1. Welcome to Marquette University’s Hazardous Waste and Emergency Procedures Awareness Training

2. Why am I here? Handle or generate hazardous materials
Formal personnel training program is a requirement for large quantity generators (49 CFR )
To be trained on the proper procedures of accumulating and storing hazardous materials to ensure compliance with the law
To prevent personal injury, property damage, or a major spill

3. Agenda Marquette’s Classification & History
Hazardous Waste Characteristics
Recognizing Hazardous Materials
Handling Hazardous Materials & Proper Personal Protective Equipment
Satellite Accumulation Procedures
90-Day Storage Area Procedures
Spill Response, Clean-Up, Emergency Response and Preparedness

4. Acronyms EPA = Environmental Protection Agency
Determines what is a hazardous waste
DOT = Department of Transportation
Regulates transportation of hazardous materials
RCRA = Resource Conservation & Recovery Act
Governs the disposal of solid and hazardous wastes
DNR = Department of Natural Resources
Governs over the generators of hazardous waste
OSHA = Occupational Safety and Health Administration
Regulates hazardous materials in the workplace
PPE = Personal Protective Equipment
Last line of defense against hazardous materials

5. Marquette’s History and Classification

6. Marquette’s Hazardous Waste History
In 2010:
8,281 pounds of Hazardous Waste
1,204 pound of Non-Hazardous Waste
In 2009:
20,157 pounds of Hazardous Waste
13,413 pounds of Non-Hazardous Waste
In 2008:
8,623 pounds of Hazardous Waste
2,198 pounds of Non-Hazardous Waste
In 2007:
12,397 pounds of Hazardous Waste
8,018 pounds of Non-Hazardous Waste
Halogenated Solvents and Non-Halogenated Solvents
Veolia ES Technical Solutions disposes of materials
Small Quantity Generator to a Large Quantity Generator
Developing procedures and plans to comply with new regulations from this transition

7. Three Categories of Generators
Very Small Quantity Generator (VSQG)
< 220 lbs/month generation or < 2205 lbs total accumulation
Small Quantity Generator (SQG)
lbs/month generation or < 13,230 lbs total accumulation
Large Quantity Generator (LQG)
> 2205 lbs generation/month or > 13,230 lbs total accumulation
Acute Waste
>2.2 lbs/month generation or > 2.2 lbs accumulation at any time makes you a LQG

8. How much is that?
2200 lbs. (1000 kg) is about five 55-gallon drums

9. Hazardous Waste Determination
Characteristic versus Listed Wastes

10. Hazardous Waste Determination
EPA Listed Wastes
P Listed: Unused acutely Hazardous Waste
U Listed: Unused non-acutely hazardous waste
K Listed: Waste from Specific Sources
F Listed: Waste from Non- Specific Sources
Characteristic Wastes
Ignitability
Corrosivity
Toxicity
Reactivity

11. Ignitable Wastes
Flashpoint <140° F, or solids that easily catch fire.
- Examples: acetone, xylene, and acetonitrile and other solvents
Compressed flammable gases, such as propane
Flammable solids, such as road flares or carbon.
Ignitable materials are represented by a D001 waste code.

12. Corrosive Wastes
- pH <2 or >12.5
- Capable of corroding steel at a rate greater than 0.25 inches per year.
Examples: nitric acid, aqueous sodium hydroxide, hydrochloric acid.
Corrosive materials are represented by a D002 waste code.
Potassium Tert-butoxide, a flammable solid

13. Reactive materials are represented by a D003 waste code.
Reactive Wastes
Materials that undergo violent change:
- react violently with water or air
- capable of detonation
- create toxic gases when exposed to pH extremes
Examples: sodium metal, extremely dry picric acid, and organic peroxides.
Reactive materials are represented by a D003 waste code.

14. Toxic Wastes
Materials that are poisonous, harmful and potentially deadly
Examples: lead acetate, mercuric chloride, benzene.
The wastes are represented by codes from D004 – D043. These codes are specific to material types. For example: Mercury has a D009 code, Benzene has D018.

