1. FR Veil Provides Low Cost Model To Achieve ASTM E-84 Class A Smoke Index John B. Rowen Avtec Industries, Inc.

2. Abstract This paper will examine the design, technology and testing program, successfully employed in the development of an economical surfacing veil based system that will provide E-84 Class A Smoke Developed Index behavior in pultruded parts.

3. Introduction Pultruded Building Materials Low cost pultruded building and structural components have excellent strength, light weight and corrosion resistant properties. However upon exposure to flame or high radiant heat, several troublesome concerns are inherent in these composite materials.

4. FST These concerns are referred to as FST: –Fire or Surface Flammability –Smoke Generation –Toxicity of Combustion By-products These characteristics are very often subject to prescribed regulatory code criteria by governing authorities and end users.

5. ASTM E-84 Historically, particular emphasis has been placed on the ASTM E-84-01 test, e.g., “Standard Test Method for Surface Burning Characteristics of Burning Materials”. A Class 1 Flame Spread Index, e.g., 25 or less, is easily achievable with FR resins and FR additives. The E-84 Class A Smoke Developed Index, e.g., less than 450, has been extremely difficult to achieve with low cost polyester resin. Not meeting this protocol criteria keeps pultruded building components from greater market acceptance where regulators deem E-84 Smoke characteristics a requirement.

6. New Sales & Market Opportunities Meeting the prescribed E-84 Class A Low Smoke Requirement can allow candidacy in building market opportunities where pultruded composites have historically been exempt.

7. Introduction Summary ASTM E-84 Class 1 Flame Spread with a Class A Smoke Index is the regulatory “toll” for candidacy in a greater share of the building construction market.

8. DISCUSSION OF EVOLUTION By way of analytical testing of innovative intumescent surface coatings applied to composite structural components, it was observed composite polymer parts could pass numerous standardized FST oriented test protocol requirements that meet favorable fire safety characteristics.

9. These Tests Included ASTM E-162- “Standard Method of Test for Surface Flammability of Materials Using a Radiant Heat Source”. ASTM E-662-”Standard Test Method for Specific Optical Density of Smoke Generated by a Solid Material”. BSS 7239- Boeing Specification Support Standard 7239 Test Method for Toxic Gas Generation by Materials Combustion. ASTM E-119- “Standard Test Method for Fire Tests of Building Construction and Materials”. Second Ion Mass Spectrophotometry Analysis to Identify a Specific Elemental Constituent. ASTM E-84-01- “Standard Test Method for Surface Burning Characteristics of Building Materials”.

10. Pultruded Surface Intumescense Whereas pultruded products employ a surfacing fabric, e.g., veil, the intumescent constituent composition could be attached to a veil and processed into a part. This fabric can provide an inter-laminate fire retardant and smoke suppressing surface layer.

11. Southwest Research Institute ASTM E-84-01 Investigation of the Surface Burning Characteristics of a Brominated Pultruded Flat Sheet with Polyester Veil

12. Southwest Research Institute ASTM E-84-01 Investigation of the Surface Burning Characteristics of a Fire Retardant Coating

13. A material design program was established to meet the following criteria: The fabric, e.g., veil, must be a non-combustible material. The fire retarding(FR) and smoke suppressing constituents incorporated on and into the fabric must be non-hazardous and in particular non- brominated. The FR powder composition must not dust or flake during end product production practices. This would include transport, storage, handling and slitting, as well as, final introduction into die cavity. All commodity polyester and vinyl ester resins should be fully compatible. The FR veil will have a glass rich side to be oriented against the die to provide traditional surface characteristics.

14. The FR veil will not require pre-wetting or dipping of the fabric into a resin bath. The veil will wet out correctly and properly when fed directly into the die from its roll. No significant changes are to be necessary, with regard to pre-former alignment or orientation. The fabric will accommodate small edge radii without cracking, loss or corruption of the intumescent chemical composition layer. Die temperature zones may be run at temperatures up to 450 deg. F with no deterioration in the systems processibility or FR effectiveness. The FR composition layer must be white or off- white so it may be pigmented any color.

15. All organic peroxide initiators and blends thereof must work properly and correctly without any special consideration or adjustment. Surface Characteristics of a finished pultruded part must exhibit the sheen and texture of a typical commercially available part. Being an integral component within a part, the system will exhibit excellent flexural movement without delamination. The FR veil will slit in accordance to any width requirement. Widths up to 72 Inches would be required with lengths generally determined by permissible roll diameters. A non-brominated pultrusion resin formula employing ATH will achieve an E-84 Class A Smoke Developed Index of less than 450 when used with the intumescent veil and costs less than $0.70/lb.

