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Chapter 6 The Periodic Table
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Introduction Activity
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Label the GROUPS & PERIODS (on BOTH sides)
1 18 2 13 14 15 16 17 3 4 5 6 7 8 9 10 11 12 Make Yourself a KEY!
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Pick a side to start on.
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Metals
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Transition Metals
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Metalloids
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Hydrogen (the ODD 1) Non Metals Make Yourself a KEY!
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Flip the Paper Over
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Representative Elements
1 18 2 13 14 15 16 17 3 4 5 6 7 8 9 10 11 12 Make Yourself a KEY!
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Hydrogen
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Alkali Metals
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Alkaline-Earth Metals
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Boron Group
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Carbon Group
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Nitrogen Group
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Oxygen Group
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Halogens
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Noble Gases
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Lanthanides
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Actinides
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All Together! Make Yourself a KEY!
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Define all of them for 3 EC points!
Chapter 6 Vocabulary Alkali metals Alkaline earth metals Anion Atomic radius Cation Electronegativity Halogens Inner transition metal Ion Ionization energy Metalloids Metals Noble gases Nonmetals Periodic law Representative elements Transition metal Define all of them for 3 EC points!
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And Again…
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Review from yesterday! Complete the chart:
Element Symbol Group Number Period Number Group Name Metal, Nonmetal, or Metalloid? Nitrogen N 15 2 Nitrogen Group Nonmetal Platinum Sn 5 Potassium 17 4 Pt 10 6 Transition Metals Metal Tin 14 5 Carbon Group Metal Antimony Sb Nitrogen Group Metalloid K 1 4 Alkali Metals Metal Bromine Br Halogens Nonmetal
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Section 6.1 Notes Organizing the Elements
Read pages
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How did chemists begin to organize the known elements?
Chemists used the properties of elements to sort them into GROUPS.
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1700 13 elements were identified Included: Copper Silver Gold Carbon
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1765-1775 5 new elements were identified Included: Hydrogen Nitrogen
Oxygen
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1829 J.W. Döbereiner (Johann Wolfgang) German chemist
Grouped some elements into triads Set of three elements with similar properties
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Cl, Br, I have very similar chemical properties.
Can you find them on the Periodic Table?
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1869 Dmitri Mendeleev Russian chemist
Published the first table of elements Arranged the elements in order of increasing atomic mass
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Mendeleev was amazing because he
left spaces in his table for elements not yet discovered predicted properties for these undiscovered elements correctly
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Mendeleev’s 1st Periodic Table
In this early version of Mendeleev’s periodic table, the rows contain elements with similar properties.
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What was wrong with Mendeleev’s Periodic Table?
Let’s look at your Periodic Table What did Mendeleev’s Periodic Table go by? Atomic Mass Any discrepancies? What does yours go by? Atomic Number
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1913 Henry Moseley British physicist
Determined the atomic number for elements Arranged the elements in order of increasing atomic number Today’s Periodic Table
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Today’s Periodic Table
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Periodic Law when elements are arranged by increasing atomic number, properties of the elements tend to repeat
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Metals to the left of the stair-step line most of the elements (80%)
Properties Good conductors of heat and electricity Shiny (luster) Solid at room temperature Except liquid mercury Ductile Drawn into wires like copper wire Malleable Hammer into thin sheets like aluminum foil
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Metals
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Of all the elements that make up the world in which we live – solids, liquids, gases – most are metals. Al Cu Zn There are metals such as aluminum, zinc, gold, copper, tin, and nickel – and ones you might not think of as metals, such as calcium, which is present in bones and teeth. Did you know that the average human body contains more than 2 lbs of calcium? Ca Ni Sn Au
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Some metals are dangerous.
Potassium reacts violently with water creating hydrogen gas. Cesium and rubidium will explode if they touch water. Cs Rb K
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Mercury is poisonous. In fact, the phrase “mad as a hatter” arose because in past centuries, fumes from the mercury used in the hat making process affected the mental health of workers in that industry!