15. Examples of Toxic Contaminants
Heavy Metals:
arsenic, barium, cadmium, chromium, lead, mercury, selenium, silver
Pesticides:
Chlordane, 2,4-D, Endrin, Lindane, Heptachlor, Methoxychlor, Silvex (2,4,5-TP), Toxaphene.
Organics:
benzene, carbon tetrachloride, chlorobenzene, chloroform,
Organics, continued:
cresol, 1,4-dichlorobenzene, 1,2-dichloroethane, 1,1-dichloroethylene, 2,4-dinitrotoluene, hexachlorobenzene, hexachlorobutadiene, hexachloroethane, methyl ethyl ketone, nitrobenzene, pentachlorophenol, pyridine, tetrachloroethylene, trichloroethylene, 2,4,5-trichlrophenol, 2,4,6-trichlorophenol, vinyl chloride.

16. Contact Dennis Daye (414) if you have questions about the status of your waste. Hazardous Waste Management can be very confusing and we are here to help you! Aaron Walters, Veolia Environmental Services On campus Wednesday from 2-4 PM

17. Recognizing Hazardous Materials

18. Recognizing Hazardous Materials
Read Material Safety Data Sheets (MSDS)
A document provided by the manufacturer
Contain ingredients and lists the hazards of materials
Lists routes of exposure and proper PPE that should be worn when handling
Has spill response, disposal and other environmental information
Contains contacts if further information is needed M S D
Material Safety Data Sheets

20. National Fire Protection Association (NFPA) Label
Colors and numbers are used to communicate the potential hazards of a material.
Flammability
Hazard
Health
Hazard
Reactivity
Hazard
Specific
Hazards

21. NFPA: Health Hazard

22. NFPA: Flammability Hazard

23. NFPA: Reactivity Hazard

24. NFPA: Specific Hazards

25. Hazardous Materials Identification System(HMIS) Label
Colors, numbers, and letters are used to communicate the potential hazards of a material as well as what kind of protective equipment should be worn.
HEALTH
0-4
FLAMMABILITY
0-4
REACTIVITY
0-4
PERSONAL PROTECTION
letter

26. B Safety glasses/gloves
HMIS: Personal Protection
Safety glasses/gloves /vapor respirator
Goggles/gloves/apron/ vapor respirator
Safety glasses/gloves/dust and vapor respirator
Goggles/gloves/apron/dust and vapor respirator
Airline hood or mask/gloves/protective coveralls/boots
Ask your supervisor
A Safety glasses
B Safety glasses/gloves
Safety glasses/gloves/apron
Face shield/gloves/apron
Safety glasses/gloves/dust respirator
Safety glasses/gloves/dust respirator/apron

27. DOT Hazard Classes
Department of Transportation (DOT) Hazard Class Diamonds and Placards
Containers and trucks are marked with diamonds to inform you of the material’s hazard class
Class 1 – Explosives
Class 2 – Gases
Class 3 – Flammable Liquids
Class 4 – Flammable Solids
Class 5 – Oxidizers and Organic Peroxides
Class 6 – Toxic Materials and Infectious Substances
Class 7 – Radioactive Materials
Class 8 – Corrosive Materials
Class 9 – Miscellaneous Hazardous Materials

28. DOT Labels

29. Hazardous Material Handling and Proper Personal Protective Equipment

30. Considerations when Handling Hazardous Materials
Use common sense!
Think before you act
Follow good housekeeping procedures
Clean-up after yourself
Always wear the proper PPE
Know the hazards of the materials you are working with!
Create and use chemical specific SOP’s (Safe Operating Procedures)

31. Material Handling and Proper PPE
Controlling Hazards
1. Engineering Controls
Eliminate the hazard from the workplace
2. Administrative Controls
Limit worker contact with the hazard
Training/Procedures, Good Housekeeping
3. PPE
LAST RESORT
Engineering and administrative controls should be used, but do not completely alleviate the hazard

32. PPE = Last Resort
When PPE is the primary control measure, the hazard is still present in the environment
Failure of the PPE or improper usage can expose the worker to the full effect of the hazards present in the environment

33. Types of PPE Head Protection Eye/Face Protection Hearing Protection
Foot Protection
Respiratory Protection
Hand and Arm Protection
Electrical Protective Devices
Special Work Clothing

34. Considerations for PPE Selection:
The types of hazards you will be in contact with
Physical Hazards
Chemical Hazards
The specific chemicals you will be in contact with
The concentration of these chemicals
The length of time the PPE is to be worn
The durability of the PPE

