1. Unit 4: BONDING Why do elements form bonds????

2. I. Energy and Bonds Elements form bonds to become more stable Forming bonds releases energy Breaking bonds absorbs energy Therefore: –Forming a bond is… –Breaking a bond is…

3. II. Types of Bonds attractive force that hold elements togetherBond = attractive force that hold elements together There are 3 major types of bonds formed between elements Each type of bond has different attractions and different properties

4. Identifying Bond Types… A] Metallic bonds: present within a metal B] Ionic bonds: metal + nonmetal –Cations and anions form neutral substances –Electrons are given/taken to form ions C] Covalent: nonmetals sharing electrons –No actual charges formed

5. III. Lewis Dot Structures Lewis dot diagrams show number and relative placement of valence electrons Uses element symbol and dots in pattern 1 2 83 56 7 4

6. A. Single Elements Count number of valence electrons [look at “s” and “p” electrons] Place in pattern around element symbol Ex.]

7. B. Ions and Ionic Compounds Determine the charge of the ion within the compound [ look at oxidation numbers on PT ] –Positive ions have NO valence electrons! –Negative ions have 8 valence electrons! Arrange with opposite charges connecting Ex.] NaClMgCl 2

8. C. Covalent Structures Determine the number of valence electrons for each element involved Choose a central atom [least popular] Organize remaining atoms symmetrically Form bonds to provide each element with 8 valence electrons May use multiple bonds for each element to see 8 Ex.] H 2 O 2 N 2

9. D. The Octet Rule Octet = eight valence electrons on an atom –valence electrons are those in “s” and “p” sublevels Elements with 8 valence electrons are very stable and usually not reactive! –What group has all 8 valence electrons naturally? –Which group of metals is most reactive? –Which nonmetals are most reactive?

10. Octets, continued… Since all elements want 8 electrons, each atom will gain or lose electrons to “see” 8 valence electrons –Metals lose electrons –nonmetals gain electrons Ex.] NaClMgO

11. Exceptions to Octet Rule Some need less than 8: –H, He, B Some can take more than 8, creating an expanded octet: –S, P, etc.

12. IV. Metallic Bonds Metallic Bonds = special bonds between the atoms within a metal sample Have fixed nuclei with mobile electrons “Sea of Mobile Electrons” Give metals special properties: –Malleability-- Good Conductivity –Ductility –http://micro.magnet.fsu.edu/electromag/java/rutherford/http://micro.magnet.fsu.edu/electromag/java/rutherford/

13. Diagram of Metallic Bonding http://www.drkstreet.com/resources/metallic-bonding- animation.swfhttp://www.drkstreet.com/resources/metallic-bonding- animation.swfmetallic bonding online demo

14. V. Covalent Bonds Covalent bonds are formed between NONMETALS who share electrons Some nonmetals can form more than one bond between the same 2 elements Different types of covalent bonding, due to symmetry and electronegativity values No formal charge, or ions, formed

15. Properties of Covalent Compounds All phases present at STP Low boiling and melting points Low density High vapor pressure, or volatility Poor conductors of heat and electricity

16. a. Nonpolar Covalent Bonds Nonpolar = equal sharing Electrons shared within a bond are “seen” equally by both atoms Between same atoms ONLY!

17. b. Multiple Bonds 1]Single Bonds = 2 e- shared between 2 atoms 1 e- from each element Not very strong Longest covalent bond Examples: –some diatomics

18. Multiple Bonds, cont. 2] Double Bonds = 4 e- shared between 2 atoms 2 e- from each element Stronger and shorter than single bonds Examples: –O 2

19. Multiple bonds cont’. 3] Triple bonds = 6 e- shared between 2 atoms 3 e- from each element Strongest and shortest bond type Examples: –N 2

20. ONLINE RESOURCES Online resources for understanding bonding geometries of common compounds: https://phet.colorado.edu/en/simulation/molecule-shapes https://phet.colorado.edu/en/simulation/molecule-shapes-basics http://www.pbslearningmedia.org/asset/lsps07_int_covalentbond/ Great Polar covalent bonds link: http://www.chem1.com/acad/webtext/chembond/cb04.html http://www.chem1.com/acad/webtext/chembond/cb04.html

21. c. Polar Bonds Polar bonds Polar bonds are formed between atoms having differences in EN oAtoms of different EN will have different attractions for the bonding electrons oThe atom with the higher EN will have a stronger attraction for the bonding electrons Most polar bonds are ‘polarized’ meaning that the electrons spend more time closer to the atom with the higher EN and less time near the atom of a lower EN

