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The Mole
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What is a mole? A conversion factor we use in chemistry to make it easier to talk about a very large amount of particles of elements or compounds 1 dozen bagels = 12 bagels 1 mole bagels = 6.02 x 10 23 bagels A conversion factor we use in chemistry to make it easier to talk about a very large amount of particles of elements or compounds 1 dozen bagels = 12 bagels 1 mole bagels = 6.02 x 10 23 bagels
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Avogadro’s Number Avogadro’s # = 6.02 x 10 23 units How does this number relate to a mole? 1 mole = 6.02 x 10 23 units *Units can be anything but in chemistry these units are referred to as: Particles Atoms Molecules Formula Units Avogadro’s # = 6.02 x 10 23 units How does this number relate to a mole? 1 mole = 6.02 x 10 23 units *Units can be anything but in chemistry these units are referred to as: Particles Atoms Molecules Formula Units
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How big is 6.02 x 10 23 ? Astronomers estimate that there is a mole of stars in the Universe. One mole of high school textbooks would cover the USA to a depth of about 300 Km. One mole of marshmallows would cover the USA to a depth of 105 000 Km. One mole of moles placed to head to tail would stretch 11 million light years and weigh 9/10 as much of the moon. One mole of pennies would make at least seven stacks that would reach the moon. One mole of watermelon seeds would be found inside a melon slightly larger than the moon. Astronomers estimate that there is a mole of stars in the Universe. One mole of high school textbooks would cover the USA to a depth of about 300 Km. One mole of marshmallows would cover the USA to a depth of 105 000 Km. One mole of moles placed to head to tail would stretch 11 million light years and weigh 9/10 as much of the moon. One mole of pennies would make at least seven stacks that would reach the moon. One mole of watermelon seeds would be found inside a melon slightly larger than the moon.
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Examples 1 mole Fe = 6.02 x 10 23 atoms Fe 1 mole C 12 H 22 O 11 = 6.02 x 10 23 molecules C 12 H 22 O 11 1 mole Al = 6.02 x 10 23 atoms Al 1 mole BeF 2 = 6.02 x 10 23 formula units BeF 2 1 mole Fe = 6.02 x 10 23 atoms Fe 1 mole C 12 H 22 O 11 = 6.02 x 10 23 molecules C 12 H 22 O 11 1 mole Al = 6.02 x 10 23 atoms Al 1 mole BeF 2 = 6.02 x 10 23 formula units BeF 2
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How is the mole measured in the lab? It is impossible to count up individual particles of chemicals in the lab because of their small size We must find another way to measure 6.02 x 10 23 particles of a substance It is impossible to count up individual particles of chemicals in the lab because of their small size We must find another way to measure 6.02 x 10 23 particles of a substance
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How does mass relate to the mole? What does an amu (atomic mass unit) measure? 1 amu = 1.66053886 × 10 -27 kilograms A relative scale used to measure the mass of single elements or compounds What does an amu (atomic mass unit) measure? 1 amu = 1.66053886 × 10 -27 kilograms A relative scale used to measure the mass of single elements or compounds
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Learning the termonology… Atomic Mass Atomic Mass - measures the mass of a single atom in amu’s Example: 1 atom Fe = 55.85 amu *Always go to the hundredths place when taking measurements from the periodic table Atomic Mass - measures the mass of a single atom in amu’s Example: 1 atom Fe = 55.85 amu *Always go to the hundredths place when taking measurements from the periodic table
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Formula Mass Formula Mass - measures the mass of a single formula unit (ionic compound) in amu’s Example: 1 formula unit BeF 2 = 1Be9.01 amu + 2F2(19.00 amu) = 47.01 amu Formula Mass - measures the mass of a single formula unit (ionic compound) in amu’s Example: 1 formula unit BeF 2 = 1Be9.01 amu + 2F2(19.00 amu) = 47.01 amu
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Molecular Mass Molecular Mass - measures the mass of a single molecule in amu’s Example: 1 molecule C 12 H 22 O 11 = 12 C atoms 12(12.01 amu) + 22 H atoms22(1.01 amu) + 11 O atoms11(16.00 amu) = 342.34 amu Molecular Mass - measures the mass of a single molecule in amu’s Example: 1 molecule C 12 H 22 O 11 = 12 C atoms 12(12.01 amu) + 22 H atoms22(1.01 amu) + 11 O atoms11(16.00 amu) = 342.34 amu
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Molar Mass The mass of 1 mole of any substance in grams Example: 1 atom Fe = 55.85 amu 1 mole (6.02 x 10 23 atoms) Fe = 55.85 g 1 molecule C 12 H 22 O 11 = 342.34 amu 1 mole (6.02 x 10 23 molecules) C 12 H 22 O 11 = 342.34 g The mass of 1 mole of any substance in grams Example: 1 atom Fe = 55.85 amu 1 mole (6.02 x 10 23 atoms) Fe = 55.85 g 1 molecule C 12 H 22 O 11 = 342.34 amu 1 mole (6.02 x 10 23 molecules) C 12 H 22 O 11 = 342.34 g
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What is a representative particle? The smallest particle that represents the true identity of the entire substance without altering it’s characteristics or properties Example: What is the representative particle of 52 Al atoms? The smallest particle that represents the true identity of the entire substance without altering it’s characteristics or properties Example: What is the representative particle of 52 Al atoms?
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Answer: 1 atom Al Example: What is the representative particle of 1 molecule of BeF 2 ? Answer: 1 atom Al Example: What is the representative particle of 1 molecule of BeF 2 ?
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Answer: 1 molecule BeF 2 1 atom of Be or 1 atom of F would not truly represent the properties and characteristics of BeF 2 Answer: 1 molecule BeF 2 1 atom of Be or 1 atom of F would not truly represent the properties and characteristics of BeF 2
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