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The high density of osmium, Os, – a metal in the same period as platinum – means that a brick of the metal can weigh as much as a small car. Osmium is used in fountain pen nibs and surgical needles. Platinum, Pt, is one of the rarest and most valuable of all metals. It is used to make jewelry and used extensively in industry.
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Can you find element names hidden in these sentences?
Nick, elbows off the table please! Grandpa is looking older. Your feet are a little stinky. Do you care about the environment? I placed a simple ad in the paper.
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Nonmetals to the right of the stair-step line
most are gases, few solids except liquid bromine Properties: poor conductors of heat and electricity solids tend to be brittle
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Hydrogen (the ODD 1) Nonmetals
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Diatomic Elements BrINCl HOF LABEL THEM ON YOUR P.T.
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Metalloids Si Touch the stair-step line
Except aluminum and polonium Have properties of both metals and nonmetals Si
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Metalloids
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Metals / Metalloids / Nonmetals Just like Intro Activity
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Metals, Nonmetals, and Metalloids
Inferring: What is the purpose for the black stair-step line?
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Quick Quiz Section 6.1
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1. The modern periodic table has elements arranged in order of
colors. melting and boiling points. increasing atomic mass. increasing atomic number.
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atomic mass. number of protons. number of electrons. atomic number.
2. Mendeleev arranged the elements in his periodic table in order of increasing atomic mass. number of protons. number of electrons. atomic number.
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3. Which one of the following is NOT a general property of metals?
ductility malleability having a high luster poor conductor of heat and electricity
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What’s Next? Book Work: Page 160 #’s 1-7
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Page 160 #1-7 How did chemists begin the process of organizing elements? What property did Mendeleev use to organize his periodic table? How are elements arranged in the modern periodic table? Name the three broad classes of elements. Which of the sets of elements have similar physical and chemical properties? Oxygen, nitrogen, carbon, boron Strontium, magnesium, calcium, beryllium Nitrogen, neon, nickel, niobium Identify each element as a metal, metalloid, or non-metal. Gold Silicon Sulfur Barium Name two elements that have properties similar to those of the element sodium.
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1. How did chemists begin the process of organizing elements?
Chemists used the properties of elements to sort them into groups, or triads.
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2. What property did Mendeleev use to organize his periodic table?
Increasing atomic mass
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3. How are elements arranged in the modern periodic table?
Increasing atomic number
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4. Name the three broad classes of elements.
Metals, Non-Metals, and Metalloids
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(B) strontium, magnesium, calcium, beryllium
5. Which of the sets of elements have similar physical and chemical properties? (B) strontium, magnesium, calcium, beryllium
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6. Identify each element as a metal, metalloid, or non-metal.
Metal (Au) Metalloid (Si) Non Metal (S) Metal (Ba)
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7. Name two elements that have properties similar to those of the element sodium.
Li, K, Rb, Cs, Fr
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Section 6.2 Notes Classifying the Elements
Read pages
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Representative Elements
Groups 1A through 8A Groups 1, 2, 13-18
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Representative Elements
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Transition Elements Transition metals Inner transition metals Group B
Groups 3-12 Inner transition metals Last 2 rows on the periodic table
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Transition Elements Inner Transition Elements
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Similar to your colored Periodic Table
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Periodic Table Key The periodic table displays the symbols and names of the elements, along with information about the structure of their atoms.
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Quick Quiz Section 6.2
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1. Which one of the following is incorrectly labeled?
Ne, noble gas Cu, transition metal Ga, transition metal Cl, halogen
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What’s Next? Book Work: Page 167 #’s 10, 12, 14
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10. What information can be included in a periodic table?
Symbols and names. Structure. Properties.
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K and Na are in the same group. (Alkali Metals)
12. Why do the elements potassium and sodium have similar chemical properties? K and Na are in the same group. (Alkali Metals)
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14. Which of the following elements are transition metals?
