1. HCl, 231007 F<-<-X, v´=1, J´=5,6,7 & REMPI spectrum for v´=7 based on H+ mass ONLY Agust,heima,...HCl,agust07-/F1DQ-231007vhwak.pxp Agust,heima,...HCl,agust07-/F1DQ-231007avhwak.pxp Agust,www,...HCl,agust07-/F1DQ-231007vhwak.ppt Agust,heima,...HCl,agust07-/F1DQ-231007vhwak.xls And Agust,heima,...HCl,agust07-/Fmass spectra vs v and J-231007ak.pxp

3. 35Cl+

5. No 35Cl+ to bee seen

7. No 35Cl+ to be seen

8. v´=0 I(H+)/(I(H35Cl+)+I(H37Cl+)) v´=1, 2 I(H+)/(I(H35Cl+)+I(H+)) DOTS: v´=0, J=7,8,9 Power / energy (mJ) Broken lines v´=2, J´=3,3,2 v´=1, J=6 UNbroken lines v´=1, J´= 5,6,7

9. Datapoints for v´=1, J´= 4-9 v´=0 I(H+)/(I(H35Cl+)+I(H37Cl+)) v´=1, 2 I(H+)/(I(H35Cl+)+I(H+)) From HClmassF01-210807vhw-ak.xls v´=1 : : v´=1 DOTS: v´=0, J=7,8,9 Power / energy (mJ) Broken lines v´=2, J´=3,3,2 v´=1, J=6 V´=1, J=8 To be compaired with:

11. Comment: 1) Slight 35Cl+ signal is seen in J´= 7, v´=1 (F<-<-X), whereas no 35Cl+ is seen for J´= 5,6 2) As to be expected the REMPI spectrum, based on H+ recording only shows big “relative signals” for J´= 8, compared to other J´levels BOTH for H35Cl and H37Cl.

12. Comment: Slight 35Cl+ signal is seen in J´= 7, v´=1 (F<-<-X), whereas no 35Cl+ is seen for J´= 5,6