1. Hazardous Material? Listed in the Hazardous Materials Table, 49 CFR 172.101 Table Listed in the Hazardous Materials Table, 49 CFR 172.101 Table Meets the defining criteria for a Hazard Class, 49 CFR part 173 Meets the defining criteria for a Hazard Class, 49 CFR part 173 Materials that are a Hazardous Substance (EPA reg in DOT rule) Materials that are a Hazardous Substance (EPA reg in DOT rule) Materials that are a Hazardous Waste, EPA RCRA regulated Materials that are a Hazardous Waste, EPA RCRA regulated

2. Who Regulated HM? US Department Of Transportation US Department Of Transportation DOTDOT International Civil Aviation Organization International Civil Aviation Organization ICAOICAO International Air Transport Association International Air Transport Association IATAIATA International Maritime Organization International Maritime Organization IMDGIMDG United Nations United Nations UN TDGUN TDG Transport Canada Transport Canada TC – TDG regulations (plain language)TC – TDG regulations (plain language)

3. What About My Material? 1 st : CLASSIFY it into a Hazard Class 1 st : CLASSIFY it into a Hazard Class 2 nd : Identify the REQUIREMENTS 2 nd : Identify the REQUIREMENTS 3 rd : Identify the EXCEPTIONS 3 rd : Identify the EXCEPTIONS 4 th : Do you qualify for the exceptions 4 th : Do you qualify for the exceptions 5 th : Use the exceptions 5 th : Use the exceptions 6 th : Package the material 6 th : Package the material 7 th : Verify and Transport 7 th : Verify and Transport

4. 172.101 Table, HMT This is the “Backbone” to the regulations This is the “Backbone” to the regulations Start here in Classification Start here in Classification Materials listed by Materials listed by Technical NameTechnical Name End Use/Product NameEnd Use/Product Name Generic Chemical/Use FamilyGeneric Chemical/Use Family Hazard Class Name (requires other classification first)Hazard Class Name (requires other classification first)

5. Multiple Hazard Materials If your material meets multiple definitions you must: If your material meets multiple definitions you must: Identify each Hazard Class/DivisionIdentify each Hazard Class/Division Go to the Precedence of Hazard TableGo to the Precedence of Hazard Table Found at 173.2a Found at 173.2a Determine the PRIMARY HAZARDDetermine the PRIMARY HAZARD Return to the HMT and look for a Hazard Class Name that includes all SUBSIDARY HAZARDS Return to the HMT and look for a Hazard Class Name that includes all SUBSIDARY HAZARDS

6. Multiple Hazard Materials BE CAUTIOUS BE CAUTIOUS Multiple hazards may remove you or limit you from the Small Quantity Exception UsageMultiple hazards may remove you or limit you from the Small Quantity Exception Usage Toxic Subsidiary Hazards may eliminate you Toxic Subsidiary Hazards may eliminate you Radioactive materials are not allowed by ANL Policy (consult with the SPM/Shipping Staff) Radioactive materials are not allowed by ANL Policy (consult with the SPM/Shipping Staff)

7. Small Quantity Exception  DOT has an EXCEPTION for small quantities  49CFR173.4 Contains Requirements  ANL Exemption to the Transportation Safety Manual more restrictive  Special requirements for air shipments in IATA  Label/marking, packaging, inner packaging

8. Quantity Limitations Apply For 6.1 PG I Maximum per inner container is 1 gram For 6.1 PG I Maximum per inner container is 1 gram For all others Maximum per inner container is 30 grams or 30 milliliter For all others Maximum per inner container is 30 grams or 30 milliliter Outer package may contain only one hazard class per package Outer package may contain only one hazard class per package Maximum package limit is 29 kg (64 lb.) Maximum package limit is 29 kg (64 lb.)

9. Tested Packaging is Required Package that has been tested available from the APS Stock Room Package that has been tested available from the APS Stock Room Packages must be tested in configuration used Packages must be tested in configuration used From 6 feet all packages withstand From 6 feet all packages withstand 1 drop on top, bottom, long side, short side,1 drop on top, bottom, long side, short side, 1 drop onto intersection of 3 corners1 drop onto intersection of 3 corners Compressive load test required Compressive load test required

10. Special Marking Required Outside of the package must be marked Outside of the package must be marked “This package conforms to 49 CFR 173.4”“This package conforms to 49 CFR 173.4” Marking must be Marking must be Visible during shipment (not on bottom)Visible during shipment (not on bottom) Contrasting colorContrasting color Durable (withstand 90 days of conditions)Durable (withstand 90 days of conditions) LegibleLegible 1/2” high lettering.1/2” high lettering.

