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Energy, Free Energy, and Equilibrium General Chemistry II CHM 112 Dr Erdal OnurhanSlide 1 Spontaneity.

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Presentation on theme: "Energy, Free Energy, and Equilibrium General Chemistry II CHM 112 Dr Erdal OnurhanSlide 1 Spontaneity."— Presentation transcript:

1 Energy, Free Energy, and Equilibrium General Chemistry II CHM 112 Dr Erdal OnurhanSlide 1 Spontaneity

2 Energy, Free Energy, and Equilibrium General Chemistry II CHM 112 Dr Erdal OnurhanSlide 2 Microstates of a System Suppose you have four dissimilar balls and two different boxes. How many ways are there to distribute the balls among the boxes? 11+5 (Distribution I and II will transpose to give 5 further arrangements) Number of the arrangements is the number of microstates of the system - 16

3 Energy, Free Energy, and Equilibrium General Chemistry II CHM 112 Dr Erdal OnurhanSlide 3 Changes in Entropy

4 Energy, Free Energy, and Equilibrium General Chemistry II CHM 112 Dr Erdal OnurhanSlide 4 Change in Entropy of Surroundings

5 Energy, Free Energy, and Equilibrium General Chemistry II CHM 112 Dr Erdal OnurhanSlide 5 Absolute Entropy

6 Energy, Free Energy, and Equilibrium General Chemistry II CHM 112 Dr Erdal OnurhanSlide 6 Convention for Standard States

7 Energy, Free Energy, and Equilibrium General Chemistry II CHM 112 Dr Erdal OnurhanSlide 7 Factor Affecting Sign of  G

8 Energy, Free Energy, and Equilibrium General Chemistry II CHM 112 Dr Erdal OnurhanSlide 8  G During a Reaction


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