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Pauli principle. Wolfgang Pauli and Niels Bohr study spin.

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Presentation on theme: "Pauli principle. Wolfgang Pauli and Niels Bohr study spin."— Presentation transcript:

1 Pauli principle

2 Wolfgang Pauli and Niels Bohr study spin

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5 Σ ∆ l = ±1 ∆ S = 0

6 Σ ∆ l = ±1 ∆ S = 0

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10 H2H2

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12 H2H2

13 He 2

14 He 2 + ion.

15 H 2 + ion

16 H 2 - ion

17 The relative sizes of the lithium 1s and 2s atomic orbitals

18 Li 2

19 The three mutually perpendicular 2p orbitals on tow adjacent boron atoms.

20 The two p oribitals on the boron atom that overlap head-on combine to form bonding and antibonding orbitals.

21 The expected MO energy-level diagram for the combination of the 2 P orbitals on two boron atoms.

22 The expected MO energy-level diagram for the B 2 molecule

23 The correct MO energy-level diagram for the B 2 molecule.

24 The MO energy-level diagrams, bond orders, bond energies, and bond lengths for the diatomic molecules, B 2 through F 2.

25 An apparatus used to measure the paramagnetism of a sample

26 When liquid oxygen is poured into the space between the poles of a strong magnet, it remains there until it boils away. Source: Donald Clegg

27 The MO energy-level diagram for the NO molecule

28 The MO energy-level diagram for both the NO+ and CN- ions

29 A partial MO energy-level diagram for the HF molecule

30 The electron probability distribution in the bonding MO of the HF molecule

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36 + ↓

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