11. Inner Receptacle Requirements (for Ground Transport ONLY) Not liquid full at 55degrees C (131 F) Not liquid full at 55degrees C (131 F) Is plastic at lease 0.2 mm (0.008 inch) thick or glass, earthenware, metal Is plastic at lease 0.2 mm (0.008 inch) thick or glass, earthenware, metal All removable closures held securely with wire, tape or other positive means All removable closures held securely with wire, tape or other positive means Air Transport packages have additional requirements Air Transport packages have additional requirements Temp range -40 to 131 degrees FTemp range -40 to 131 degrees F Withstand internal pressure of 95 kPaWithstand internal pressure of 95 kPa

12. Packaging Requirements Cushioning and absorbent must: Cushioning and absorbent must: Not react with materialNot react with material Be capable of absorbing entire contentsBe capable of absorbing entire contents Receptacles packed in inner packaging, then placed into outer Receptacles packed in inner packaging, then placed into outer Outer package must be sealed, and may not be opened during transportation. Outer package must be sealed, and may not be opened during transportation.

13. Safety For all packages received: For all packages received: Competent person must inspect packages for:Competent person must inspect packages for: signs of leakage signs of leakage significant damage to packaging significant damage to packaging Must be performed before the package if openedMust be performed before the package if opened Use this inspection to verify that all materials have been disclosed to the CAT/beamline group, compare against ESAFUse this inspection to verify that all materials have been disclosed to the CAT/beamline group, compare against ESAF If package is acceptable release to user.If package is acceptable release to user.

14. Leaking or Suspect Packages If package appears to be damaged: If package appears to be damaged: Place package in the nearest fume hoodPlace package in the nearest fume hood Be sure there are no incompatibles in the hood Be sure there are no incompatibles in the hood Close sash to fully closed position Close sash to fully closed position Block or close drains Block or close drains Contact the APS Chemical Hygiene OfficerContact the APS Chemical Hygiene Officer Contact shipper and user if possibleContact shipper and user if possible Verify contents of package from documentationVerify contents of package from documentation

15. Leaking or Suspect Packages If leaking contact 911 for assistance If leaking contact 911 for assistance Notify the Floor Coordinator or the APS Chemical Hygiene OfficerNotify the Floor Coordinator or the APS Chemical Hygiene Officer If shipper can provide appropriate information, continue with package inspectionIf shipper can provide appropriate information, continue with package inspection If outer packaging is damaged, but contents are not, release contents to user.If outer packaging is damaged, but contents are not, release contents to user.

16. Leaking or Suspect Packages Packaging and Waste Materials Packaging and Waste Materials Treat materials as a Hazardous WasteTreat materials as a Hazardous Waste Contact EMO-Waste Management for guidance if required or Contact EMO-Waste Management for guidance if required or Contact APS Chemical Hygiene Officer for guidance Contact APS Chemical Hygiene Officer for guidance If packaging appears contaminatedIf packaging appears contaminated Move to satellite accumulation area in another container Move to satellite accumulation area in another container Mark the container “Suspect Hazardous Waste” Mark the container “Suspect Hazardous Waste” Do not intermingle with other wastes Do not intermingle with other wastes

17. Leaking or Suspect Packages Package and Contents Breached Package and Contents Breached Seek guidance from EMO-Waste Management on disposalSeek guidance from EMO-Waste Management on disposal Treat as hazardous wasteTreat as hazardous waste Do not attempt to recover materialsDo not attempt to recover materials May be attempted after appropriate safety review has been completed May be attempted after appropriate safety review has been completed Only allowed if appropriately characterized and adequate controls in place Only allowed if appropriately characterized and adequate controls in place CAT management has authorized work to proceed CAT management has authorized work to proceed Written procedures for recovery may be needed.Written procedures for recovery may be needed.

