrons C. 16 protons and 14 electrons D. 16 protons and 18 electrons √ E. 32 protons and 18 electrons

33 Answer Key 1-A 2-E 3-B 4-B 5-C 6-D
Problems 2.10 – 2.11 – 2.12 – 2.14 – 2.16 – 2.18 – 2.36 – 2.44 – 2.46 – 2.50

34 Chemical Nomenclature of
Ionic Compounds Metal (cation) nonmetal (anion) The most reactive metals (green) and the most reactive nonmetals (blue) combine to form ionic compounds.

35 Metal (cation) nonmetal (anion)
Ionic Compounds Consists of Metal (cation) nonmetal (anion)

36 Ionic bond Li F 2 1 2 1

37 Ionic bond Li F 2 1 2 1

38 The attraction between
Ionic bond Li F-1 2 1 2 1 The attraction between a cation and an anion.

39 Chemical Nomenclature
Ionic Compounds often a metal (cation) + nonmetal (anion) The cation is always named first and the anion second anion (nonmetal), add “ide” to element name Binary compounds are compounds formed from just two kinds of elements BaCl2 barium chloride K2O potassium oxide Ternary compounds are compounds formed from three kinds of elements. Mg(OH)2 magnesium hydroxide KNO3 potassium nitrate 2.7

40 Chemical Nomenclature of
Ionic Compounds Metal (cation) nonmetal (anion)

41 Metal (cation) Transition metals
Monovalent elements Divalent elements trivalent elements Transition metals Lithium (Li+) Sodium (Na+) Potassium (K+) Robidium (Rb+) Cesium (Cs+) Silver (Ag+) Magnisium (Mg2+) Calcium (Ca2+) Strontium (Sr2+) Barium (Ba2+) Lead (Pb2+) Zinc (Zn2+) Aluminium (Al3+) Galium (Ga3+) (Fe2+) iron(II) (Fe3+) iron(III) (Cr3+) chromium (III) (Cu2+) cupper (II) (Cu+) cupper (I) (Mn2+) manganese(II) (Mn3+) manganese(III) (Mn4+) manganese(IV) (Mn7+) manganese(VII) (Sn2+) stannous or tin(II) (Hg22+) mercury(I) (Hg2+) mercury(II) Common name of metal cation: NH4+ ammonium

42 nonmetal (anion) Hydrogen hydride (H-) Oxygen oxide (O2-)
Nitrogen nitride (N3-)

43 Transition metal ionic compounds
indicate charge on metal with Roman numerals In the Stock system the different cations charge are designated with Roman numerals FeCl2 iron(II)chloride 2 Cl- -2 so Fe is +2 FeCl3 3 Cl- -3 so Fe is +3 iron(III)chloride Cr2S3 3 S-2 -6 so Cr is +3 (6/2) chromium(III)sulfide 2.7

44 Some common oxygenated anions
(SO42-) sulphate , (SO32-) sulphite (HSO4-) hydrogen sulphate or bisulphate (PO43-) phosphate (PO33- ) phosphite (HPO42-) hydrogen phosphate (H2PO4-) dihydrogen phosphate (NO3-) nitrate (NO2-) nitrite (ClO3– ) chlorate (ClO2- ) chlorite (BrO3– ) bromate (BrO2- ) bromite (CO32–) carbonate (HCO3– ) bicarbonate

45 2.7

46 Name the following ionic compounds:
Cu(NO3)2 Copper(II)nitrate KH2PO4 Potassium dihydrogen phosphate NH4SCN Ammonium thiocyanate Cs2O2 Cesium peroxide Li2SO3 Lithium sulphite Ca3(PO3)2 Calcium phosphite KMnO4 Potassium permenganate Hg2Cl2 Mercury(I)chloride K2CrO4 Potassium chromate

47 Write formulas for the following ionic compounds:
Manganese(II)oxide MnO Potassium hydrogen phosphate K2HPO4 Ammonium chlorate NH4ClO3 Lead hydroxide Pb(OH)2 Sodium bicarbonate NaHCO3 Barium cyanide Ba(CN)2 Rubidium hydrogensulphate RbHSO4 Mercury(II)bromide HgBr2 Strontium hydride SrH2

48 Molecular Compounds 1- Consists of (metalloids + nonmetals) Ex. SiC
Or (nonmetal + nonmetal) Ex. PCl3 2- Many molecular compounds are Binary Compounds 3- common names of some molecular compounds Diborane B2H6 Methane CH4 Silane SiH4 Ammonia NH3 Phosphine PH3 Water H2O Hydrogen sulfide H2S 4- last element ends in -ide

49 5- element further left in periodic table is 1st (less electronegative)
(HCl) H(1A) and Cl(7A), so hydrogen is 1st, the name is hydrogen chloride 6- element closest to bottom of group is 1st (less electronegative) (SiC) Si(4A) and C also belongs to (4A) ,but (Si) is closest to bottom of the group, so silicon is 1st , the name is silicon carbide 7- if more than one compound can be formed from the same elements, use prefixes to indicate number of each kind of atom. (NO) nitrogen monooxide (NO2) nitrogen dioxide (N2O) dinitrogen monooxide

50 Second Element (anion)
Naming of Elements Element’s symbol First Element Second Element (anion) H Hydrogen hydride C Carbon carbide Si Silicon silicide N Nitrogen nitride P Phosphorus phosphide O Oxygen oxide S Sulpher sulphide F fluorine fluoride Cl Chlorine chloride Br Bromine bromide I Iodine iodide

51 Examples of Molecular Compounds
HI hydrogen iodide PF3 phosphorus trifluoride H2O2 Hydrogen peroxide N2O4 dinitrogen tetraoxide TOXIC! NO2 nitrogen dioxide N2O dinitrogen monooxide Laughing Gas ICl3 Iodine trichloride 2.7

52 Name the following molecular compounds:
SO2 Sulpher dioxide SiCl4 Silicon tetrachloride BrF7 Bromine heptaflouride P4O10 Tetraphosphorus decoxide Cl2O7 Dichlorine heptoxide CH4 Methane CS2 Carbon disulphide Br2O7 Dibromine heptoxide

53 Write formulas for the following molecular compounds:
Sulphur tetraflouride SF4 Dinitrogen pentoxide N2O5 Sulfur trioxide SO3 Disilicon hexabromide Si2Br6 Phosphorus pentachloride PCl5 Tetraphosphorus decasulphide P4S10 Nitrogen peroxide N2O2 Carbon monoxide CO Iodine heptaflouride IF7

54 Fill the blanks in the following table
name formula anion cation Barium bicarbonate Ba(HCO3)2 HCO3- Ba2+ Iron(III)nitrite Fe (NO2)3 NO2- Fe3+ Hyrdogen flouride HF F- H+ Manganise(IV)oxide MnO2 O2- Mn4+ Sodium peroxide Na2O2 O22- Na+ Cesium chlorate CsClO3 ClO3- Cs+ Lithium nitride Li3N N3- Li+


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