1. Foods and Fuels Section 5.8

2. Objectives Examine foods and fuels as sources of energy Discuss related health and social issues

3. Key Terms Fuel value Fossil fuels Natural gas Petroleum Coal Renewable energy

4. Fuel Value The energy released when one gram of a material is combusted Represents the heat released Positive values Measured by calorimetry

5. Energy in Foods Most of the fuel in the food we eat comes from carbohydrates and fats.

6. Breakdown of Carbohydrates Starch (a carb) are decomposed in the intestines into glucose, C 6 H 12 O 6 Soluble in blood- blood sugar Transported by the blood to cells: C 6 H 12 O 6 (s)+ 6O 2 (g)  6CO 2 (g) + 6H 2 0 (l)  H° = -2803kJ Rapid breakdown, very little stored Average fuel value = 17kJ/g

7. Breakdown of Fats Body uses chemical energy of foods to maintain temperature, contract muscles, repair tissues Excess energy is stored as fats Insoluble in water Produce more energy per gram than proteins or carbohydrates Average fuel value = 38kJ/g

8. Breakdown of Fats Ex: tristearin 2C 57 H 110 O 6 (s) + 163O 2 (g)  114 CO 2 (g) + 110 H 2 0(l)  H°=-75,520kJ

9. Breakdown of Proteins Produces less energy Different products than carbs and fats Contain nitrogen Building materials for the body Average fuel value = 17kJ/g

11. SAMPLE EXERCISE 15.13 Comparing Fuel Values A plant such as celery contains carbohydrates in the form of starch and cellulose. These two kinds of carbohydrates have essentially the same fuel values when combusted in a bomb calorimeter. When we consume celery, however, our bodies receive fuel value from the starch only. What can we conclude about the difference between starch and cellulose as foods? PRACTICE EXERCISE The nutritional label on a bottle of canola oil indicates that 10 g of the oil has an energy value of 86 kcal. A similar label on a bottle of pancake syrup indicates that 60 mL (about 60 g) has an energy value of 200 kcal. Account for the difference.

12. Solution If cellulose does not provide fuel value, we must conclude that it is not converted in the body into CO2 and H2O, as starch is. A slight, but critical, difference in the structures of starch and cellulose explains why only starch is broken down into glucose in the body. Cellulose passes through without undergoing significant chemical change. It serves as fiber, or roughage, in the diet, but provides no caloric value. Answer: The oil has a fuel value of 8.6 kcal/g, whereas the syrup has a fuel value of about 3.3 kcal/g. The higher fuel value for the canola oil arises because the oil is essentially pure fat, whereas the syrup is a solution of sugars (carbohydrates) in water. The oil has a higher fuel value per gram; in addition, the syrup is diluted by water.

13. SAMPLE EXERCISE 15.14 Estimating the Fuel Value of a Food from Its Composition (a) A 28-g (1-oz) serving of a popular breakfast cereal served with 120 mL of skim milk provides 8 g protein, 26 g carbohydrates, and 2 g fat. Using the average fuel values of these kinds of substances, estimate the energy value (caloric content) of this serving. (b) A person of average weight uses about 100 Cal/mi when running or jogging. How many servings of this cereal provide the energy value requirements for running 3 mi? Solution (a) Analyze: The energy value of the serving will be the sum of the energy values of the protein, carbohydrates, and fat. Plan: We are given the masses of the protein, carbohydrates, and fat contained in the combined cereal/milk serving. We can use the data in Table 5.4 to convert these masses to their energy values, which we can sum to get the total energy value. Solve: Recall that the dietary Calorie is equivalent to 1 kcal. Thus, the serving provides 160 Cal. This corresponds to 160 kcal:

14. SAMPLE EXERCISE 15.14 continued (b) Analyze: Here we are faced with the reverse problem, calculating the quantity of food that provides a specific energy value. Plan: The problem statement provides a conversion factor between Calories and miles. The answer to part (a) provides us with a conversion factor between servings and Calories. Solve: We can use these factors in a straightforward dimensional analysis to determine the number of servings needed, rounded to the nearest whole number:

15. Fuels In the combustion of fuels, carbon is converted to carbon dioxide and hydrogen is converted to water Both are negative enthalpies of formation

16. Societal Implications US consumed 1.03 x 1017 kJ of energy in 2002 100 times greater than the per capita food-energy needs Energy intensive society US population is 4.5% of world, but it accounts for 25% of total world energy consumption

17. Fossil Fuels Major energy sources of the world Formed millions of years from the decomposition of plants and animals Depleted much faster than formed Coal, petroleum, and natural gas

18. Sources of Energy for US

19. Natural Gas Gaseous hydrocarbons Primarily methane, CH 4 Smaller amounts of: Ethane, C 2 H 6 Propane, C 3 H 8 Butane, C 4 H 10

20. Petroleum Liquid composed of hundreds of compounds Most are hydrocarbons Small amount are organic (S, N, O)

21. Coal Solid containing hydrocarbons of high molecular weight Small amount of S, N, and O compounds Most abundant fossil fuel 80% of fossil fuel reserves of the US 90% of the world’s fossil fuel

22. Disadvantages of Coal Combustion of coal releases SO2, an air pollutant Recovery of coal is expensive and dangerous Deposits are far from locations of high- energy use

23. Syngas Mixture of gaseous hydrocarbons made by coal gasification Pulverize and treat coal with steam Coal + steam  complex mixture  CH 4 + H 2 + CO (syngas) Easily transported (pipelines) Less air pollution

24. Nuclear Energy Energy released in either the splitting or the fusion of nuclei of atoms Produces 22% of electric power in US 8% of total US energy production Free of polluting emissions BUT produce radioactive waste products

25. Renewable Energy Fossil fuels and nuclear energy are NONrenewable resources Renewable energy sources are inexhaustible Solar energy- Sun Wind energy- windmills Geothermal energy- mass of Earth Hydroelectric energy- flowing rivers Biomass energy- crops

26. 1. 1. carbohydrates 2. 2. proteins 3. 3. fats

27. 1. 1. carbohydrates 2. 2. proteins 3. 3. fats