18. Leaking or Suspect Packages Actions required Actions required CAT management must consult with APS Chemical Hygiene Officer to:CAT management must consult with APS Chemical Hygiene Officer to: determine investigation requirements determine investigation requirements determine reporting requirements determine reporting requirements prepare appropriate reports prepare appropriate reports document the situation and actions taken document the situation and actions taken

19. TUD-23 Small Quantity Exception DOT Class or Division Number Name of Class or Division Maximum amount per container (gram solid or ml liquid) (Materials that can be transported by APS Users in small quantities on ANL site) Class 3 Flammable and combustible liquid 30 Division 4.1 Flammable solid 30 Division 4.2 (PGII and PGIII) Spontaneous combustible material 30 Division 4.3 (PGII and PGIII) Dangerous when wet material 30 Division 5.1 Oxidizer30 Division 5.2 Organic Peroxide 30 Division 6.1 (PGI) Poisonous material 1 Division 6.1 (PGII and PGIII) Poisonous material 30 Class 8 Corrosive material 30 Class 9 Misc. hazardous material 30 Qualifying materials and quantity limits of materials that may be transported to the APS by APS Users. This table applies to ground transport only.

20. TUD-23 Small Quantity Exception DOT Class or Division Number Name of Class or Division Maximum amount per container (gram solid or ml liquid) (Materials that cannot be transported by APS Users in small quantities on ANL site) Class 1 All divisions of explosives and detonating devices 0 Class 2 Flammable gas, non- flammable compressed gas, and poisonous gas 0 Division 4.2 (PGI) Spontaneous combustible material 0 Division 4.3 (PGI) Dangerous when wet material 0 Division 6.2 Infectious agents 0 Division 7 Radioactive material 0

21. TUD-25 Transport of Cryo-Preserved Biological Samples Proper Shipping Name Hazard Class UN Number Labels Required Propane2.119782.1 Ethane2.110352.1 Chlorodifluoromethane2.210182.2 Refrigerant gas, n.o.s. 2.210782.2 Authorized Materials

22. TUD-25 Transport of Cryo-Preserved Biological Samples Manufacturer Characteristic International Cryogenics Taylor-WhartonMVE Generic product name (as described in the manufacturer’s literature) Liquid Nitrogen Shipping Vessel Liquid Nitrogen Biological Shipper Vapor Shipper Model Number VS series (3 sizes) CX, CP series (4 sizes) SC series (4 sizes) LN 2 Capacity (liters) 4, 5, 6 CP 4, 5, 6, 12, CX 4.4, 6.4 2, 3, 4, 9 Static holding time (days) 23, 37, 40 11, 14, 30, 30, 34 8, 14, 14, 25 Evaporation rate (liters/day) 0.12 to 0.19 0.17 to 0.40 0.19 to 0.85 Outside diameter (inches) 8.75 to 15 9.2 to 15.6 7.2 to 18.3 Height (inches) 20.6 to 25 18.2 to 26.4 13.5 to 22 Full weight (pounds) 21.5 to 33 18.6 to 50.0 8.8 to 38 Capacity, number of vials (depending on size of shipper) 36 to 924 (1.2 ml) 30 to 500 (2 ml) 9 to 1134 (1.2 or 2 ml) Lockable necktube insert YesYesYes Outer Shell Aluminum Ribbed aluminum Aluminum Allowed dry shippers

23. User Shipping Summary DOT Hazard Classification Options for Shipment Handling ANL Shipping Department User Transport on the ANL Site User Arranged Carrier Pickup Non- hazardous material Including dry shippers not containing DOT hazardous materials AllowedAllowed Allowed 1,2 Hazardous Materials and Dangerous Goods 1. Small Quantities Allowed Allowed 3 Allowed 1,2 (ground transport only) 2. Bio-samples in dry shippers with frozen propane, etc. 4 Allowed Allowed (on the ANL-E site only) Not Permitted 3. All other Hazardous Materials Required Not Permitted Who Can Handle Non-Radioactive APS User Shipments 1 Shipping papers shall be addressed as from: User Name, User’s Home Institution, c/o APS Sector ___, 9700 South Cass Avenue, Argonne, IL 60439. 2 If the sender is an ANL employee or if ANL material is being sent then the shipment must be arranged through the ANL Shipping Department. 3 In accordance with the small quantity exception as specified in APS Technical Update 23 (16 July 1998). 4 Air shipment allowed in accordance with the DOT requirements as specified in APS Technical Update 25 (20 May 1999).

24. Dry Shipper