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OxiMax Bio - F Clear using nature to amend natural disaster

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Presentation on theme: "OxiMax Bio - F Clear using nature to amend natural disaster"— Presentation transcript:

1 OxiMax Bio - F Clear using nature to amend natural disaster
Unique systems for removal of fluoride and iron from drinking water HES Water Engineers (India) Pvt Ltd (Group Company of Water Engineers Australia Pty Ltd, Australia) K-27, Five Star Industrial Zone, MIDC, Butibori, Nagpur , INDIA Phone: , , Fax: E Mail: Website: OXIMAX BIO-F CLEAR - Clean Water, Healthy Life

2 Worldwide Issues: Fluoride removal Iron removal
HES WATER ENGINEERS (INDIA) PVT LTD, NAGPUR. Phone: , Fax: ,

3 High adsorption capacity Steady adsorption capacity Simple to operate
Aims: Safety Affordability High adsorption capacity Steady adsorption capacity Simple to operate HES WATER ENGINEERS (INDIA) PVT LTD, NAGPUR. Phone: , Fax: ,

4 Effect of co-existing anions
Technology Development Pilot Trail Activated and treatment process Bio-material Screening Defluoride Capacity Effect of pH Safety analysis Defluoridation Efficiency Effect of co-existing anions HES WATER ENGINEERS (INDIA) PVT LTD, NAGPUR. Phone: , Fax: ,

5 What is Bio-F? Bio-F is a biological adsorbent, using nature shell as raw material Porous crystal and hexagonal structure Insoluble in water High temperature tolerance Multi-purpose (Fe, Mn removal) Image of Bio-F x 20 HES WATER ENGINEERS (INDIA) PVT LTD, NAGPUR. Phone: , Fax: ,

6 F adsorption Capacity(48h): 7.77mg/g
Bio-F can remove fluoride, iron & manganese efficiently F adsorption Capacity(48h): 7.77mg/g Mn adsorption Capacity(24h): 3.187mg/g Fe adsorption Capacity(24h): 6.969mg/g HES WATER ENGINEERS (INDIA) PVT LTD, NAGPUR. Phone: , Fax: ,

7 High fluoride removal efficiency High fluoride removal capacity
Bio-F Benefits: Safety High fluoride removal efficiency High fluoride removal capacity Suitable for various water Stable regeneration capability Cost effective HES WATER ENGINEERS (INDIA) PVT LTD, NAGPUR. Phone: , Fax: ,

8 Bio-F Value Propositions: Improve Water Quality
Fluoride removal >90% Iron removal >82% Manganese removal >70% HES WATER ENGINEERS (INDIA) PVT LTD, NAGPUR. Phone: , Fax: ,

9 Performance of Bio-F defluoridation equipment: 1 Contact time: 3~5min
2 Feed pressure: <0.3Mpa 3 Work temperature: 5℃~45℃ 4 Waste Water : <1% 5 Defluoridation efficiency: >90% 6 Applicable range of raw water pH: 5~9 7 Total automation 8 Operation cost (electricity & reagent ): ≤Re.1/ m3 HES WATER ENGINEERS (INDIA) PVT LTD, NAGPUR. Phone: , Fax: ,

10 Safety Evaluation of Bio-f Plumbum
Harmful Element Concentration (mg/kg) Maximum levels of contaminants in foods (mg/kg) Plumbum 0.24 0.02 ( Infant Milk Powder ) hydrargyrum 0.005 0.01(Fresh Milk)-0.05 ( Meat & Egg ) arsenic 0.46 0.05 ( Fresh Milk ) -1 (Shrimp & Crab) aluminium < 0.5 100 ( Flour Food ) cadmium 0.004 0.05 ( Egg ) The above table clearly shows no harmful element exceeds the limits of water quality HES WATER ENGINEERS (INDIA) PVT LTD, NAGPUR. Phone: , Fax: ,