Cu, Sr, Cd, Au, Al, Ge, Co
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Section 6.3 Notes Periodic Trends
Read pages
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What does the word periodic mean to you?
Happens in intervals What are some examples of things that happen periodically? Birthdays, holidays, periodicals
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Why is the periodic table called “The Periodic Table”?
the properties of elements repeat
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Trend A predictable change Periodic Trend
Properties of the elements repeat and form patterns Allows us to make predictions about the chemical behavior of elements How elements will react with other elements Many trends exist in the periodic table
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Atomic Radius Half the distance between two nuclei of the same atom
Describes the size of the atom
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Rb K Atomic Radius Trend Na Down a group Increases Why?
Li Na Down a group Increases Why? Number of energy levels increases Period 1 = 1 e. l., Period 2 = 2 e. l., Etc… K Rb 85
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Na Mg Atomic Radius Trend Al Si P Across a period S Cl Decreases Why?
Ar Across a period Decreases Why? Electron / proton attraction increases Opposite of tug of war!
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Trends in Atomic Size alkali metal Predicting:
If a halogen and an alkali metal are in the same period, which one will have the larger radius? alkali metal
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Shielding Effect “shielding” is the nuclear pull on electrons
Valence electrons are “shielded” from the pull / charge of the nucleus by all the electrons in between.
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Ions Positively charged ion Formed by metals Lost electrons
An atom with a charge Cation Positively charged ion Formed by metals Lost electrons Anion Negatively charged ion Formed by nonmetals Gained electrons
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How do ions form? Positive and negative ions form when electrons are transferred between atoms.
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Positive Ions When a sodium atom loses an electron, it becomes a positively charged ion. Interpreting Diagrams: What happens to the protons and neutrons during these changes? NOTHING!!!
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Negative Ions When a chlorine atom gains an electron, it becomes a negatively charged ion. Interpreting Diagrams: What happens to the protons and neutrons during these changes? NOTHING!!!
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Cation Metals Anion Nonmetals
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Comparing and Contrasting:
This diagram compares the relative sizes of atoms and ions for selected alkali metals and halogens. The data are given in picometers. Comparing and Contrasting: What happens to the radius when an atom forms a cation? When an atom forms an anion?
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Ionic Size Size of the ion compared to the parent atom Cations
Positive ions are smaller than the atom it comes from Why? It lost electrons Anions Negative ions are larger than the atom it comes from It gained electrons
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Trends in Ionic Size Ionic Radius Increases Ionic Radius Decreases
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First Ionization Energy
energy needed to remove an electron from an atom
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First Ionization Energy Trend
Down a group Across a period Decreases Why? Valence electrons are farther away from the nucleus Increases Why? The atom becomes more stable with more valence electrons
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Multiple Ionization Energies
What would the 2nd Ionization Energy mean? Energy needed to remove the second electron What would the 3rd Ionization Energy mean? Energy needed to remove the third electron Why are elements such as H and He missing some ionization energy values?
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Trends in Ionization Energy
Predicting: Which element would have the larger first ionization energy, an alkali metal in period 2 or an alkali metal in period 4? Period 2 alkali metal
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Electronegativity The ability of an atom to attract electrons to itself when bonded to another atom
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Electronegativity Trend
Down a group Across a period Decreases Why? Valence electrons are farther away from the nucleus Same reason as ionization energy Increases Why? Atom becomes more stable with more valence electrons Same reason as ionization energy Don’t count noble gases
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Most Active Elements Most active metal Most active nonmetal Why? Why?
Fr (Francium) Why? Lowest electronegativity Most active nonmetal F (Fluorine) Why? Highest electronegativity
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Summary of Trends Recap
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Atomic Size Decreases Increases
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Ionization energy Increases Decreases
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Electronegativity Increases Decreases
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Page 178: Draw arrows to show periodic trends below.
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Quick Quiz Section 6.3
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1. Which of the following sequences is correct for atomic size?
Mg > Al > S Li > Na > K F > N > B F > Cl > Br
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2. Metals tend to gain electrons to form cations.
gain electrons to form anions. lose electrons to form anions. lose electrons to form cations.