22. Polar Bonds cont’ Molecules with polar bonds will have “Dipoles” Dipoles = a charge imbalance within a bond created by different attractions for the bonding electrons

23. d. Coordinate Covalent Bonds Coordinate covalent bonds bonds formed when only one element contributes electrons to the bond Only in special cases:

24. d. Network Covalent Bonds Network covalent bonds = these are very strong bonds formed within a network solid between atoms of the same element or molecule Special cases:

25. VI. Molecular Structures Molecular shapes depend upon the distribution of electrons number of bonds formed Shapes are 3- Dimensional http://www2.chemistry.msu.edu/faculty /reusch/virttxtjml/models.htm#starthttp://www2.chemistry.msu.edu/faculty /reusch/virttxtjml/models.htm#start

26. a. Nonpolar Molecules Nonpolar bondsNonpolar bonds are formed only between atoms having the same EN Only diatomic elements have true nonpolar bonds All bonding electrons are shared equally between atoms of the same EN Ex. Diatomic molecules…

27. Nonpolar, cont’ Even polar bonds can create nonpolar molecules… Nonpolar molecules are SYMMERTICAL! Electrons are evenly distributed throughout the molecule, making it nonpolar! S ymmetrical = N onpolar Ex.] CF 4

28. b. Polar Molecules Polar Molecules have an asymmetric pull of electrons throughout the molecule Nonbonding electrons from lone pairs also create an asymmetric pull within the molecule A symmetric = P olar Ex.] H 2 O

29. Polar or Nonpolar Molecule??? Examples: a. CO 2 b. OF 2 c. CCl 4 d. CH 2 Cl 2 e. HCN

30. c. Molecular Shapes, in 3D! Atoms are 3-dimensional substances that create 3-D structures when bonding Both the bonds and the lone pair [nonbinding] electrons play a role in determining the shape of a molecule

31. Bonding/Molecular Shape Terms DomainDomain = placement of electrons around an atom Bonding DomainBonding Domain = includes all electrons participating in a bond; counts as one area of space Nonbonding DomainNonbonding Domain = space occupied by a lone pair of electrons [nonbonding]

32. Additional [secret] information: the VSEPR Theory VSEPR = Valence Shell Electron Pair Repulsion –This theory explains why the electrons within the bonds and the nonbonding electrons move as far apart as possible, creating a structure in 3-dimensional space Nonbonding pairs sometimes have a greater effect than single bonds… let’s see!

33. B. Shapes and Bond Angles http://intro.chem.okstate.edu/1314F97/Chapter9/VSEPR.html Or http://en.wikipedia.org/wiki/Molecular_geometry

34. 1. Linear 1 or 2 bonding domains 180 o bond angle Symmetric if same elements, or distributed evenly Asymmetric if different atoms Examples: Diatomics, CO 2, HCl

35. 2. Trigonal Planar 3 bonding domains 120 o bond angle Symmetric if all same elements Flat molecule! Examples: BF 3, SO 3

36. 3. Trigonal Pyramidal 3 bonding domains, 1 nonbonding domain 107 o bond angle Asymmetric due to lone pair electrons Examples: NH 3, PCl 3

37. 4. Bent 2 bonding domains, 2 nonbonding domains 104.5 o bond angle Asymmetric due to two lone pairs of electrons Examples: H 2 O, SCl 2

38. 5. Tetrahedron 4 bonding domains 109.5 o bond angle Symmetric if all the same atoms bonded Asymmetric if different atoms Examples: CH 4, CCl 4

39. 6. Trigonal Bipyramidal 5 bonding domains Expanded octet of 10 electrons 120 o and 90 o bond angle Symmetric if all the same atoms bonded Asymmetric if different atoms Examples: PF 5

40. 7. Octahedral 6 bonding domains Expanded octet of 12 electrons 90 o bond angle Symmetric if all the same atoms bonded Asymmetric if different atoms Examples: SF 6

41. VII. Ionic Bonds Ionic bonds = a bond formed due to the transfer of electrons between metals and nonmetals Attractions [bonds] occur between ions [charged atoms that have gained/lost electrons] CationsCations = positive ions; have _______e- –Metals form cations AnionsAnions = negative ions; have ______e- –Nonmetals form anions

42. Properties of Ionic Bonds High melting/boiling points Hard, but brittle crystals [solids] Dissolve in polar solvent Conduct electricity as liquid or in solution, but NOT as a solid