11 Test Results by GWSSB, Gujarat
Standards for Drinking Water Quality Raw Water Product Water Desirable Permissible 458 402 Colour Hazen Units 5 25 NIL ODOUR UO TURBIDITY NTU 10 DISSOLVED SOLIDS mg/l 500 2000 250 380 pH 6.5 TO 8.5 No relaxation 7.3 7.58 Total hardness (as CaCo3) mg/l 300 600 120 40 Calcium (as Ca) mg/l 75 200 38 13 Magnesium (as Mg) mg/l 30 100 6 2 Chlorides (as Cl) mg/l 1000 48 184 Nitrate (as No3) mg/l 45 23.92 Sulphates ( as SO4) mg/l 400 Fluoride (as F) mg/l 1.00 1.50 4.43 0.25 Alkalinity (as CaCo3) mg/l 104 312 OPINION UNFIT FIT HES WATER ENGINEERS (INDIA) PVT LTD, NAGPUR. Phone: , Fax: ,

12 Fluoride Content in PPM
Test results by State Public Health Laboratory, Government of Maharashtra, Pune FLUORIDE IRON Fluoride Content in PPM Sr. No. Type of Sample Raw Water before passing through Bio-F Unit Product Water (10 minutes after passing through Bio-F unit) Product Water (20 minutes after passing through Bio-F unit) 1 Batch No.1 1.0 0.143 0.112 2 Batch No. 2 5.0 0.177 0.139 3 Batch No. 3 7.0 0.211 0.205 4 Batch No. 4 10.0 0.271 0.220 5 Batch No. 5 Nil Iron Content in PPM Sr. No. Type of Sample Raw Water before passing through Bio-F Unit Product Water (10 minutes after passing through Bio-F unit) Product Water (20 minutes after passing through Bio-F unit) 1 Batch No.1 1.0 0.01 0.02 2 Batch No. 2 10.0 0.17 3 Batch No. 3 25.0 0.10 0.05 4 Batch No. 4 50.0 0.22 0.08 5 Batch No. 5 Nil HES WATER ENGINEERS (INDIA) PVT LTD, NAGPUR. Phone: , Fax: ,

13 Test Report: Food & Drug Laboratory, Vadodara
Sl. No. Fluoride content in Raw Water Contact Time with Media Fluoride content in Product Water 1 1.40 PPM 10 Minutes 0.047 PPM 2 2.48 PPM 0.042 PPM 3 3.50 PPM 0.044 PPM 4 5.37 PPM 0.041 PPM 5 7.46 PPM 0.038 PPM HES WATER ENGINEERS (INDIA) PVT LTD, NAGPUR. Phone: , Fax: ,

14 * SOURCE: “FLUORIDE IN DRINKING WATER” BY W.H.O.
Bio-F compared to Activated Alumina Sl. No Activity Activated Alumina* OxiMax Bio-F Clear 1 Defluoridation capacity 1mg/g 4mg/g 2 Regeneration Process Regeneration by exposing to 4 percent caustic soda (hazardous chemical) and therefore can not be carried out at local level. Must be taken to a center Regeneration only by salt and/or alum. Can be carried out by a layman at site. 3 Wastewater Waste water contaminated with fluoride thus going back to ground at the same location Waste water not contaminated with fluoride. Regeneration process in Bio-F only does a fresh coating and not releasing any fluoride in waste water 4 Neutralization Neutralization required with sulphuric acid after regeneration, again a hazardous chemical. Cumbersome and risky process No neutralization required 5 Capacity reduction Capacity reduced by 30-40% after regeneration Capacity reduced marginally 2-5% 6 Number of regenerations possible 3-4, after which media needs to be replaced. 15-20 times regeneration can be carried out. 7 Presence of aluminium after regeneration Regeneration may result in presence of aluminium at a concentration greater than 0.2 mg/l, if the pH is not readjusted to normal. No such possibility HES WATER ENGINEERS (INDIA) PVT LTD, NAGPUR. Phone: , Fax: ,