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3. Which of the following is the most electronegative element?
Cl Se Na I
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What’s Next? Book Work: Page 178 #’s 16-23
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16. How does atomic size change within groups and across periods?
In general, atomic size increases from top to bottom within a group and decreases from left to right across a period.
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17. When do ions form? Positive and negative ions form when electrons are transferred between atoms.
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18. What happens to first ionization energy within groups and across periods?
First ionization energy tends to decrease from top to bottom within a group and increase from left to right across a period.
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19. Compare the size of ions to the size of atoms from which they form.
Cations (+) are always smaller than the atoms from which they form. Anions (-) are always larger than the atoms from which they form.
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20. How does electronegativity vary within groups and across periods?
In general, electronegativity values decrease from top to bottom within a group. For representative elements, the values tend to increase from left to right across a period.
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21. In general, how can the periodic trends displayed by the elements be explained?
The trends that exist among these properties can be explained by variations in atomic structure.
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Sodium > Aluminum > Sulfur > Chlorine
22. Arrange the elements in order of decreasing atomic size: Sulfur, Chlorine, Aluminum, Sodium. Sodium > Aluminum > Sulfur > Chlorine
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23. Which element in each pair has the larger first ionization energy?
Sodium, Potassium Magnesium, Phosphorus
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You need to know the NAME (Spelling Counts) and SYMBOL of the following elements (not the location)
Be B C N O F Ne Na Mg Al Si P S Cl Ar K Ca Ti Cr Mn Fe Co Ni Cu Zn As Br Rb Ag Sn I Ba Pt Au Hg Pb Fr 40 of them
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The Periodic Law A Puzzle Activity
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Introduction The present organization of the elements is a product of the first periodic table published by Dmitri Mendeleev in The amazing accuracy of his predictions has been very important to chemists in this century. However, the basis of his arrangement was the atomic masses of the elements. This approach proved incorrect as it would have placed some elements in a group with dissimilar properties. Henry Moseley rearranged the table on the basis of the atomic numbers of the elements. In accordance with Moseley’s revision, the periodic law states: the properties of the elements are periodic functions of their atomic numbers. Each of the 100+ known elements has its own set of characteristic properties. These range from solid to gas, lustrous to dull, low to high melting points, various colors, and so on. The elements are arranged within the periodic table into groups (vertical columns) and periods (horizontal rows). This arrangement reflects the periodic or repeating nature of the properties of the elements.
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Purpose In this activity, you will use your knowledge of periodic properties and a list of clues to correctly arrange the elements from a scrambled periodic table.
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Procedure / Clues The following sets of elements belong together in groups: PSIF, JXBE, ZRD, LHT, QKA, WOV, GUN, YMC Letter clues: The electrons of atom N are distributed over three energy levels. J has an atomic number three times that of T U has a total of six electrons I2A is the simple formula of an oxide P is less dense than S S is an alkali metal E is a noble gas W is a liquid Z has the smallest atomic mass in its group B has ten protons O has an atomic number larger than V D has the largest atomic mass of its group C has five electrons its outer energy level F is a gas X has an atomic number one higher than F L is an alkaline earth element with atomic mass of 40 Y is a metalloid O is a halogen The atomic mass of T is more than that of H Q has an atomic mass 2 times A Atoms of I are larger than those of S M has an atomic number one less than that of A The atomic radius of K is the largest of the group
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Then you know that GUN are in this group
Place the correct letter below in their appropriate spot according to the Periodic Table! 1 2 13 14 15 16 17 18 Then you know that GUN are in this group U Let’s do one together… J has an atomic number three times that of T U has a total of six electrons
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Have Fun Extra Credit – Due Tomorrow
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Answers F X P H Z U M A V B S T R N C Q O E I L D G Y K W J 1 2 13 14
15 16 17 18 F X P H Z U M A V B S T R N C Q O E I L D G Y K W J
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