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Published byLinda Holland Modified over 9 years ago
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Some Transition Metals can form more than one type of cation. For example, copper can have either a +1 or a +2 charge Iron can have either a +2 or a +3 charge. (see periodic table) The charge of an ion is also called the “combining capacity” or “valence” of the element.
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The charge of the metal in a compound is noted in the name with a matching Roman Numeral: +1 = (I) +2 = (II) +3 = (III) This is called the STOCK system for naming compounds.
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Charge on Copper ion = +1 or +2 Since the Roman Numeral shown is (I), the charge to use is +1 Charge on Sulfur ion = -2 Cu S +1 -2 Criss Crossing gives the formula Cu 2 S
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The Roman Numeral (II) means to use the charge of +2 for Copper The charge for Sulfur is -2 Cu S +2 -2 Equal ratio of charges means the formula is CuS
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1. Copper (I) Oxide 1.Cu 2 O 2. Lead (IV) Bromide 1.PbBr 4 3. Iron (III) Sulfide 1.Fe 2 S 3 4. Nickel (II) Fluoride 1.NiF 2 5. Manganese (IV) Sulfide 1.Mn 2 S 4 MnS 2 (must reduce to lowest terms)
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Fe Cl 3 (Iron can have a charge of either +2 or +3) Cl has a charge of -1 Fe Cl 3 ____ - 3 (-1 x 3 = -3) The charge on Fe must balance with charge on Cl Since there is One Fe, the charge on it must be +3 So the iron used is the Fe+3 ion, so use the Roman Numeral (III) in the name: The name is Iron (III) Chloride
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Cu = +1 or +2 S = -2 Cu 2 S _____ - 2 Since there are 2x Cu, and since the overall charge must = +2, the charge on one Cu must be +1 The name is Copper (I) Sulfide
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Note: Change #1 (h) to Nickle (II) Chloride Change #2 (f) to BeF 2
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1. Iron (III) Oxide 2. Lead (IV) Oxide 3. Nickel (II) Chloride 4. Chromium (III) Nitride 5. Mercury (II) Oxide
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(II)
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BeF 2
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