35. PPE continued PPE Limitations PPE Failure Degradation
Permeation/Breakthrough
Penetration
Tears/Rips
Location
PPE Failure
Knowing how to recognize PPE failure is crucial since PPE is the last line of protection between you and the chemical
Limit contact time with the chemical/hazard and inspect and change PPE frequently

36. Satellite Accumulation Procedures

37. Satellite Accumulation
“A generator may accumulate as much as 55 gallons of hazardous waste…in containers at or near any point of generation…which is under the control of the operator…”
Up to 1 quart of acutely hazardous waste (P-coded) can be collected in a satellite accumulation area
Your research labs, student labs or other rooms where materials are collected and accumulated are considered to be Satellite Accumulation Areas

38. Satellite Accumulation
Material name must be on label –
NO CHEMICAL FORMULAS OR ABBREVIATIONS!!!
The container must have the words “hazardous waste”
Containers must remain closed when not adding waste
Must be leak-proof and in good condition
Containers must be compatible with contents
No corrosive materials in metal containers
Store liquid wastes in secondary containers
Must be able to hold 110% of the largest containers volume
Containers must be moved to storage location within 3 days after being filled
The containers must remain closed when waste is not being added or removed
The containers must be leak-proof and in good condition
The containers must be compatible with contents
The containers must be moved to storage location within 3 days after being filled***
The accumulation start date is the day the container is filled – not the day you first add material into the container.

39. Accumulation Start Date
There are two (2) Regulations to follow:
Material can not be stored / accumulated in satellite accumulation area for more than one year.
Material can not be stored for more than 90 days in 90-Day Storage Area.
So, please put the date that you start accumulating material on the Hazardous Waste Tag.
Before submitting for disposal, please cross-out and initial by the old date and write in the current date

40. Example of Inadequate Labeling

41. Example of Inadequate Labeling

42. Container Management Attach label BEFORE adding waste
Container must be closed when not adding waste
Lids must be on – no funnels
Containers should be kept in their designated areas
Keep the outsides of containers free of waste
Do not use the top of the container as a storage shelf
Free access to containers must be maintained at all times!
Segregate Chemicals according to compatibility

43. MARQUETTE UNIVERSITY CHEMICAL COMPATIBILITY IN STORAGE
Keep stored incompatible chemicals apart from each other. Keep incompatible chemicals apart by cabinet, drawer, shelving unit or shelf. For liquid and high hazard chemicals, secondary containers are effective tools to prevent reactions between incompatible chemicals. When storing reactive chemicals, secondary containment can prevent degradation and reactions that occur during storage. It is best to use secondary containers made of materials that are non-reactive (i.e., polyethylene, polypropylene). Refer to Marquette’s Guidelines for Preventing Chemical Incompatibility Hazards.
Hazard Storage Class
Storage Type
Examples
Inorganic Acids
Corrosives Cabinet Do not store acids and bases in same cabinet
Conc. Hydrochloric Acid (37%), Phosphoric Acid
Less than concentrated: Sulfuric Acid, Nitric Acid
Organic Acids
Corrosives Cabinet
Dichloroacetic Acid, EDTA (ethylenedinitrilo tetraacetic acid), Thimerosal
Bases
Corrosives Cabinet Do not store acids and bases in same cabinet
Ammonium Hydroxide, Calcium Oxide, Potassium Hydroxide, Sodium Hydroxide
Oxidizing / Special Handling Inorganic Acids
Cabinet labeled ‘Oxidizing / Special Handling Inorganic Acids’
Separate secondary containment for each (& label)
Bromine, Hydrofluoric Acid
Concentrated: Nitric Acid (70%) , Perchloric Acid (60%), Sulfuric Acid (96%)
Oxidizers
General Storage Cabinet Cabinet labeled ‘Oxidizers’
Sodium Hypochlorite. The following are generally considered oxidizing substances: Peroxides, Perchlorates, Chlorates, Nitrates, Nitrites and less than concentrated Perchloric Acid.
Toxics
Designated Storage Cabinet
Cabinet labeled ‘Toxics’ , use secondary containment
Chloroform, Ethidium Bromide, Lead, Mercury Compounds, Potassium Cyanide, Phenol
Flammables
Flammable Storage Cabinet Only keep flammables in a flammable cabinet
Acetone, Acetic Acid, Benzene, Ethyl Ether, Formaldehyde, Heptane, Hexane, Methanol, Pentane, Picric Acid, Toluene, Xylene
NONE
General Storage Cabinet
Double check NFPA Ratings to ensure general storage is appropriate
If there is an asterisk with the hazard storage class number (6*), the chemical is considered to be a particularly hazardous substance by Marquette University. A Standard Operating Procedure (SOP) is required for all particularly hazardous substances.

