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The valence electrons in an atom have HIGH POTENTIAL ENERGY By bonding with other atoms, potential energy is decreased creating stable compounds.
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Symbols of atoms with dots to represent the valence-shell electrons. (The valence- are the e- directly involved in bonding). Ar Mg C
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The Noble Gases do not react with other elements because they are already STABLE. The outer most “s” and “p” orbitals are completely filled with 8 electrons, satisfying the octet rule. Ne
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Elements combine with each other to achieve noble gas electron configurations or (8 outer e-) **The exceptions to the octet rule are Hydrogen and Helium (they only need 2)
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The forming of chemical compounds results in chemical change. Compounds are made up of chemically united elements Compounds have completely different characteristics than its component elements Compounds are NEUTRAL
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2H 2 O = H 2 O = HHO H 2 O HHO Subscript = # of atoms Coefficient = # of molecules
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N: 1 H: 5 O: 1
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The Gaining and Losing of Electrons to form IONS. (An ion is an atom with a charge.)
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sharing of electrons
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Soluble in water Do not transmit electric current Brittle High melting and boiling points
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Ionization Energy: the amount of energy needed to remove an e- from an atom. Nonmetals have high ionization energy because they are closer to satisfying the octet rule! Metals have a low ionization energy
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the higher the electronegativity the greater the ability to pull electron to itself The nature of a bond is determined by differences in electronegativity. The GREATER the electronegativity difference, the MORE ionic the bonding.
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Ionic compounds result when metals react with nonmetals Metals lose electrons to achieve a stable outer energy level Positive ions form when electrons are given away Group 1 metals ion 1+ Group 2 metals ion 2+ Group 13 metals ion 3+
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1. Write the symbol for the cation (+) followed by the symbol for the anion (-). 2. Put any polyatomic ions (see green boxes) in parenthesis 3. Write the oxidation numbers above the appropriate ions 4. Use the criss-cross method to deterimine # of atoms (do not criss-cross ones) 5. Make sure the sum of all ox# is ZERO. 6. Reduce
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Na – e Na + Sodium Atom Sodium Ion 11 p+ 11 e- 0 11 p+ 10 e- 1+
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+ e 1- Fluoride Atom Fluoride Ion 17 p+ 17 e- 0 17 p+ 18e- 1-
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Na + Na 1+1-
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YOUR TURN … Using dot diagrams, draw the Lewis structures that result when the following elements form ionic bonds: A.Potassium + chlorine B.Magnesium + fluorine
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Potassium + Chlorine Magnesium + Fluorine K Cl K + FMg + F F
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Oxidation: the process of losing electrons ▪ Creates an ion with a + charge ▪ Creates cations Reduction: the process of gaining electrons ▪ Creates an ion with a – charge ▪ Creates anions
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1. Write the name of the cation (+) 2. Write the name of the anion (-) with an ide suffix NaCl Sodium and Chlorine Sodium Chloride
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The oxidation number is not always the same, it varies. The variable oxidation states are represented with a roman numeral in parentheses and are located in groups 3-12 on the periodic chart. Copper Copper (I) = Cu+ Copper (II) = Cu2+
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Write the symbol for the cation followed by the symbol for the anion. Write the oxidation numbers above the appropriate ions. Criss-Cross Copper(III) Oxide: CuO Cu 2 O 3 Copper(I) Oxide: CuO Cu 2 O 3+2- 1+ 2-
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SO 4 Sulfate2- C 2 H 3 0 2 Acetate1- NO 3 Nitrate1- NO 2 Nitrite1- NH 4 Ammonium1+ HCO 3 Bicarbonate1- CO 3 Carbonate2- OHHydroxide1- ClO 3 Chlorate1- PO 4 Phosphate3-
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1. Write the name of the cation (+) 2. Write the name of the anion (-) 3. If either is a polyatomic ion write the name of the polyatomic ion (you don’t need to change any suffixes) Na(OH) Sodium Hydroxide
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Write the symbol for the cation followed by the symbol for the anion. Put all polyatomic ions in parentheses!! Write the oxidation numbers above the appropriate ions. Criss-Cross Calcium Phosphate: Ca(PO 4 ) Ca 3 (PO 4 ) 2 Ammonium Phosphate: (NH 4 )(PO 4 ) (NH 4 ) 3 (PO 4 ) 2+ 3 - 1+ 3 -
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Cu(OH) Copper (I) Hydroxide Ni 2 O 3 Nickel (III) Oxide 1-= 01+ 2- 6-=03+
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sharing of electrons
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Between nonmetallic elements of similar electronegativity. Formed by sharing electron pairs Stable non-ionizing particles, they are not conductors at any state Examples; O 2, CO 2, C 2 H 6, H 2 O, SiC
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Water is a polar molecule because oxygen is more electronegative than hydrogen, and therefore electrons are pulled closer to oxygen.
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A polar molecule has a (+) and a (-) end. A nonpolar molecule does not have charged ends.
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Metal + Nonmetal --> ionic compound (usually) Metal + Polyatomic ion —> ionic compound (usually) Nonmetal + Nonmetal —> covalent compound (usually) Hydrogen + Nonmetal —> covalent compound (usually)
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The chemical symbol for the atom is surrounded by a number of dots corresponding to the number of valence electrons
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1. Write the name of the cation (+) with appropriate prefix (do NOT use mono for the cation) 2. Write the name of the anion (-) with the appropriate prefix CO 2 Carbon Dioxide
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1:mono 2:di 3:tri 4:tetra 5:penta 6:hexa
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Formula weight is the sum of the atomic masses. Example- CO 2 Mass, C + O + O 12.011 + 15.994 + 15.994 43.999
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