43. Properties cont. Ionic substances have high heats of vaporization Low vapor pressure; not very volatile Most dissolve in water to form (+) and (-) ions, or electrolytes

44. A. Electronegativity Differences Ionic Bonds Large differences in EN = Ionic Bonds When there is a larger difference in EN, the element with the higher EN will most likely to “see” the bonding electrons more, or share them less Ionic bonds have the greatest differences in EN! reinforced by the fact that one of the elements will actually TAKE the electrons instead of sharing them

45. Covalent Bonds and EN do Even though nonmetals have relatively low EN in general, they do have slight differences The only time there is no EN difference between atoms is for Diatomic elements This means that the electrons in the bond(s) between the diatomic elements will be shared equally

46. Rankings of EN Differences See Figure 6-11, page 107, and figure 6-14, page 109 00.31.7>1.9 Diatomic Nonpolar Polar Ionic Elements Covalent Covalent Bonds

47. Polar bonds in Molecules Arrows point to the element with the highest EN Use lower case Greek letter delta to represent partial charges: δ+ or δ- Partially negative = more Electronegative atom!

48. b. Polyatomic Ions See Table E!!! Have BOTH covalent and ionic properties Covalent bonds hold the atoms together within the ion Overall, the structure has lost/gained electrons to have a charge Share electrons within, has brackets and charges for the Lewis Structure

49. E. Resonance Structures Lewis dot structures with double-bond electrons that rotate from one pair to another Overall structure = hybrid of all resonance structures

50. Other Resonance structures NO 3 -1 C 6 H 6 SO 3 -2 CO 3 -2

51. Review: Bond Strengths Network Covalent Ionic Covalent Triple Bond Covalent Double Bond Covalent Single Bond More Stable Molecules = Stronger Bonds

52. Larger EN Differences = Stronger Bonds Stronger Bonds Equal More Stable Molecules

53. VIII. Intermolecular Forces INTRAmolecular forces: forces between atoms –Bonds = forces between the atoms INTERmolecular forces: forces between molecules –Four major variations –Depends on the type of molecules or ions involved

54. 1] Molecule-Ion Attractions: Definition: Invisible force of attraction holding polar molecules and ions together in a solution Need: polar molecules as solvent and ionic compound [create (+) and (-) ions]

55. Molecule-ion forces… The strongest of all the intermolecular forces! –Positive ion attracted to partially negative end of polar molecule –Negative ion attracted to partially positive end of polar molecule –Orientation of polar molecules important!!!! –Ex.] Solution of NaCl(aq)

56. 2] Dipole-Dipole Attractions Definition: Partially positive and partially negative ends of polar molecules develop attractive forces Need: polar molecules as liquid

57. Dipole-Dipole forces… Occur within a sample of polar molecules Attraction occurs between partially positive ends of several of same polar molecules –Partially positive end of the molecule– near the atom with lower EN [bonding electrons pulled away from it] –Partially negative end of molecule—near the atom with the highest EN [pulls bonding electrons towards it] Ex.] HCl, HBr, HI

58. 3] Hydrogen Bonding Definition: Special type of dipole- dipole forces occurring between polar molecules containing hydrogen and fluorine, oxygen, or nitrogen Ex.] HF, H 2 O, and NH 3

59. Hydrogen Bonding… Stronger than Dipole-Dipole, but weaker than actual bonds forming Hydrogen [partially (+)] strongly attracted to F, O, or N [partially (-)] end of molecule F, O, and N have high EN, small radii, and strong pull on bonding electrons Responsible for: –Abnormally high boiling point of water –Larger volume of water in liquid phase

60. 4] Weak, London Dispersion, or Van der Waals Forces Definition: Weak attractive forces present between nonpolar molecules Need: Nonpolar, symmetric molecules

61. Weak, LD, or VdW forces… Weakest attractive forces Created when nonpolar atoms/molecules have small, temporary dipoles formed via distribution of electrons Change as… –Distance between molecules increase, forces decrease –Mass of molecules increase, forces increase

62. “Special effects” of weak/LD/VdW forces… Reason why diatomic elements of group 17 have increasing boiling points from top to bottom –Remember phases of group 17: –gas, gas, liquid, solid, solid Cause hydrocarbons of fossil fuels to have increasing boiling points as their size and mass increase –Methane is a gas, gasoline is a liquid, grease is a solid at the same temperatures

63. Strengths of IMF’s: Strongest to Weakest 1] Molecule-ion 2] Hydrogen bonding 3] Dipole-Dipole 4] London Dispersion/Van der Waals/Weak