44. 90-Day Hazardous Waste Accumulation Area Procedures

45. 90-Day Storage Area
Full, labeled and dated containers should be brought here for storage until the next waste pickup
Accumulation date is the date it is brought into storage area
Containers labeled and label is facing forwards
Containers must be clean, closed and intact
Incompatible materials must be segregated
There must be at least 3 feet of aisle space at all times
The area must be free of debris and spills
These parameters above are federal & state regulations that must be followed or fines will be incurred!!

46. The 90-day storage area is inspected weekly to ensure that all of these regulations are complied with
Waste can only be stored in the accumulation area for 90 days
Any waste brought into the storage area must be marked on the waste generation form that is to be sent to Dennis

47. 11/05/08
Olin Engineering 126 1 1
Jon Pipkorn
Toluene
Liquid
4 L
2 L
Glass 1

48. Your Responsibilities
You must fill out an inventory of material generated or discarded and send it to Dennis
State and Federal Regulations State:
“The identity and location of all stored hazardous waste shall be known throughout the entire accumulation period.”
To maintain documentation of hazardous waste that is currently being stored, in case of an emergency
Makes waste shipment easier
Aids in determining waste generation rate
Helps identify waste minimization opportunities
Please fill out sheet for materials to be disposed of on a regular basis
Inspect your work area to ensure proper procedures and practices are being followed

49. 90-Day Hazardous Waste Storage

50. What happens when an Acid and Oxidizer are mixed?

51. Spill Response, Clean-Up, and Emergency Response

52. Please reference the Marquette University Emergency Procedures Guide and Contingency Plan for further details on what to do in case of an emergency.

53. Mercury Thermometer Exchange Program
Replace mercury thermometers with alcohol thermometers for FREE
The new alcohol thermometers will be paid for by EHS
Eliminates the possibility of mercury spills occurring
Please fill out the “Mercury Thermometer Exchange Request” Form and send to Dennis Daye

54. Causes of chemical spills are as follows:
Causes of a Spill
Causes of chemical spills are as follows:
Inappropriate handling techniques;
Inappropriate storage containers;
Damaged storage containers;
Uncontrolled access to chemical storage;
Lack of chemical-related training; and
Lack of supervision.

55. Dangers of Chemical Spills
Slip, trip, fall hazard
Contamination of other materials
Risk of Fire
Possible Release to the Environment
Routes of Exposure to Hazardous Materials
Inhalation
Injection
Ingestion
Absorption

56. Dangerous to you… Why chemicals are dangerous? Chemicals can cause:
- Burns
- Adverse health effects
- Permanent disabilities
- Death
Sometimes problems occur immediately (Acute effect)
Others may happen after years of exposure (Chronic effect).

57. Spill Prevention Planning
Only buy and store amount of material needed
Buy the least hazardous materials possible
Use non-hazardous materials when possible
Minimize traffic in the area
Store liquid wastes in secondary containers
Regularly inspect containers to ensure their integrity
Be aware of evacuation routes and emergency equipment

58. Managing A Spill
What type and size of spills am I capable of managing?
You should only be cleaning up small spills (less than 1 gallon) of known materials that you work with on a regular basis after you have had attended a hands-on training session given by the EHS department.
Small spill clean-up kits are located in the 90-day storage area and in “all” laboratories.
Notify the Public Safety Department (x8-1911) for larger spills, or spills containing reactive or highly toxic materials. Public Safety will notify the proper authorities.

59. Spill Kits
These spill kits contain everything you need to properly manage a small spill in your labs.
These are available for $48 each.
Please contact Dennis Daye to place an order and purchase.

