1. Breakthrough Technologies For Downstream Oil Industry

2. Contents 1.IndianOil R&D 2.Breakthrough Technologies

3. Alternative Energy - Biofuels - Hydrogen-CNG - CTL / Gasification - Shale Oil Biotechnology Polymers & Petrochemicals Technical Services Refinery Technology - FCC/HD - Catalyst - Pipelines (iPIG) Lubricant Technology Nanotechnology Fuel Additives IndianOil-R&D

4. 52 Pilot Plants 61 Research and Technology Partners 332 Patents filed till date 200 Effective Patents 231 Scientists IndianOil-R&D At a Glance

5. IISc BARC DCE NCCR IITM IndianOil-R&D COLLABORATIVE RESEARCH IITD

6. Contents 1.IndianOil R&D 2.Breakthrough Technologies

7. Indmax Indadept Kero HDT Food Grade Hexane IndianOil R&D TECHNOLOGY BASKET Catalyst Sweetening Process CFC Delayed Coking Indalin DHDT Isom Needle Coke

8. Indmax Technology- Resid to LPG, Light Olefins & High Octane Gasoline  Technology demonstrated in 2003  Can process wide variety of feedstocks including Atmospheric Residue and Vacuum Residue with CCR upto 11 wt%  High flexibility to produce LPG, Gasoline and diesel.  Employs proprietary catalyst formulation  Typical product yields LPG 35-50 wt% (Propylene 45-50wt% in LPG) Gasoline 20-40 wt% (High octane 98+) Diesel 15-25 wt% INDMAX unit at GR (100,000 TPA)

9. BRPL (0.74) Paradip (4.0) INDMAX Guwahati (0.1)  Worldwide licensing through Lummus Technology Inc., USA  Proposals submitted to various refineries globally– Takreer, Ras Tanura, Idemitsu, Japan, OMV, Austria (Aug’08), PTTAR, Thailand (Sep’08) Digboi (0.1)

10. Polymer Grade Hexane (PGH) /Food Grade Hexane (FGH) Joint Technology Licensing with EIL 28,000 TPA Unit operational at Gujarat Refinery 1 Unit (20,000 TPA) licensed to Bhatinda Refinery PGH and FGH from paraffinic Naphtha and raffinate from Aromatic Extraction Unit Benzene Reduction Feed : 1.3-4 % Product : < 100 ppm

11. 11 DHDT Technology Can upgrade straight run as well as cracked diesel streams Sulphur reduction from ~1.8% to less than 50/ 10 ppm Cetane improvement by 7-10 units Proprietary catalyst Joint licensing with Engineers India Ltd. 1.2 MMTPA unit under construction at Bongaigaon Refinery. Commissioning in Mar, 2010 5.0 MMTPA unit under implementation at Paradip Refinery based on process data input from IOC R&D

12. 12 INDAdept Process Adsorptive Deep desulphurisation Only novel adsorptive, low cost, efficient deep desulphurisation technology for both Gasoline and Diesel Proprietary adsorbent in hydrogen environment Two reactors operated in swing mode of adsorption and regeneration Adsorption Regeneration H2H2 Air N2N2 Diesel 1 2

13. 13 INDAdept Process INDAdept D S reduction from 500 to < 10 ppm No change in cetane & other properties H 2 consumption 0.1 wt% only INDAdept G S reduction from 1000 to < 10 ppm RON reduction of ~ 2 units H 2 consumption 0.2 wt% Suitable for treating Coker/ FCC gasoline Employs single reaction step

14. Category – Technical Development “Hydro-Processing Technology for Green Fuels World Petroleum Congress Award Chairman, IOCL Receiving the Award from King of Spain: WPC 2008

15. INDALIN+ Value addition from Naphtha/Condensate –50-55% LPG with <3% olefins meeting Auto Grade spec. –17-34% High Octane Gasoline (95+) with 95% Sulphur reduction –25-30% BTX in gasoline –Can also handle gas oil range feed stocks –No external hydrogen supply and feed desulfurization –Proprietary catalyst –Process developed for upgrading condensate to Propylene/ Ethylene / LPG for Saudi Aramco. Propylene yield ~18% on feed.

