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How to predict a Product
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Synthesis Acid anhydride + water acid Base anhydride + water base
Nonmetallic oxide is acid anhydride Metallic oxide is base anhydride
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Decomposition Electrolysis: splits the molecule Heating: most common
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Heat hydroxides Produce the oxide and water
Exceptions: group 1 hydroxides
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Heat carbonates Produce oxide and CO2 Exceptions: group 1 carbonates
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Heat sulfates Produce oxide and sulfur trioxide
Exceptions: groups 1 and 2
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Heat nitrates Produce oxide, oxygen, and nitrogen dioxide
Exceptions: group I nitrates produce nitrites and oxygen
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Heat chlorates All produce the chloride and oxygen gas
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Heat oxides Only for silver, mercury, platinum, palladium, and gold
Produce metal and oxygen gas
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Single replacement Free metal must be higher on the reactivity series
Free nonmetal must be higher on the nonmetal reactivity series
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Activity Series of the Metals
Li Rb K Ba Sr Ca Na Mg Al Mn Zn Cr Fe Cd Co Ni Sn Pb H2 Sb Bi Cu Hg Ag Pt Au
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Activity Series of the Nonmetals
Cl2 Br2 I2
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Double replacement Both conditions must occur
Both reactants must be soluble in water Must be evidence of a chemical reaction Color change Precipitate Bubbles
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Solubility Rules 1. All nitrates, acetates, and chlorates are soluble.
2. All chlorides, bromides, and iodides are soluble except for Ag+, Hg22+, and Pb 2+ 3. All sulfates are soluble except for Ca 2+, Sr 2+, Hg22+, Pb2+, and Ag+ 4. All carbonates, chromates, sulfites, and phosphates are insoluble except those of group I and NH4+ 5. All hydroxides are insoluble except for those of group I and lower II 6. All sulfides except those of the I and II groups are insoluble 7. Salts containing a group I metal or the ammonium ion are soluble
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Complete combustion Always produces carbon dioxide and water
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Decomposition problems what if you heat:
Calcium oxide Aluminum hydroxide Sodium chlorate Sodium sulfate Sodium nitrate Calcium nitrate Magnesium carbonate Magnesium sulfate
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answers Calcium oxide: nothing
Aluminum hydroxide aluminum oxide and water Sodium chlorate sodium chloride and oxygen Sodium sulfate nothing Sodium nitrate sodium nitrite and oxygen Calcium nitrate calcium oxide, O2 , NO2 Magnesium carbonate MgO and CO2 Magnesium sulfate nothing
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