60. Managing A Spill…
In the event of a chemical spill, first decide if you are trained, knowledgeable and equipped to handle the incident.
Prepare a plan of action (e.g. waiting for help, attend to injured, shutting off the valve, turn off ignition sources in presence of flammables if safe to do so)
Immediately evacuate the lab and notify Public Safety if there is a possibility of an acute respiratory hazard present or if you need assistance to clean up the spill.
Never proceed to clean up a spill if you do not know the hazards associated with the chemical or if you are unsure of how to clean up the spill.
If anyone is injured or contaminated, immediately notify Public Safety and begin decontamination measures or first aid, if trained.
Make sure to wear the proper PPE.
Apron, Gloves, Goggles, etc.

61. Managing A Spill…
Contain the spill (Stopping the source and stopping the spread)
stopping the source includes:
Closing a valve;
Shutting down a pump to stop flow;
Putting “bandage” around a leaking hose;
Positioning of leaking container.
stopping the spread includes:
Building a barrier around the spill;
Make a flow channel;
Use of absorbent or spill pads;

62. Managing A Spill…
Absorbent should be distributed over the entire spill area, working from the outside, circling to the inside.
This stops the spread of the spilled chemical.
When spilled materials have been absorbed, use brush and scoop to place materials in an appropriate container (bag is provided in spill kits).
Dispose of any contaminated PPE used during cleanup.
Complete hazardous waste
sticker, identifying the material
as Spill Debris involving XYZ
Chemical, and affix onto the
container. Arrange for pick-up
by EH&S Dept. as soon as
possible.

63. Flammable Liquids When managing a spill of a flammable liquid…
Turn off all sources of ignition
Lay the chemical spill pads over the spill
Pads are designed to suppress flammable vapors
Allow pads to completely absorb the liquid
Place the pads in plastic disposal bag
Wipe up any remaining liquid with paper towel
Dispose of the paper towel in plastic bag
Seal bag and attach a completed hazardous waste sticker

64. After the spill…
Remember that absorbed materials have the same properties and hazards as the original spilled materials.
Safely dispose all disposable coveralls, gloves and respirators.
Decontaminate all non-disposable items (brooms, shovels, thongs, protective clothing) using a mild detergent and water.
Arrange for pick up by EH&S Dept. as soon as possible.

65. After the spill… Review what happened to prevent reoccurrence.
No matter how small the spill, keep a record of what happened.
Make sure that supplies (e.g. first aid, spill control kit) are replaced immediately. (Contact EH&S)
ONLY HANDLE SPILLS OF A GALLON OR LESS OF A KNOWN MATERIAL. FOR LARGE SPILLS OR REACTIVE MATERIALS CONTACT PUBLIC SAFETY (x8-1911) .

66. What to do when an emergency occurs…
TAKE CARE OF THE SAFETY OF YOURSELF AND OTHERS!
Activate the building’s fire alarm system.
If you have bodily contact with material:
immediately remove any contaminated clothing
flush the area with copious amounts of water
Call Public Safety at
Identify yourself and why you are calling
Identify the exact location and nature of the emergency
Identify any injuries of symptoms involved
Identify all hazardous materials involved (if known)

67. What to do when an emergency occurs…
Evacuate building to a safe distance (at least 100 feet)
leave clear access for emergency personnel
Keep all persons exposed in the same area. They should not leave until they are cleared by proper authorities.
If you have time to do so safely
Close, but do not lock, doors behind you to isolate the area
Turn off, unplug, or remove potential sources of ignition
Contain the spill material with berms or other means
Post a sign to warn others not to enter the area
YOUR SAFETY AND THE SAFETY OF OTHERS
SHOULD BE YOUR TOP PRIORITY!

68. ALWAYS CALL 288-1911 ON CAMPUS TO
This is a general awareness training. You are not trained as an emergency responder and should not attempt to manage emergencies. Emergency agencies such as the Fire Department, Police Department and Haz Mat Response Teams will be responsible for situations other than easily contained spills or incidental situations.
ALWAYS CALL ON CAMPUS TO
REPORT AN EMERGENCY

69. Questions or Suggestions?
Feel free to contact Dennis Daye (414) or
Aaron Walters with questions, concerns, or suggestions.

70. Thank you for participating in Hazardous Waste Generator Requirements Training