16. Intumescent Chemical Composition The intumescent composition contains many compounds and materials. These constituents are categorized into 5 different functional groups or families. These groups function in the following stepwise sequence when exposed to open flame or high radiant heat.

17. Intumescent First- Catalyst Second- Carbonific Third- Blowing Agent Fourth- Inorganic Binder Fifth- Ceramic

18. Fabric Physical Properties The glass surfacing veil fabric has excellent tensile strength and porosity, or pore volume, which holds the FR composition in place. The glass rich side of the assembly provides excellent surface characteristics after pultrusion processing.

19. Fabric Binder & Processing The adhesive binder that holds the FR powder composition to the glass fabric is thermally sensitive in the temperature ranges in which pultrusion dies operate. Although it crosslinks above 300°F, it behaves like a thermoplastic at lower temperatures. The softening of the binder allows the FR fabric to accommodate small radii and integration of the FR powder to the part surface, reducing surface flammability characteristics.

20. Testing Although full scale E-84 testing was done on pultruded specimens, the majority of the development testing was accomplished by vacuum bagging a wide variety of specimens and testing them by Cone Calorimetry.

21. Southwest Research Institute ASTM E-84-01 Investigation of the Surface Burning Characteristics of a Fire Retardant Coating

22. Southwest Research Institute ASTM E-84-01 Investigation of the Surface Burning Characteristics of a Brominated Pultruded Flat Sheet with Polyester Veil

23. ASTM E-84 PropertyFR Glass MatPolyester Veil Flame Spread Ratio 19.2 23.4 Smoke Obscuration Index 751 984.0 ASTM E-84-01 results on two brominated pultruded laminates. The only difference between the two is the surfacing veil.

24. Cone Calorimeter PropertyFR Mat & Laminate Typical Brominated Laminate Initial Mass 40.6 g Final Mass 23.6 g26.2 g Smoke Obscuration Avg. Smoke Yield (g/g).057.106 Total Smoke Release (g) 13.97926.130 Cone Calorimeter Tests at 50 kW/m 2 performed on two pultruded specimens. One has an FR veil with a non-brominated resin. The second is a brominated resin specimen with a polyester veil.

25. Cone Calorimeter Sample /Test # Placard initial mass(g) Mass Correlated Conversion factor Correlated Total Smoke Release Correlated Average Smoke Production (g/m²/s) Duration of Test Peak Heat (kW/m²) Release Time(s) to ignition Standard Generation 4 Veil 85.51.0023.98.03469122541 Sample 1 glass up FR glass mat out 80.71.0621.20.018119891 25 & 430* Sample 2 TSWB out FR glass mat down 81.61.0419.88.020105812346 Sample 3 Double coat FR mat sandwich construction 82.21.0616.16.012134911056 Pultruded Bromine Panel Polyester veil 40.62.0453.31.14446518546 50 kW/m 2 Cone Calorimeter test results comparing three specimens with three different FR veil orientations to an earlier standard veil and the brominated specimen

26. Cone Calorimeter Sample /Test # Placard initial mass(g) Mass Correlated Conversio n factor Correlated Total Smoke Release Correlated Average Smoke Production (g/m²/s) Duration of Test (s) Peak Heat (kW/m ²) Release Time (s) to ignitio n Standard Pultruded Br Veil, Polyester 40.61.0026.13.07146518546 Sample 1 Vacuum Bag FR mat Wt.: 36.2 g/ft² 80.70.5010.00.009119891 25 & 430* Sample 2 Vacuum Bag FR Mat Wt.: 33.0 g/ft² 81.80.5013.09.012953140 29 & 271* Sample 3 Vacuum Bag FR Mat Wt.: 33.0 g/ft² 81.90.5011.40.013859172 55 & 126* Sample 4 Pultruded FR Mat Wt.: 33.0 g/ft² 93.60.437.67.007967160 50 & 181* 50 kw/m 2 Cone Calorimeter Test Results of the Pultruded, Brominated Panel Described Earlier Verses Three Vacuum Bagged FR Veil Placards and a Pultruded, ATH Panel Described the next slide’s ASTM E-84

27. Pultrusion Resin Formula Commodity Grade Iso-Polyester Resin ATH, e.g., Aluminum Trihydroxide A liquid Phosphorous Material Pigment Dispersion Mold Release U.V. Inhibiter Methyl Methacrylate A three stage Peroxide Initiator Package. Final formula viscosity was approx. 2,300 cps. Cost Model of the final formula totals $0.64 / lb.

28. Southwest Research Institute ASTM E-84-01 Investigation of the Surface Burning Characteristics of a Pultruded Glass Fiber/Polyester Resin Laminate with Fire Retardant and Smoke Suppressing Surfacing Veil