15 Comparison of adsorption capacity
Much higher capacity as compared to bone charcoal. HES WATER ENGINEERS (INDIA) PVT LTD, NAGPUR. Phone: , Fax: ,

16 Contact Time Comparison of Activated Clinopitolite with Bio-F in dynamic testing have shown that activated clinopitolite need to be regenerated after 75 liter water produced ( contact time 20 min), but 700 liter for Bio-F (contact time 3.5 min). HES WATER ENGINEERS (INDIA) PVT LTD, NAGPUR. Phone: , Fax: ,

17 Effect of co-existing ions on removal of F, Fe(ll) and Mn(ll)
NOTE: High concentration of Ca2+, NO3, HPO4(2) could favour defluoridation with bio-f while concentration of Co3(2) and HCO3 marginally reduces the capacity of bio-F Anions Ion concentration /mmol.l-1 Adsorption capacity/mg.g-1 (mean n=2) Control 5.58 HPO4(2) 1 6.698 2 6.853 3 6.971 NO3 1.5 6.421 6.34 5 6.266 HCO3- 5.391 4.992 CO3(2) 3.332 1.821 SiO3(2) 0.1 5.379 0.3 5.531 SO4(2) 5.762 Cl 5.936 6.104 Cations Ion concentration /mmol.l-1 Adsorption capacity/mg.g-1 (mean n=2) Control 3.47 Na+ 1 3.055 2 3.085 K+ 1.5 3.850 3 3.635 Ca2+ 3.765 5.250 Mg2+ HES WATER ENGINEERS (INDIA) PVT LTD, NAGPUR. Phone: , Fax: ,

18 Effect of pH on defluoridation capacity
Key Result: Bio-F has a stable adsorption capacity under pH 4-9. HES WATER ENGINEERS (INDIA) PVT LTD, NAGPUR. Phone: , Fax: ,

19 Effect of flow on adsorbents
Key result: Bio-F has better adsorption capability than others in same velocity of flow, and can work in a shorter contact time. HES WATER ENGINEERS (INDIA) PVT LTD, NAGPUR. Phone: , Fax: ,

20 Regeneration Process:
Dissolve Alum (30% water and 5% alum) Transportation to the columns Retain for 2-3 hours Wash redundant alum F- F- F- F- F- F- F- F- F- F- HES WATER ENGINEERS (INDIA) PVT LTD, NAGPUR. Phone: , Fax: ,

21 Stability of capacity after regeneration:
HES WATER ENGINEERS (INDIA) PVT LTD, NAGPUR. Phone: , Fax: ,

22 Key Results: Bio-F adsorbent can remove Fe from pH 3.5-7.5, and
Effect of pH on removal of iron and manganese: Key Results: Bio-F adsorbent can remove Fe from pH , and the better condition for Bio-F to adsorb Mn is alkaline. HES WATER ENGINEERS (INDIA) PVT LTD, NAGPUR. Phone: , Fax: ,

23 Treatment process: Component of waste water: Waste disposal:
Inorganic salt Treatment process: process produces solid inorganic salt cake easily disposed in Non-hazardous waste landfill HES WATER ENGINEERS (INDIA) PVT LTD, NAGPUR. Phone: , Fax: ,

24 Bio-F Benefits: International intellectual property (patent pending)
Safety; High defluoridation capacity; Lower cost; Suitable for wide range of pH ; Steady capacity under other ionic competition; Simple regeneration process, Non-hazardous in wastewater, easy to disposal; Steady capacity after regeneration; Environment friendly HES WATER ENGINEERS (INDIA) PVT LTD, NAGPUR. Phone: , Fax: ,

25 No electricity required
Caters to all needs: Hand Pump No electricity required Domestic unit Open well/ tube well HES WATER ENGINEERS (INDIA) PVT LTD, NAGPUR. Phone: , Fax: ,

26 Thank You ! HES WATER ENGINEERS (INDIA) PVT LTD, NAGPUR. Phone: , Fax: ,


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