16. Delayed Coker Joint Licensing with EIL Needle Coke  Commercialized at GR in 2003  Licensed to BGR in 2003 & NRL in 2007  Value addition ~ $700-800 per MT of Needle Coke Light Naphtha Isomerisation Joint licensing with EIL Licensed to Bongaigaon Refinery (0.15 MMTPA). Commissioning by March, 2010 Other Technologies

17. Light Naphtha Isomerisation Joint licensing with EIL Licensed to Bongaigaon Refinery (0.15 MMTPA). Commissioning by March, 2010 Other Technologies

18. FCC catalyst and additive technology (i-Max series) for LPG & Propylene enhancement ZSM-5 additives (i-MAX, i-MAX Super, i-MAX Supreme and i-MAX Ultra)- Used in IOC and non-IOC refineries in India Propylene selective ZSM-5 additive Metal Passivator additive for RFCC units FCC & RFCC Catalysts & Additives

19. DHDT Catalyst Commercial demonstration of INDICAT-DH-IV Demonstrated at CPCL in Jun, 09 Consistent performance with Diesel meeting Euro-IV/V quality 88- 90% Desulphurisation in VGO mode Delta Diesel Cetane (Product- Feed) of 7 units under 55 Kg/cm 2 g

20. FCC & RFCC (FCC MOD) Hydrocracker (HC MOD) CRU (REF MOD) Diesel-hydrodesulphurisation (DHDS-MOD) Delayed Coker Hydrogen Generation Unit Used for Troubleshooting, Optimization, Process design, catalyst evaluation and Technology development PROCESS SIMULATORS

21. TECHNICAL SOLUTIONS Right Fit Technology Selection & Licensing Revamp of Process Units Catalyst Management –FCC/Hydroprocessing –Catalyst Selection –Catalyst Health Monitoring –Remaining Life Prediction Process Optimisation Troubleshooting Static Equipment Inspection Services Unit Turnaround Management

22. SERVO-LI Lubricity improver for diesel –Excellent Lubricity Performance –Biodegradable source –Good Storage Stability SERVO-AO : for gasoline –Excellent Oxidation Stability –High Storage Life –Minimum Treat Cost MFA for diesel –High Performance –Component in Premium Diesel FUEL ADDITIVES

23. Bioremediation OiliVorous-S Oily sludge site before treatment Oily sludge site after treatment Bio-Process for bioremediation of oily sludge using OiliVorous-S bacteria. In use at refineries, marketing & pipeline installations at both IOC & Non-IOC locations since 1994. Bioremediation carried out both on sea and on-shore. Good results obtained on sea using bacteria, especially designed to weather high salt concentration.

24. Before treatment After treatment Bioremediation of oil contaminated water at Duliajan (Assam) Bioremediation OiliVorous-S

25. Automobile Industry Textile Chemical Railways Cement Aviation Defence Steel Lubricant Technology

26. LUBRICANTS The TECHNOLOGY BASKET SERVO Lubricants Covering: Automotive oils Rail Road Oil Marine Oil Industrial lubricants Metal Working oils Jute Batching Oils Rubber Process oils Agro spray oils High Performance Greases Synthetic Lubricants More than 4000 formulations accounting for ~ 800 commercial grades With strong R&D backup, SERVO holds 38% National Lube Business About 200 New and Revised formulations every year

27. High performance engine oils meeting latest API, ACEA, JIS and OEM customized specifications Gas Engine Oils Energy efficient, long life industrial lubricants & greases Synthetic compressor, gear, specialty lubricants NSF listed food grade lubricants & greases Biodegradable lubricants LUBRICANTS TECHNOLOGY BASKET

28. Marine Oils

29. Servo RR 606MG First ever Multi-grade RR Oil in India Indian Railways saved over $ 200 million since 2000 LUBRICANTS RAILROAD OIL

30. AFRICA 2008 Total Energy Consumption: 453 Mmtoe (4% of world consumption) Total Proven Oil Reserves: 125.6 Billion barrels (10% of world reserves) Crude Oil Production: 10.3 million bopd (12.5% of world oil production) Total Oil Consumption: 2.9 million bopd (3.4% of world consumption) Total Refining Capacity: 3.2 million bopd ( 3.65% of world refining capacity)

31. AFRICA 2008 ‘000 bpd 666 1232 429 554

32. AFRICA 2030 Product DeficitProduct Surplus LPG MS JetKero HSD Others Total 5 24 3 38 1 71 Naphtha FO Total 11 25 36 Figs in MMTPA Net Product Deficit:35 MMTPA

33. 33 Diesel Quality worldwide

34. Our Offering Novel Technologies, Technological Solutions & Technical Services for : –Refinery Revamp/ Modernization –Setting up Green Field Refineries, and Installations, –Efficiency, Productivity & Profitability Improvement, Energy Conservation etc –Value Addition –Product Quality Improvement –Reliability Enhancement –Product, Crude Oil & Gas Pipleines –Environment Protection –Collaborative R&D