1. Metals

2. Elements found in the Earth’s crust
Metals make up a relatively small proportion of the Earth’s crust and are normally found in rocks as ores
46%
Oxygen
28%
Silicon
Aluminium 8% 5%
Iron 4%
Calcium 3%
Sodium
Magnesium 2%
Potassium 2%
Titanium
0.5%
Hydrogen
0.5%
All other elements 1%

3. Most metals are found as ores
Bauxite – aluminium oxide (Al2O3)
Haematite – iron oxide (Fe2O3)
Malachite – copper carbonate (CuCO3)
In ores, the metal or metal compound is concentrated enough to make it economic to extract the metal.
Some unreactive metals such as gold can be found as the metal itself – chemical separation is not needed.

4. The method used to extract a metal from its ore depends on the reactivity of the metal.
K Na Ca Mg Al
Zn Fe Sn Pb
Cu Ag Au Pt
Most reactive
Very reactive metals – extracted using electrolysis C
More reactive metals – usually extracted by reduction – heating with carbon to remove oxygen H
Unreactive metals – little or no extraction needed (found native)
Least reactive
Sometimes non-metals are included for reference.

5. Using the reactivity series, decide which items would be most corroded.
Gold ring
Iron sword
Copper pin
Silver bracelet

6. The extraction of iron – reduction in the blast furnace
Raw materials
ron ore (haematite)
I_______
C____
oke
hot waste gases
L________
imestone
iron oxide + carbon (coke)
iron + carbon dioxide
a reduction (loss of oxygen) – the iron oxide is reduced to iron metal
1500oC
hot air
hot air
molten slag
molten iron

7. Blast furnaces (for extracting iron) at Port Talbot

8. Copper
Malachite – copper ore
Polished malachite
Copper is a good heat and electrical conductor and used for saucepans and electrical wire.
Since it is an unreactive metal it is also used for water pipes and coinage.

9. The outside of the Statue of Liberty is made from copper.
Over time, the colour has changed as the copper has weathered.

10. Why are aluminium alloys used for the following?

11. Aluminium is extracted from the ore bauxite
Aluminium is the most common metal in the Earth's crust.
Aluminium is extracted from the ore bauxite
However it is a reactive metal (high in the reactivity series) and has to be extracted using electrolysis (passing electricity through the molten ore).
Because lots of energy is needed and there are several stages to the process, aluminium is relatively expensive despite being a common metal.

12. ALUMINIUM - ELECTROLYSIS

13. ALUMINIUM - ELECTROLYSIS

14. flow of electrons
+ve
electrode
-ve electrode
-ve ions
+ve ions

15. Open cast mining of bauxite in Australia

16. Open cast mining for metal ores
What effect does this have on the environment?

17. Uses of aluminium
Like most metals, pure aluminium is not used very much – it is usually made into alloys.
Alloys of aluminium have low density and high strength, vital for the aerospace industry.
Aluminium alloys were used to make the external fuel tanks of the space shuttle.

18. Because of its low density and good electrical conductivity, aluminium is used in overhead power cables.
Although aluminium is a reactive metal it is normally covered with a protective oxide layer and doesn’t corrode easily.

19. Titanium
Like aluminium, titanium is an extremely useful metal because it is light, strong and resists corrosion.
Titanium ore
It was used in the manufacture of Concorde
….. and is used in artificial hip joints

20. TITANIUM EXTRACTION

21. TITANIUM EXTRACTION 1) TiO2 + 2 Cl2 + 2 C → TiCl4 + 2 CO
2) Purify TiCl4 by fractional distillation
TiCl Na → Ti NaCl
TiCl Mg → Ti MgCl2
Expensive due to:
High temperatures (high energy)
Use of Ar
Cost of Na/Mg

22. Replacement hip joints
USES OF TITANIUM
Titanium is
Low density
Strong
Corrosion resistant
Replacement hip joints
Nuclear reactors
Aircraft

23. Good conductors of heat and electricity
The transition metals
These are found in the middle block of the Periodic Table Sc Ti V Cr Mn Fe Co Ni Cu Zn
They are useful metals and have typical metallic properties:
Good conductors of heat and electricity
Strong
Malleable
High melting point