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Published byJesse Leonard Modified over 9 years ago
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Why Biodiesel? Produced locally Improved air quality
Renewable resource Simple production process Works in existing infrastructure Today’s diesel cars and trucks Today’s distribution system Today’s filling stations
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Brevard Biodiesel seeks to promote the availability and use of clean-burning, renewable biodiesel fuel as a replacement for petroleum by raising public awareness of its environmental, economic, and national security benefits. Brevard BioDiesel was formed in 2004 in Brevard County, Florida. Web site: BrevardBiodiesel.org
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Making Biodiesel Convert “3-headed” Oils into HydroCarbon chains similar to petroleum diesel… + = Methanol Typical “Biodiesel” (Methyl-Ester) + Typical Oil, three fatty acid chains attached to glycerol. Byproduct: Glycerol aka Glycerine Cetane – typical of petro-diesel
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Making Biodiesel Inputs: Outputs: Vegetable Oil (“Feedstock”)
Methanol/Ethanol Catalyst - “Lye” (Sodium Hydroxide or Potassium Hydroxide) Water Outputs: Biodiesel Dirty Water Glycerine
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Biodiesel Production (Batch type)
FEEDSTOCK: Low-FFA Waste Vegetable Oil Triglycerides Free Fatty Acids (FFA) Water Catfish & French Fries Biodiesel Production (Batch type) Catfish & French Fries Screen Triglycerides FFA Water Methanol Heat & Time Holding/Settling Tank Water Triglycerides FFA NaOH or KOH Transesterification Reactor Reversible Reaction ~60%? Boost using: Excess Methanol Heat (<148ºF) Pressure Remove some glycerin & biodiesel Heat & Agitation Methyl Esters (biodiesel) Soaps Diglycerides Monoglycerides Excess Methanol Glycerin Excess Methanol Settling & Separation Methanol Recovery Wash Waste Water Distillation Methyl Esters (biodiesel) Soaps Diglycerides Monoglycerides Excess Methanol Glycerin Compost (KOH only) Filter Pump & Drive Copyright 2007 Brevard Biodiesel
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Feedstock Choices Waste Vegetable Oil (WVO) Virgin Vegetable Oil Soy
Canola (variety of Europe’s Rapeseed) Palm Other: Hemp, Sunflower, Camelina Tallow Human? Algae
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Oil Feedstock Yields per Acre per Year
Corn – 15 gallons Hemp – 31 gallons Soybeans – 38 gallons Camelina – 50 gallons Sunflowers – 82 gallons Rapeseed/Canola – 102 gallons Jatropha – 162 gallons Oil palm – 508 gallons Algae - 20,000 gallons? (LiveFuels Inc.) GreenFuel Inc:Algae in smokestack filter stack
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Other feedstock considerations
Sustainable source? Palm Oil – Roundtable on Sustainable Palm Oil: rspo.org Will increased biofuel usage minimize human food production? Chemical properties differ – for example palm oil based B100 biodiesel will start to gel at about 55 degrees F! Is there enough? In the US we use billion gallons of diesel on our highways each year. We produce ~5 billion gallons of vegetable oil per year.
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Production System Choices
“Batch” processing vs. Continuous processing Small Scale / Batch processing / (“Homebrewing”) Appleseed “Open Source” Reactor (~$ ) FuelMeister (~$3000-$4000) BioPro (50 gallons in 60 hours) (~$8000) Medium/Large Scale Xenerga, Kissimmee, WVO, 5 million gallons per year (MMgy) (~$2,000,000) ADM, North Dakota, Canola, 85 MMgy
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Appleseed Processor “open-source” design – improved upon by community
Build-it yourself, $200-$500 Kits: Range from $200 for hardware less tank/vents, $700 w/tank, $2000 built on-site.
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Other small processors
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Small System Costs/Sources
Where/How to get Vegetable Oil – restaurants, Prefilter WVO Water settles to bottom of waste oil, scoop from top or press oil from seeds: Methanol/Ethanol – racing fuel Sunoco Racing Alcohol = Methanol $ for 55 gallons Sodium/Potassium Hydroxide Red Devil Lye = NaOH KOH $2-$3/lb at 50lbs for What to do with Glycerine… Making soap: Compost? – but probably not if NaOH, only KOH
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Small System Regulations
Zoning considerations. For example, City of Melbourne incorporates Florida Fire Prevention Code Limits on storage of material, methanol is one of most concern. Recommend talking to nearest fire station captain before starting to review your plans and configuration. Taxes Federal excise tax: analysis of excise tax re: biodiesel: FL State excise tax: ???
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Larger Processing
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Installed Cost Estimates
Roughly $1 per gallon – e.g. 10 Mmgy plant costs about $10,000,000 Links to feasibility studies:
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Government Incentives
Jobs Creation Act of 2004 – Up to $1.00 per gallon tax credit (to blender of biodiesel) Energy Policy Act Credits for using Biodiesel in fleets (EPAct) Minnesota requires 2% of diesel in state be biodiesel (2005+) More:
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Looking Ahead… Biodiesel can be a piece of a comprehensive renewable energy solution. Feedstock selection can impact economic, environmental, and chemical processes. Traditional vegetable oil alone is very unlikely to source the transportation fuel needs of the world. Algae might prove an order of magnitude more important in coming years. “15,000 square miles of algae ponds would be needed to replace all petroleum transportation fuels with biodiesel. “ “$46.2 billion per year for all the algae farms, to yield all the oil feedstock necessary for the entire country. Compare that to the $ billion the US spends each year just on purchasing crude oil from foreign countries, with all of that money leaving the US economy.”
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